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y(bution)k(in)g(a)g(\015ux)g(from)f(a)h(Kn)n(udsen)f(cell)h(held)g (at)g Fi(T)34 b Ft(=)23 b(1360)14 b(K.)-150 4894 y(The)31 b(p)r(opulations)f(in)h(the)g(vibrational)f(ground)f(state)i(are)f(de-) -150 4989 y(termined)40 b(from)g(the)g(\015uorescence)f(signals)g(and)h (the)g(kno)n(wn)-150 5085 y(excitation)52 b(probabilities)g(\(H\177)-42 b(onl-London)52 b(faktor,)58 b(F)-7 b(ranc)n(k-)-150 5180 y(Condon)33 b(faktor\).)55 b(Since)34 b(the)g(rotational)e(states) h(are)g(prob)r(ed)-150 5276 y(via)k(di\013eren)n(t)h(vibronic)f(bands)h (of)g(the)g Fi(B)1241 5246 y Fm(1)1278 5276 y Ft(\006)j Fk( )f Fi(X)1578 5246 y Fm(1)1614 5276 y Ft(\006)e(tran-)2060 1343 y @beginspecial 1 @llx 1 @lly 842 @urx 595 @ury 1700 @rhi @setspecial %%BeginDocument: Lifmessung.prn /defineresource where{pop}{userdict begin/defineresource{userdict/Resources 2 copy known{get begin}{15 dict dup begin put}ifelse exch readonly exch currentdict 1 index known not{dup 30 dict def}if load 3 -1 roll 2 index put end}bind readonly def/findresource{userdict/Resources get exch get exch get} bind readonly def/resourceforall{pop pop pop pop}bind readonly def /resourcestatus{userdict/Resources 2 copy known{get exch 2 copy known{get exch known{0 -1 true}{pop pop false}ifelse}{pop pop pop false}ifelse}{pop pop false }ifelse}bind readonly def end}ifelse /Pscript_Win_Driver 200 dict dup begin /FatalErrorIf{{initgraphics findfont exch scalefont setfont counttomark 3 div cvi{moveto show}repeat showpage quit}{cleartomark}ifelse}bind def /VM? {vmstatus exch sub exch pop gt { [ (Der Auftrag erfordert mehr Speicher als im Drucker verfügbar ist.) 100 500 (Gehen Sie wie folgt vor, und wiederholen Sie den Vorgang:) 100 485 (Klicken Sie auf Optimale Portierung im Dialogfeld PostScript.) 115 470 (Überprüfen Sie im Dialogfeld Geräteoptionen, ob der verfügbare Druckerspeicher richtig angegeben ist.) 115 455 (Verringern Sie die Anzahl der Schriftarten im Dokument.) 115 440 (Drucken Sie das Dokument seitenweise.) 115 425 12 /Times-Roman showpage (%%[ PrinterError: Low Printer VM ]%%) = true FatalErrorIf}if} bind def /|/def load def/,/load load |/~/exch , |/?/ifelse , |/!/pop , |/`/begin , |/^ /index , |/@/dup , |/+/translate , |/$/roll , |/U/userdict , |/M/moveto , |/- /rlineto , |/&/currentdict , |/:/gsave , |/;/grestore , |/F/false , |/T/true , |/N/newpath , |/E/end , |/Ac/arc , |/An/arcn , |/A/ashow , |/D/awidthshow , | /C/closepath , |/V/div , |/O/eofill , |/L/fill , |/I/lineto , |/-C/rcurveto , |/-M/rmoveto , |/+S/scale , |/Ji/setfont , |/Lc/setlinecap , |/Lj/setlinejoin , |/Lw/setlinewidth , |/S/show , |/LH/showpage , |/K/stroke , |/W/widthshow , |/R/rotate , |/b{bind |}bind |/bd{bind |}bind |/xd{~ |}bd/ld{, |}bd/lw/Lw ld /lc/Lc ld/lj/Lj ld/sg/setgray ld/L2? F/languagelevel where{! languagelevel 2 ge{! T}if}if |/g{@ not{U/DefIf_save save put}if U/DefIf_bool 2 ^ put}b /DefIf_El{if U/DefIf_bool get not @{U/DefIf_save get restore}if}b/e{DefIf_El ! }b/self & |/reinitialize{[/TextInit/GraphInit/UtilsInit counttomark{@ where{ self eq}{F}?