Publications 2019

published

  1. G.G. Eshetu, T. Diemant, M. Hekmatfar, S. Grugeon, R.J. Behm, S. Laruelle, M. Armand, and S. Passerini
    Impact of electrolyte salts on the solid electrolyte interphase formation in sodium ion batteries
    Nano Energy, 55, 327-340 (2019)
    DOI: 10.1016/j.nanoen.2018.10.040

  2. B. Qin, H. Zhang, T. Diemant, X. Dou, D. Geiger, R.J. Behm, U. Kaiser, A. Varzi, and S. Passerini
    Exploring SnS Nanoparticles Interpenetrated with High Concentration Nitrogen-Doped-Carbon as Anodes for Sodium Ion Batteries
    Electrochim. Acta, 296, 806-813 (2019)
    DOI: 10.1016/j.electacta.2018.11.112

  3. Z. Jusys, J. Schnaidt, and R.J. Behm
    O2 reduction on a Au film electrode in an ionic liquid in the absence and presence of Mg2+ ions: Product formation and adlayer dynamics
    J. Chem. Phys., 150, 041724 (2019)
    DOI: 10.1063/1.5051982

  4. J. Schnaidt, T.L. Nguyen, Z. Jusys, and R.J. Behm
    How many electrons are transferred during the electrochemical O2 reduction in a Mg2+ -free / Mg2+ -containing ionic liquid?
    Electrochim. Acta, 299, 372-377 (2019)
    DOI: 10.1016/j.electacta.2018.12.159

  5. M. Eckardt, K. Sakaushi, A. Lyalin, M. Wassner, N. Hüsing, T. Taketsugu, and R.J. Behm
    The Role of Nitrogen-doping and the Effect of the pH on the Oxygen Reduction Reaction on Highly Active Nitrided Carbon Sphere Catalysts
    Electrochim. Acta, 299, 736-748 (2019)
    DOI: 10.1016/j.electacta.2019.01.046

  6. S.M. Lang, T.M. Bernhard, V. Chernyy, J.M. Bakke, R.N. Barnet, and U. Landman
    Selective C-H bond Activation of Ethane by Free Gold Clusters
    Int. J. Mass Spectrom., 435, 241-150 (2019)
    DOI: 10.1016/j.ijms.2018.10.034

  7. F. Buchner, M. Fingerle, J. Kim, T. Späth, R. Hausbrand, and R.J. Behm
    Interaction of Ultrathin Films of Ethylene Carbonate with Oxidized and Reduced Lithium Cobalt Oxide ‒  A Model Study of the Cathode | Electrolyte Interfaces in Li-ion Batteries
    Adv. Mater. Interfaces, 6, 1801650 (2019)
    DOI: 10.1002/admi.201801650

  8. J. Kim, E.-Ha Shin, J. Seo, H. Kim, G. Rojas, X. Chen, A. Enders, H. Kim, and J.-S. Kim
    Origin of the R(15 × 3) surface reconstruction of carburized W(110) - revisited
    Surf. Sci., 682, 33-37 (2019)
    DOI: 10.1016/j.susc.2018.10.023

  9. J. Klein, S. Brimaud, A.K. Engstfeld, and R.J. Behm
    Atomic scale insights on the electronic and geometric effects in the electro-oxidation of CO on PtxRu1-x/Ru(0001) surface alloys
    Electrochim. Acta, 306, 516-528 (2019)
    DOI: 10.1016/j.electacta.2019.03.053

  10. A.M. Abdel-Mageed, B. Rungtaweevoranit, M. Parlinska-Wojtan, X. Pei, O.M. Yaghi, and R.J. Behm
    Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal–Organic Framework
    J. Am. Chem. Soc., 141, 5201-5210 (2019)
    DOI: 10.1021/jacs.8b11386

  11. S. Chen, A.M. Abdel-Mageed, C. Gauckler,  S.E. Olesen, I. Chorkendorff, and R.J. Behm
    Selective CO Methanation on Isostructural Ru Nanocatalysts: The Role of Support Effects
    J. Catal., 373, 102-115 (2019)
    DOI: 10.1016/j.jcat.2019.03.015

