Publications 2013


  1. J. Schnaidt, M. Heinen Z. Jusys, and R.J. Behm
    Mechanistic aspects of the electro-oxidation of ethylene glycol on a Pt-film electrode: A combined in situ IR spectroscopy and online mass spectrometry study of kinetic isotope effects
    Catalysis Today, 202, 154-162 (2013)
    DOI: 10.1016/j.cattod.2012.05.019
  3. Ali M. Abdel-Mageed, S. Eckle, H.G. Anfang, R.J. Behm
    Selective CO methanation in CO2-rich H2 atmospheres over a Ru/zeolite catalyst: The influence of catalyst calcination
    J. Catal., 298, 148-160 (2013)
    DOI: 10.1016/j.jcat.2012.11.001
  5. L.A. Mancera, R.J. Behm, and A. Groß
    Structure and local reactivity of PdAg/Pd(111) surface alloys
    Phys.Chem.Chem.Phys., 15, 1497-1508 (2013)
    DOI: 10.1039/C2CP42914D
  7. T. Waldmann, J. Klein, H.E. Hoster, and R.J. Behm
    Stabilization of Large Adsorbates by Rotational Entropy: A Time-Resolved Variable-Temperature STM Study
    ChemPhysChem, 14, 162–169 (2013)
    DOI: 10.1002/cphc.201200531
  9. L.-C. Wang, Y. Zhong, H. Jin, D. Widmann, J. Weismüller, and R.J. Behm
    Scale effects on the surface chemistry of nanoporoius materials: Mechanistic aspects of the CO oxidation reaction on nanoporous Au catalysts
    in: Advances Nanotechnology Physics, Chemistry and Biology of Functional Nanostructures, Eds. T. Schimmel, H. v. Loehneysen, and M. Barczewski, Baden-Württemberg Stiftung, Research Series. No. 69, Karlsruhe (2013), p. 41-71
  11. S. Sun, Z. Jusys, and R.J. Behm
    Electrooxidation of ethanol on Pt-based and Pd-based catalysts in alkaline electrolyte under fuel cell relevant reaction and transport conditions
    J. Power Sources, 231, 122-133 (2013)
    DOI: 10.1016/j.jpowsour.2012.12.091
  13. L.C. Wang, Y. Zhong, H.J. Jin, D. Widmann, J. Weissmüller, and R.J. Behm
    Catalytic activity of nanostructured Au: Scale effects vs. bimetallic / bifunctional effects in low temperature CO oxidation on nanoporous Au
    Beilstein Journal of Nanotechnology, 4, 111-128 (2013)
    DOI: 10.3762/bjnano.4.13
  15. S.M. Lang, A. Frank, I. Fleischer, and T.M. Bernhardt
    Is gold actor or spectator in the reaction of small AunPdm+ clusters with O2?
    Eur. Phys. J. D, 67: 19 (2013)
    DOI: 10.1140/epjd/e2012-30623-1
  17. S. Ditze, M. Röckert, F. Buchner, E. Zillner, M. Stark, H.-P. Steinrück, and H. Marbach
    Towards the engineering of molecular nanostructures: local anchoring and functionalization of porphyrins on model-templates
    Nanotechnology, 24, 115305 (2013)
    DOI: 10.1088/0957-4484/24/11/115305
  19. Y. Han, A.K. Engstfeld, C.-Z. Wang, L.D. Roelofs, R.J. Behm, and J.W. Evans
    Atomistic modeling of Ru nanocluster formation on  graphene/Ru(0001):  Thermodynamically versus kinetically directed-assembly
    MRS Proceedings, 1498, mrsf12-1498-s05-29 (2013)
    DOI: 10.1557/opl.2013.106
  21. I. Fleischer, D.M. Popolan, M. Krstić, V. Bonačić-Koutecký, and T.M. Bernhardt
    Composition dependent selectivity in the coadsorption of H2O and CO on pure and binary silver-gold clusters
    Chem. Phys. Lett., 565, 74-49 (2013)
    DOI: 10.1016/j.cplett.2013.02.013
  23. M. Stark, S. Ditze, M. Drost, F. Buchner, H.-P. Steinrück, and H. Marbach
    Coverage Dependent Disorder − Order Transition of 2H- Tetraphenylporphyrin on Cu(111)
    Langmuir, 29, 4104-4110 (2013)
    DOI: 10.1021/la3046753
  25. L.C. Wang, M. Tahvildar Khazaneh, D. Widmann, and R.J. Behm
    Dynamic TAP reactor studies of the oxidizing capability of CO2 on Au/CeO2 catalyst – A first step towards identifying a redox mechanism in the reverse water gas shift reaction
    J. Catal., 302, 20-30 (2013)
    DOI: 10.1016/j.jcat.2013.02.021
  27. Y. Han, A.K. Engstfeld, R.J. Behm, and J.W. Evans
    Atomistic modeling of the directed-assembly of bimetallic Pt-Ru nanoclusters on Ru(0001)-supported monolayer graphene
    J. Chem. Phys., 138, 134703 (2013)
    DOI: 10.1063/1.4798348