{cvx exec}{!}?}repeat cleartomark}b/initialize{`{/ADO_mxRot ~ | /TextInitialised? F | reinitialize E}{U/Pscript_Win_Data 200 dict @ ` put /ADO_mxRot ~ |/TextInitialised? F | reinitialize}?}b/terminate{!{& self eq{ exit}{E}?}loop E}b/suspend/terminate , |/resume{` Pscript_Win_Data `}b/snap{ transform 0.25 sub round 0.25 add ~ 0.25 sub round 0.25 add ~ itransform}b /dsnap{dtransform round ~ round ~ idtransform}b<04>cvn{}|/setjn{{statusdict /jobname known{statusdict/jobname 3 -1 $ put}if}stopped cleartomark}b/solid{[] 0 setdash}b/setdsh{0 setdash}b/colspRefresh{}b/rp{4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/rr{1 ^ 0 - 0 ~ - neg 0 - C}b L2? not g{/rf{N rp L}b/fx{1 1 dtransform @ 0 ge{1 sub 1}{1 add -0.25}? 3 -1 $ @ 0 ge{1 sub 1}{1 add -0.25}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{ 4 -2 $ snap + +S fx rf}b/rs{N rp C K}b/rc{N rp clip N}b/sg{setgray}b/sco{ setrgbcolor}b/sgco{{sg}{sco}?}b}e L2? g{/colspA/DeviceGray |/colspABC/DeviceRGB |/setAorABC{{colspA}{colspABC}? setcolorspace}b/rf/rectfill , |/fx{1 1 dtransform @ 0 ge{1 sub 0.5}{1 add -0.5 }? 3 -1 $ @ 0 ge{1 sub 0.5}{1 add -0.5}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{4 -2 $ snap + +S fx rf}b/rs/rectstroke , |/rc/rectclip , |/sg {@ @ setcolor}b/sco{setcolor}b/colspRefresh{colspABC setcolorspace}b/sgco{{sg }{sco}?}b/UtilsInit{F setglobal}b/definecolorrendering{/ColorRendering defineresource !}b/findcolorrendering{@/ColorRendering resourcestatus{! ! /ColorRendering findresource T}{! F}?}b/selectcolorrendering{@/ColorRendering resourcestatus{! !/ColorRendering}{!/DefaultColorRendering/ColorRendering}? findresource setcolorrendering}b}e /bullets{{/bullet}repeat}b/ANSIEncoding[/grave/acute/circumflex/tilde/macron /breve/dotaccent/dieresis/ring/cedilla/hungarumlaut/ogonek/caron/dotlessi 18 bullets StandardEncoding 32 95 getinterval aload ! 3 bullets/quotesinglbase /florin/quotedblbase/ellipsis/dagger/daggerdbl/circumflex/perthousand/Scaron /guilsinglleft/OE 4 bullets/quoteleft/quoteright/quotedblleft/quotedblright /bullet/endash/emdash/tilde/trademark/scaron/guilsinglright/oe 2 bullets /Ydieresis/space/exclamdown/cent/sterling/currency/yen/brokenbar/section /dieresis/copyright/ordfeminine/guillemotleft/logicalnot/hyphen/registered /macron/degree/plusminus/twosuperior/threesuperior/acute/mu/paragraph /periodcentered/cedilla/onesuperior/ordmasculine/guillemotright/onequarter /onehalf/threequarters/questiondown/Agrave/Aacute/Acircumflex/Atilde/Adieresis /Aring/AE/Ccedilla/Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute /Icircumflex/Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute/Thorn/germandbls /agrave/aacute/acircumflex/atilde/adieresis/aring/ae/ccedilla/egrave/eacute /ecircumflex/edieresis/igrave/iacute/icircumflex/idieresis/eth/ntilde/ograve /oacute/ocircumflex/otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex /udieresis/yacute/thorn/ydieresis]| ANSIEncoding @ 39/quotesingle put 96/grave put/ANSIEncodingOld ANSIEncoding 256 array copy | ANSIEncodingOld @[138 153 154 169 172 174 177 178 179 181 185 188 189 190 208 215 221 222 240 247 253 254]{/bullet put @}forall 166/bar put 176/ring put /TextInit{TextInitialised? not{/Pscript_Windows_Font & |/TextInitialised? T | /fM[1 0 0 -1 0 0]|/mFM matrix |/iMat[1 0 0.212557 neg 1 0 0]|}if}b/xUP null | /yUP null |/uW null |/xSP null |/ySP null |/sW null |/copyfont{1 ^ length add dict `{1 ^/FID ne{|}{! !}?}forall & E}b/rF{3 copyfont @ `/Encoding ANSIEncoding &/CharStrings known{CharStrings/Eth known not{! ANSIEncodingOld} if}if | E}b/mF{findfont ~{@/Encoding get @ StandardEncoding eq{! T}{{ ISOLatin1Encoding}stopped{! F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{rF}{3 copyfont}? ` /OrigFontType ~ |/OrigFontName ~ | & E 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/xF{scalefont Pscript_Windows_Font 3 1 $ put}b/xMF{mFM astore makefont Pscript_Windows_Font 3 1 $ put}b/xF2/scalefont , |/xMF2{mFM astore makefont}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/sSU{N/uW ~ |/yUP ~ |/xUP ~ |}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ |/ySP ~ |/xSP ~ |}b/sT{xSP ySP sW sLT}b/sR{: + R 0 0 M}b /sRxy{: matrix astore concat 0 0 M}b/eR/; , | /mBF{@ 4 copyfont `/FontName ~ |/OrigFontType ~ |/OrigFontName ~ | 0 FontMatrix idtransform ! &/PaintType known{PaintType 0 eq{/PaintType 2 | /StrokeWidth ~ |}{PaintType 1 eq PaintType 2 eq or PaintType 3 eq or & /StrokeWidth known and{StrokeWidth add/StrokeWidth ~ |}{!}?}?}{!}? @ & E definefont Pscript_Windows_Font 3 1 $ put}b/xBF{Pscript_Windows_Font ` 1 ^ /FontName get 1 ^ scalefont 3 1 $ scalefont 2 copy ~ | ~ ! | E}b/xMBF{mFM astore Pscript_Windows_Font ` 1 ^/FontName get 1 ^ makefont 3 1 $ makefont 2 copy ~ | ~ ! | E}b/xBF2{/sB0 ~ mBF/sB1 sB0 3 -1 $ xBF sB1}b/xMBF2{/sB0 ~ mBF mFM astore/sB1 sB0 3 -1 $ xMBF sB1}b/sB{: Pscript_Windows_Font currentfont get Ji @ S ; S}b/asB{: Pscript_Windows_Font currentfont get Ji 3 copy A ; A}b/wsB{ : Pscript_Windows_Font currentfont get Ji 4 copy W ; W}b/awsB{: Pscript_Windows_Font currentfont get Ji 6 copy D ; D}b/sBT3{: @ S ; 1 1 -M S}b /asBT3{: 3 copy A ; 1 1 -M A}b/wsBT3{: 4 copy W ; 1 1 -M W}b/awsBT3{: 6 copy D ; 1 1 -M D}b/mIF{iMat 4 3 -1 $ put 2 copyfont `/OrigFontType ~ |/OrigFontName ~ | @ & E definefont iMat makefont Pscript_Windows_Font 3 1 $ put}b /SavedCTM null |/CTMsave{/SavedCTM SavedCTM currentmatrix |}b/CTMrestore{ SavedCTM setmatrix}b/mp null |/ADO_mxRot null |/GDIHMatrix null | /GDIHPatternDict 22 dict | GDIHPatternDict `/PatternType 1 |/PaintType 2 | /Reps L2?