  12. X. Dou, D. Buchholz, M. Weinberger, T. Diemant, M. Kaus, S. Indris, R.J. Behm, M. Wohlfahrt-Mehrens, and S. Passerini
    Study of the Na-Storage Mechanism in Silicon Oxycarbide -  Evidences for Reversible Silicon Redox Activity
    Small Methods, 3, 1800177 (2019)
    DOI: 10.1002/smtd.201800177

  13. J. Klein, F. Argast, A.K. Engstfeld, S. Brimaud, and R.J. Behm
    Electro-oxidation of methanol on Ru-core Pt-shell type model electrodes
    Electrochim. Acta, 311, 244-254 (2019)
    DOI: 10.1016/j.electacta.2019.04.081

  14. Z. Jusys, M. Binder, J. Schnaidt, and R.J. Behm
    A Novel DEMS Approach for Studying Gas Evolution at Battery-type Electrode|electrolyte Interfaces: High-voltage LiNi0.5Mn1.5O4 Cathode in Ethylene and Dimethyl Carbonate Electrolytes
    Electrochim. Acta, 314, 188-201 (2019)
    DOI: 10.1016/j.electacta.2019.05.076

  15. S. Mauthe, I. Fleischer, T.M. Bernhardt, S.M. Lang, R.N. Barnet, and U. Landman
    A gas phase CanMn4‐nO4+ cluster model for the oxygen evolving complex of photosystem II
    Angew. Chem., 131, 8592-8597 (2019)
    Angew. Chem. Int. Ed., 58, 8504-8509 (2019)
    DOI: 10.1002/ange.201903738
    DOI: 10.1002/anie.201903738

  16. D. Alwast, J. Schnaidt, K. Hankock, G. Yetis, and R.J. Behm
    Effect of Li+ and Mg2+ on the Electrochemical Decomposition of the Ionic Liquid 1-Butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide and Related Electrolytes
    ChemElectroChem, 6, 3009-3019 (2019)
    DOI: 10.1002/celc.201900371

  17. A.M. Abdel-Mageed, A. Klyushin,  A. Knop-Gericke, R. Schlögl, and R.J. Behm
    The Influence of CO on the Activation, O-Vacancy Formation and Performance of Au/ZnO Catalysts in CO2 Hydrogenation to Methanol
    J. Phys. Chem. Lett., 10, 3645-3653 (2019)
    DOI: 10.1021/acs.jpclett.9b00925

  18. Bi. Qin, T. Diemant, H. Zhang, A. Hoefling, R.J. Behm, J. Tübke, A. Varzi, and S. Passerini
    Revisiting the Electrochemical Lithiation Mechanism of Aluminum and the Role of Li -rich Phases (Li1+xAl) on Capacity Fading
    ChemSusChem, 12, 2609-2619 (2019)
    DOI: 10.1002/cssc.201900597

  19. M.A. Cambaz, B.P. Vinayan, H. Geßwein, A. Schiele, A. Sarapulova, T. Diemant, A. Mazilkin, T. Brezesinski, R.J. Behm, H. Ehrenberg, and M. Fichtner
    Oxygen activity in Li-rich disordered rock-salt oxide and influence of LiNbO3 surface modification on the electrochemical performance
    Chem. Mater., 31, 4330-4340 (2019)
    DOI: 10.1021/acs.chemmater.8b04504

  20. A.M. Abdel-Mageed, A. Klyushin, A. Rezvani, A. Knop-Gericke, R. Schlögl, and R.J. Behm
    Negative Charging of Au Nanoparticles during Methanol Synthesis from CO2 / H2 on a Au/ZnO Catalyst: Insights from Operando Infrared and Near-ambient Pressure XPS and XAS
    Angew. Chem., 131, 10431-10436 (2019)
    Angew. Chem. Int. Ed., 58, 10325-10329 (2019)
    DOI: 10.1002/ange.201900150
    DOI: 10.1002/anie.201900150

  21. S. Chen, A.M. Abdel-Mageed, D. Li, J. Bansmann, S. Cisneros, J. Biskupek, W. Huang, and R.J. Behm
    Morphology-Engineered Highly Active and Stable Ru/TiO2 Catalysts for Selective CO Methanation
    Angew. Chem., 131, 10842-10847 (2019)
    Angew. Chem. Int. Ed., 58, 10732-10736 (2019)
    DOI: 10.1002/ange.201903882
    DOI: 10.1002/anie.201903882