  29. S.M. Lang, A. Frank, and T.M. Bernhardt
    Activation and catalytic dehydrogenation of methane on small Pdx+ and PdxO+ clusters
    J. Phys. Chem. C, 117, 9791–9800 (2013)
    DOI: 10.1021/jp312852r
  31. J. Schnaidt, M. Heinen, Z. Jusys, and R.J. Behm
    Oxidation of 1-propanol on a Pt film electrode studied by combined electrochemical, in situ IR spectroscopy and online mass spectrometry measurements
    Electrochimica Acta, 104, 505-517 (2013)
    DOI: 10.1016/j.electacta.2012.12.139
  33. J. Schnaidt, M. Heinen, Z. Jusys, and R.J. Behm
    Oxidation of the partly oxidized ethylene glycol oxidation products glycol- aldehyde, glyoxal, glycolic acid, glyoxylic acid and oxalic acid on Pt electrodes - A combined ATR-FTIRS and DEMS spectro-electrochemical study
    J. Phys. Chem. C, 117, 12689–12701 (2013)
    DOI: 10.1021/jp402986z
  35. S. Brimaud and R.J. Behm
    Electro-deposition of a Pt monolayer film – Using kinetic limitations for atomic layer epitaxy
    J. Am. Chem. Soc., 135, 11716–11719 (2013)
    DOI: 10.1021/ja4051795
  37. H. Hartmann, T. Diemant, and R.J. Behm
    Spill-over effects on bimetallic Pt/Ru(0001) surfaces
    Topics Catal., 56, 1333-1344 (2013)
    DOI: 10.1007/s11244-013-0137-8
  39. F. Buchner, K. Forster-Tonigold, B. Uhl, D. Alwast, N. Wagner, A. Groß, and R.J. Behm
    Towards the Microscopic Identification of Anions and Cations at the Ionic Liquid | Ag(111) Interface: A Combined Experimental and Theoretical Investigation
    ACS Nano, 7, 7773–7784 (2013)
    DOI: 10.1021/nn4026417
  41. C. Pietzka, J. Scharpf, M. Fikry, D. Heinz, K. Forghani, T. Meisch, Th. Diemant, R. J. Behm, J. Bernhard, J. Biskupek, U. Kaiser, F. Scholz, E. Kohn
    Analysis of Diamond Surface Channel FETs with AlN Passivation Layers
    J. Appl. Phys., 114, 114503 (2013)
    DOI: 10.1063/1.4819453
  43. B. Uhl, Mi. Roos, R.J. Behm, T. Cremer, F. Maier, and H.-P. Steinrück
    Ionic liquid | metal interface: Structure formation and temperature dependent behavior of an ionic liquid adlayer on Au(111)
    Phys.Chem.Chem.Phys., 15, 17295 - 17302 (2013)
    DOI: 10.1039/C3CP52184B
  45. S.M. Lang, A. Frank, and T.M. Bernhardt
    Comparison of methane activation and catalytic ethylene formation on free gold and palladium dimer cations: product binding determines the catalytic turnover
    Catal. Sci. Technol., 3, 2926-2933 (2013)
    DOI: 10.1039/c3cy00286a
  47. H. Hartmann, T. Diemant, and R.J. Behm
    Kinetically limited CO adsorption: Spill-over as a highly effective adsorption pathway on bimetallic surfaces
    ChemPhysChem, 14, 3801-3805 (2013)
    DOI: 10.1002/cphc.201300722
  49. R. Reichert, J. Schnaidt, Z. Jusys, and R.J. Behm
    The Role and Impact of Reactive Side Products in Electrocatalytic Reactions: Methanol Oxidation as Case Study
    ChemPhysChem, 14, 3678-3681 (2013)
    DOI: 10.1002/cphc.201300726
  51. C. Osterkamp, J. Scharpf, S. Pezzagna, J. Meijer, T. Diemant, R.J. Behm, B. Naydenov, and F. Jelezko
    Increasing the creation yield of shallow single defects in diamond by surface plasma treatment
    Appl. Phys. Lett., 103, 193118 (2013)
    DOI: 10.1063/1.4829875
  53. S.M. Lang, A. Frank, and T.M. Bernhardt
    Composition and size dependent methane dehydrogenation on binary gold-palladium clusters
    Int. J. Mass Spectrom, 354-355, 365–371 (2013)
    DOI: 10.1016/j.ijms.2013.07.014
  55. S.M. Lang, I. Fleischer, T.M. Bernhardt, R.N. Barnett, and U. Landman
    Dimensionality Dependent Water Splitting Mechanisms on Free
    Manganese Oxide Clusters

    Nanoletters, 13, 5549–5555 (2013)
    DOI: 10.1021/nl4031456
  57. B. Uhl, F. Buchner, D. Alwast, N. Wagner, and R.J. Behm
    Adsorption of the ionic liquid [BMP][TFSA] on Au(111) and
    Ag(111) – Substrate effects on the structure formation
    investigated by STM

    Beilstein Journal of Nanotechnology, 4, 903-918 (2013)
    DOI: 10.3762/bjnano.4.102