{1}{5}? |/XStep 8 Reps mul |/YStep XStep |/BBox[0 0 XStep YStep]| /TilingType 1 |/PaintProc{` 1 Lw[]0 setdash PaintData , exec E}b/FGnd null | /BGnd null |/HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b /HS_BDiagonal{biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? |/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b/vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag {Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E /makehatch{GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0/HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{ /h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5/HS_DiagCross makehatch}b/GDIBWPatternDict 17 dict @ `/PatternType 1 |/PaintType L2?{1}{2}? |/RepsV L2?{1}{6}? |/RepsH L2?{1}{5}? |/BBox[0 0 RepsH 1]|/TilingType 1 | /XStep 1 |/YStep 1 |/Height 8 RepsV mul |/Width 8 |/mx[Width 0 0 Height neg 0 Height]|/FGnd null |/BGnd null |/SetBGndFGnd L2?{{BGnd null ne{BGnd aload ! sgco BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! sgco}if} }{{}}? b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E |/GDIBWPatternMx null |/pfprep{save 4 1 $ /PatternOfTheDay 4 1 $ GDIBWPatternDict `/PaintData ~ |/BGnd ~ |/FGnd ~ | E CTMsave GDIBWPatternMx setmatrix GDIBWPatternDict matrix mp CTMrestore ~ !}b /hrf null |/prf{pfprep ~ 6 1 $ 5 hrf restore}b/GraphInit{GDIHMatrix null eq{ /SavedCTM matrix | : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly | ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E dsnap +S/GDIBWPatternMx matrix currentmatrix readonly | ; ;}if}b/cirp{360 0 An C}b/ellp{CTMsave + +S 0.5 0 M 0 0 0.5 360 0 An C CTMrestore}b/rrp{/rad ~ |/y2 ~ |/x2 ~ |/y1 ~ |/x1 ~ | x2 x1 add 2 V y1 M x1 y1 x1 y2 rad arct x1 y2 x2 y2 rad arct x2 y2 x2 y1 rad arct x2 y1 x1 y1 rad arct C}b/RRp{CTMsave + +S/dyS ~ |/dxS ~ | dxS 2 V 0 M 0 0 0 dyS 0.5 arct 0 dyS dxS dyS 0.5 arct dxS dyS dxS 0 0.5 arct dxS 0 0 0 0.5 arct C CTMrestore}b L2? not g{/arct{arcto ! ! ! !}b/GDIpattfill{@ ` BGnd null ne PaintType 2 eq and{: BGnd aload ! sgco fEOFill{O}{L}? ; FGnd aload ! U/fGray 2 ^ put{2}{4}? -1 $}if E @ patterncalc : 4 ^/PaintType get 2 eq{fGray{6 -1 $ sg}{8 -3 $ sco}? }if fEOFill{eoclip}{clip}? N patternfill ; N}b/hrf{/fGray 1 ^ 6 eq | -4 $ N rp C/fEOFill F | GDIpattfill}b/hfMain{/fEOFill ~ |/fGray ~ | GDIpattfill}b/hf{T hfMain}b/hfW{F hfMain}b/hs{currentpoint strokepath M hfW}b/pfMain{/fEOFill ~ | pfprep GDIpattfill restore N}b/pf{T pfMain}b/pfW{F pfMain}b/ps{currentpoint strokepath M pfW}b/mpstr 1 string |/mp{~ @ length 12 add dict copy ` /PatternCTM matrix currentmatrix |/PatternMatrix ~ |/PatWidth XStep mpstr length mul |/PatHeight YStep |/FontType 3 |/Encoding 256 array | 3 string 0 1 255{Encoding ~ @ 3 ^ cvs cvn put}for !