  22. K. Wiese, A.M. Abdel-Mageed, A. Klyushin, and R.J. Behm
    Dynamic Changes of Au/ZnO Catalysts during Methanol Synthesis:  A Model Study by Temporal Analysis of Products (TAP) and Zn LIII Near Edge X-Ray Absorption Spectroscopy
    Catal. Today, 336, 193-202 (2019)
    DOI: 10.1016/j.cattod.2018.11.074

  23. F. Buchner,  K. Forster-Tonigold, J. Kim, J. Bansmann, A. Groß, and R.J. Behm
    Interaction between Li, Ultrathin Adsorbed Ionic Liquid Films and CoO(111) Thin Films: A Model Study of the Solid|Electrolyte Interphase Formation
    Chem. Mater., 31, 5537-5549 (2019)
    DOI: 10.1021/acs.chemmater.9b01253

  24. S.M. Lang, T.M. Bernhardt, J.M. Bakker, B. Yoon, and U. Landman
    Methanol C–O Bond Activation by Free Gold Clusters Probed via Infrared Photodissociation Spectroscopy
    Z. Phys. Chem., 233, 865-880 (2019)
    DOI: 10.1515/zpch-2018-1368

  25. Z. Li, B.P. Vinayan, S. Liu, T. Diemant, R. Klingeler, R.J. Behm, Z. Zhao-Karger, K. Wang, M. Fichtner, and C. Kübel
    Hetero-layered MoS2/C composites enabling ultrafast and durable Na storage
    Energy Storage Mater., 21, 115-123 (2019)
    DOI: 10.1016/j.ensm.2019.05.042

  26. J. Bansmann, A.M. Abdel-Mageed, S. Chen, C. Fauth, T. Häring, G. Kučerová, Y. Wang, and R.J. Behm
    Chemical and Electronic Changes of the CeO2 Support During CO Oxidation on Au/CeO2 Catalysts: Time resolved Operando XAS at the Ce LIII Edge
    Catalysts, 9, 785 (2019)
    DOI: 10.3390/catal9100785

  27. I. Weber, J. Schnaidt, T. Diemant, B. Wang, and R.J. Behm
    Model Studies on the SEI Formation on Graphite Electrodes in Ethylene-and Dimethyl Carbonate Part I: Highly Ordered Pyrolytic Graphite
    ChemElectroChem, 6, 4985-4997 (2019)
    DOI: 10.1002/celc.201900909

  28. Y. Ma, Y. Ma, G.-T. Kim, T. Diemant, R.J. Behm, D. Geiger, U. Kaiser, A. Varzi, and S. Passerini
    Superior Lithium Storage Capacity of α‐MnS Nanoparticles Embedded in S‐Doped Carbonaceous Mesoporous Frameworks
    Adv. Ener. Mater., 1902077 (2019)
    DOI:  10.1002/aenm.201902077

  29. J. Kim, I. Weber, F. Buchner, J. Schnaidt, and R.J. Behm
    Surface Chemistry and Electrochemistry of an Ionic Liquid and Lithium on Li4Ti5O12(111) – A Model Study of the Anode|Electrolyte Interface
    J. Chem. Phys., 151, 134704 (2019)
    DOI: 10.1063/1.5119765

  30. S.M. Lang, T.M. Bernhardt, J.M. Bakker, B. Yoon, and U. Landman
    Co-adsorption of O2 and C2H4 on a Free Gold Dimer Probed via Infrared Photodissociation Spectroscopy
    J. Am. Soc. Mass Spectrom., 30, 1895–1905 (2019)
    DOI: 10.1007/s13361-019-02259-7

in press

  1. B. P. Vinayan, H. Euchner, Z. Zhao-Karger, T. Diemant , Z. Li, R.J. Behm, A. Gross, and M. Fichtner
    Insights into the electrochemical processes of rechargeable Magnesium-Sulfur batteries with new cathode design
    J. Chem. Mater. A, in press (2019)
    DOI: 10.1039/C9TA09155F