/FontMatrix matrix |/FontBBox BBox | /BuildChar{! @ ` XStep 0 FontBBox aload ! setcachedevice/PaintProc , E : exec ;}b & E ~ @ 3 -1 $ definefont}b/patterncalc{` : PatternCTM setmatrix PatternMatrix concat BBox aload ! ! ! + pathbbox ; PatHeight V ceiling 4 1 $ PatWidth V ceiling 4 1 $ PatHeight V floor 4 1 $ PatWidth V floor 4 1 $ 2 ^ sub cvi abs ~ 3 ^ sub cvi abs ~ 4 2 $ PatHeight mul ~ PatWidth mul ~ E}b /patternfill{5 -1 $ @ ` Ji PatternCTM setmatrix PatternMatrix concat 0 2 ^ 2 ^ M 0 1 mpstr length 1 sub{1 ^ mpstr 3 1 $ put}for ! 2 ^{currentpoint 5 ^{mpstr S}repeat YStep add M}repeat ! ! ! ! E}b}e L2? g{/mp/makepattern , |/hrf{6 eq setAorABC setpattern rectfill}b/hf{ setAorABC setpattern O}b/hfW{setAorABC setpattern L}b/hs{setAorABC setpattern K}b/pf{pfprep setpattern O restore N}b/pfW{pfprep setpattern L restore N}b/ps{ pfprep setpattern K restore N}b}e /iw 0 |/ih 0 |/im_save 0 |/s 0 |/polarity 0 |/smoothflag 0 |/mystring 0 |/bpc 0 |/setup1asciiproc{[currentfile mystring/readhexstring cvx/! cvx]cvx bind}b /setup1binaryproc{[currentfile mystring/readstring cvx/! cvx]cvx bind}b /setup2asciiproc{currentfile/ASCII85Decode filter/RunLengthDecode filter}b /setup2binaryproc{currentfile/RunLengthDecode filter}b/mycolorspace{colspABC}| /myimagedict{/myimagedict 10 dict | myimagedict @ `/ImageType 1 | /MultipleDataSource F | E}b/imageprocarray[/setup1binaryproc/setup1asciiproc /setup2binaryproc/setup2asciiproc/setup1binarydecodeproc/setup1asciidecodeproc ]|/L2Polarity{{[1 0]}{[0 1]}?}b/Q{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/X{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/Z{im_save restore}b/Y{sgco myimagedict @ ` /Width iw |/Height ih |/Decode polarity |/ImageMatrix[iw 0 0 ih 0 0]| /DataSource s |/BitsPerComponent 1 |/Interpolate smoothflag | E imagemask}b L2? not g{/setup2asciiproc{[/Level2ImagesError , aload ! T FatalErrorIf}b /setup2binaryproc/setup2asciiproc , |/L2Polarity{}|/Y{sgco iw ih polarity[iw 0 0 ih 0 0]s imagemask}b}e L2? not g{/testsystemdict{where{systemdict eq{T}{F}?}{F}?}b/c 1 |/colorimage where{! T}{F}?{/c 0 statusdict `/processcolors where{! ! processcolors}{ /deviceinfo where{! deviceinfo/Colors known{!{deviceinfo/Colors get}}if}if}? E | c 0 ne{/colorimage testsystemdict/setcolortransfer testsystemdict /currentcolortransfer testsystemdict/currentcmykcolor testsystemdict and and and not{/c 0 |}if}if}if c @ 1 ne ~ @ 3 ne ~ 4 ne and and{/c 0 |}if c 1 eq g{ /expandbw{expandfactor mul round cvi bwclut ~ get 255 V}b/doclutimage{!/bwclut ~ | bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/expandfactor ~ |[/expandbw ,/exec , @ currenttransfer ~]cvx bind settransfer iw ih bpc[iw 0 0 ih 0 0]s image}b}e c @ 3 eq ~ 4 eq or g{/nullproc{{}}|/concatutil{/exec , 7 -1 $/exec ,}b/defsubclut{ 1 add getinterval |}b/spconcattransfer{/Dclut ~ |/Cclut ~ |/Bclut ~ |/Aclut ~ |/ncompute ~ , | currentcolortransfer[{Aclut ncompute}concatutil]cvx[{Bclut ncompute}concatutil]cvx[{Cclut ncompute}concatutil]cvx[{Dclut ncompute} concatutil]cvx setcolortransfer}b/setuprgbcluts{/bit3x rgbclut length 3 sub | /bit1x bit3x 3 idiv |/rclut rgbclut |/gclut rclut 1 bit3x defsubclut/bclut rclut 2 bit3x defsubclut}b}e c 3 eq g{/3compute{~ bit3x mul round cvi get 255 V}b/doclutimage{/rgbclut ~ | ! setuprgbcluts/3compute rclut gclut bclut @ spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @]cvx nullproc nullproc T 3 colorimage}b}e c 4 eq g{/ftoint{1 ~ sub 255 mul round cvi}b/stuffclut{ cmykindex 3 -1 $ put}b/4compute{~ bit4x mul round cvi get 255 V}b /invalidcolortable? T |/computecmykclut{setuprgbcluts/bit4x rgbclut length 3 idiv 4 mul 4 sub |/cmykclut bit4x 4 add string |/cclut cmykclut |/mclut cclut 1 bit4x defsubclut/yclut cclut 2 bit4x defsubclut/kclut cclut 3 bit4x defsubclut/cmykindex 0 | 0 1 bit1x{@/cmykindex ~ bit1x ~ sub 4 mul | 3 mul @ rclut ~ get 255 V ~ @ gclut ~ get 255 V ~ bclut ~ get 255 V setrgbcolor currentcmykcolor ftoint kclut stuffclut ftoint yclut stuffclut ftoint mclut stuffclut ftoint cclut stuffclut}for}b/doclutimage{/rgbclut ~ | ! invalidcolortable?{computecmykclut}if/4compute cclut mclut yclut kclut spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @ @]cvx nullproc nullproc nullproc T 4 colorimage}b}e c 0 eq g{/a{3 mul 3 getinterval putinterval ~ 3 add ~ 3 copy}b/8lookup/a , |/4lookup{/byte 1 ^ | -4 bitshift a byte 15 and a}b/2lookup{/byte 1 ^ | -6 bitshift a byte -4 bitshift 3 and a byte -2 bitshift 3 and a byte 3 and a}b/colorexpand{mystringexp 0 rgbclut 3 copy 7 -1 $/mylookup , forall ! ! ! ! !}b/createexpandstr{/mystringexp ~ mystring length mul string |}b/doclutimage{/rgbclut ~ | !/mylookup bpc 8 eq{3 createexpandstr/8lookup}{bpc 4 eq{6 createexpandstr/4lookup}{12 createexpandstr/2lookup}?}? , | iw ih bpc[iw 0 0 ih 0 0][s/exec ,/colorexpand ,/exec ,]cvx F 3 colorimage}b}e/colorimage where{! T}{F}? g{/do24image{iw ih 8 [iw 0 0 ih 0 0]s F 3 colorimage}b}DefIf_El{/rgbtogray{/str ~ |/len str length |/smlen len 3 idiv |/rstr str |/gstr str 1 len 1 sub getinterval |/bstr str 2 len 2 sub getinterval | str @ 0 1 smlen 1 sub{@ 3 mul rstr 1 ^ get 0.3 mul gstr 2 ^ get 0.59 mul add bstr 3 -1 $ get 0.11 mul add round cvi put @}for ! 0 smlen getinterval}b/do24image{iw ih 8[iw 0 0 ih 0 0][s/exec ,/rgbtogray ,/exec ,]cvx bind image}b}e/doNimage{bpc 24 eq{do24image}{iw ih bpc[iw 0 0 ih 0 0]s image}?