  2. Z. Jusys and R.J. Behm
    The Effect of Anions and pH on the Activity and Selectivity of an Annealed Polycrystalline Au Film Electrode in the Oxygen Reduction Reaction - Revisited
    ChemPhysChem, in press (2019)
    DOI: 10.1002/cphc.201900960

  3. L. Eifert, Z. Jusys, R.J. Behm, and R. Zeis
    Side Reactions and Stability of Pre-treated Carbon Felt Electrodes for Vanadium Redox Flow Batteries: A DEMS study
    Carbon, in press  (2019)
    DOI: 10.1016/j.carbon.2019.11.029

submitted

  1. M. Wassner, M. Eckardt, A. Reyer, T. Diemant, M.S. Elsaesser, R.J. Behm, and N. Hüsing
    Synthesis of amorphous and graphitized porous nitrogen doped carbon spheres as oxygen reduction reaction catalysts
    submitted (2018)
    2018_CN spheres

  2. A.M. Abdel-Mageed, M. Parlinska-Wojtan, K. Wiese, A. Hauble, and R.J. Behm
    Controlling the Selectivity in CO2  Reduction on Highly Active Ru/TiO2 Catalysts: Interplay of Phase Changes and Metal –Support Interactions
    submitted (2019)
    2019_CO2 Methanation-RWGS_RuTiO2

  3. J. Klein, V. Chesnyak, M. Löw, M. Schilling, A.K. Engstfeld, and R.J. Behm
    Selective Modification and Probing of the Electrocatalytic Activity of Step Sites
    submitted (2019)
    2019_KLEI18-COOx on Au-Pt-Pt(111)

  4. S. Cisneros, S. Chen, T. Diemant, A.M. Abdel-Mageed, M. Goepel, S.E. Olesen, E.S. Welter, R. Gläser, I. Chorkendorff, and R.J. Behm
    Tuning the Metal-Support Interactions in High-Surface-Area Ru/TiO2 Catalysts via SiO2-Doping
    submitted (2019)
    2019_Si-doping-SelMeth

  5. D. Alwast, J. Schnaidt, Z. Jusys, and R.J. Behm
    Ionic Liquid Electrolytes for Metal-Air Batteries: Interactions between O2 , Zn2+, and H2O Impurities
    submitted (2019)
    2019_Alwast_IL_Electrolytes

  6. J. Klein, A.K. Engstfeld, S. Brimaud, and R.J. Behm
    Pt nanocluster size effects in the hydrogen evolution reaction:  Approaching the theoretical maximum activity
    submitted (2019)
    2019_HER cluster size effects

  7. Y. Ma, Y. Ma, G. Giuli, H. Euchner, A. Groß, G. Orazio Lepore, F. d'Acapito, D. Geiger, U. Kaiser, T. Diemant, R.J. Behm, M. Kuenzel, S. Passerini, and D. Bresser
    Introducing highly redox-active atomic centers into insertion-type electrodes for lithium-ion batteries
    submitted (2019)
    2019_CeFeO_Li

  8. Y. Ma, Y. Ma, T. Diemant, K. Cao, U. Kaiser, T. Diemant, R.J. Behm, A. Varzi, and S. Passerini
    Heterostructured α-MnS/MnO/S-doped C Porous Micro-Rod Composite for High-performance Anodes in Lithium-Ion Batteries
    submitted (2019)
    2019_MnS-MnO-SCPF

  9. A. Rezvani, A.M. Abdel-Mageed, T. Ishida, T. Murayama, M. Parlinska-Wojtan, and R.J. Behm
    CO2  Reduction to Methanol on Au/CeO2  Catalysts: Mechanistic Insights from De-Activation and SSITKA Measurements
    submitted (2019)
    2019_AuCeO2_MeOH_SSITKA

  10. A.M. Abdel-Mageed, K. Wiese, M. Parlinska-Wojtan, and R.J. Behm
    Encapsulation of Ru Nanoparticles: Modifying the Reactivity Toward CO and CO2 Methanation on Highly Active Ru/TiO2 Catalysts
    submitted (2019)
    2019_Encapsulation_SMSI