}b}e L2? g{/doclutimage{/rgbclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[ /Indexed colspABC hival rgbclut]setcolorspace myimagedict @ `/Width iw | /Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s | /BitsPerComponent bpc |/Interpolate smoothflag | E image}b/doCMYKclutimage{ /CMYKclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[/Indexed/DeviceCMYK hival CMYKclut]setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc | /Interpolate smoothflag | E image}b/doNimage{bpc 24 eq{colspABC}{colspA}? setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode bpc 24 eq{[0 1 0 1 0 1]}{[0 1]}? |/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc 24 eq{8}{bpc}? |/Interpolate smoothflag | E image}b/doCMYKimage{ /DeviceCMYK setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 1 0 1 0 1 0 1]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent 8 | /Interpolate smoothflag | E image}b}e /GreNewFont{10 dict @ 3 1 $ | @ ` 4 1 $/FontType 3 |/FontMatrix ~ |/FontBBox ~ |/Encoding 256 array | 0 1 255{Encoding ~/.notdef put}for/CharProcs 257 dict | CharProcs/.notdef{}put/Metrics 257 dict | Metrics/.notdef 3 -1 $ put/BuildChar {/char ~ |/fontdict ~ |/charname fontdict/Encoding get char get | fontdict /Metrics get charname get aload ! setcachedevice fontdict ` Encoding char get CharProcs ~ get E exec}| E definefont !}|/AddChar{` Encoding 3 1 $ put CharProcs 3 1 $ put Metrics 3 1 $ put E}| /FEbuf 2 string |/FEglyph 3 string |/FE{(G00)FEglyph copy ! 1 ~{@ 16 lt{ /offset 2 store}{/offset 1 store}? @ 16 FEbuf cvrs FEglyph ~ offset ~ putinterval 1 ^ ~ FEglyph cvn put}for}bind |/Type1Hdr{11 dict `/FontName ~ | /PaintType ~ |/FontType 1 |/FontMatrix[1 3 ^ V 0 0 1 6 ^ V 0 0]| !/Encoding 256 array 0 1 255{1 ^ ~/.notdef put}for 3 ^ 3 ^ FE | ! !/FontBBox{0 0 0 0}| & E currentfile eexec}bind | /pp 1 string |/ss 1 string |/rledecodebinary{/DC 0 |/BC 0 |{DC mystring length ge{exit}if currentfile ss readstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{ mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/rledecodeascii{/DC 0 | /BC 0 |{DC mystring length ge{exit}if currentfile ss readhexstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readhexstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readhexstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/setup1asciidecodeproc{[/rledecodeascii cvx]cvx bind}b /setup1binarydecodeproc{[/rledecodebinary cvx]cvx bind}b userdict/Pscript_Win_Compat 13 dict dup begin/bd{bind def}bind def/ld{load def }bd/CB{pop pop pop pop}bind def/B{pop pop pop pop}bind def/$x matrix def/SS{ /pagesave save def}bind def/RS{/pagesave where{pop pagesave restore}{$x matrix invertmatrix concat}ifelse}bind def/ANSIVec[0/grave 1/acute 2/circumflex 3 /tilde 4/macron 5/breve 6/dotaccent 7/dieresis 8/ring 9/cedilla 10 /hungarumlaut 11/ogonek 12/caron 13/dotlessi 39/quotesingle 96/grave 124/bar 130/quotesinglbase 131/florin 132/quotedblbase 133/ellipsis 134/dagger 135 /daggerdbl 136/circumflex 137/perthousand 138/Scaron 139/guilsinglleft 140/OE 145/quoteleft 146/quoteright 147/quotedblleft 148/quotedblright 149/bullet 150 /endash 151/emdash 152/tilde 153/trademark 154/scaron 155/guilsinglright 156 /oe 159/Ydieresis 160/space 161/exclamdown 164/currency 165/yen 166/brokenbar 167/section 168/dieresis 169/copyright 170/ordfeminine 171/guillemotleft 172 /logicalnot 173/hyphen 174/registered 175/macron 176/degree 177/plusminus 178 /twosuperior 179/threesuperior 180/acute 181/mu 182/paragraph 183 /periodcentered 184/cedilla 185/onesuperior 186/ordmasculine 187 /guillemotright 188/onequarter 189/onehalf 190/threequarters 191/questiondown 192/Agrave 193/Aacute 194/Acircumflex 195/Atilde 196/Adieresis 197/Aring 198 /AE 199/Ccedilla 200/Egrave 201/Eacute 202/Ecircumflex 203/Edieresis 204 /Igrave 205/Iacute 206/Icircumflex 207/Idieresis 208/Eth 209/Ntilde 210/Ograve 211/Oacute 212/Ocircumflex 213/Otilde 214/Odieresis 215/multiply 216/Oslash 217/Ugrave 218/Uacute 219/Ucircumflex 220/Udieresis 221/Yacute 222/Thorn 223 /germandbls 224/agrave 225/aacute 226/acircumflex 227/atilde 228/adieresis 229 /aring 230/ae 231/ccedilla 232/egrave 233/eacute 234/ecircumflex 235/edieresis 236/igrave 237/iacute 238/icircumflex 239/idieresis 240/eth 241/ntilde 242 /ograve 243/oacute 244/ocircumflex 245/otilde 246/odieresis 247/divide 248 /oslash 249/ugrave 250/uacute 251/ucircumflex 252/udieresis 253/yacute 254 /thorn 255/ydieresis]def currentdict{dup type/operatortype eq{[exch]cvx def}{ pop pop}ifelse}forall/initialize{currentdict exch begin begin}bind def /terminate{/@FL where not{pop end end}{pop}ifelse}bind def/suspend/terminate load def/resume/initialize load def/M/moveto load def end put/Courier findfont 10 scalefont setfont end /ProcSet defineresource pop Pscript_Win_Compat dup /initialize get exec [ 0 1.000 -1.000 0 0 0 ] false /Pscript_Win_Driver /ProcSet findresource dup /initialize get exec /mysetup [ 0.120 0 0 -0.120 0.960 594.960 ] | userdict begin /pagesave save def end mysetup concat colspRefresh : 1.000 1.000 1.000 sco 0 0 4958 7016 rf ; 913 376 N M 5752 3747 rr 913 376 N M 5753 3748 rr 16 Lw 0 Lc 0 Lj solid 0 0 0 sco K 913 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(\(0{0\))g(to)h(\(3{0\))f(Lyman)g(bands)g(also)g(lines)g(of)-150 4767 y(vibrationally)32 b(excited)h(molecules)g(in)g(the)h(\(3{1\),)g (\(4{1\),)g(and)-150 4862 y(\(5{1\))k(bands)h(are)f(clearly)g(resolv)n (ed)f(and)i(iden)n(ti\014ed.)71 b(Rota-)-150 4958 y(tional)20 b(state)g(p)r(opulations)g(of)h Fi(J)859 4928 y Fh(00)924 4958 y Ft(=)i(0)d(to)h(12)e(in)i(the)g(vibrational)-150 5053 y(ground)30 b(state)g(and)g Fi(J)559 5023 y Fh(00)630 5053 y Ft(=)d(0)j(to)h(8)f(in)h(the)g(\014rst)f(excited)h(vibra-)-150 5149 y(tional)c(state)h(ha)n(v)n(e)f(b)r(een)h(measured.)36 b(In)28 b(this)g(exp)r(erimen)n(t)g(the)-150 5244 y(p)r(olarization)36 b(of)i(the)g(exciting)g(VUV)h(and)e(the)i(ionizing)e(UV)-150 5340 y(laser)24 b(b)r(eams)i(are)e(parallel)g(to)i(eac)n(h)e(other)h (and)g(parallel)g(to)g(the)1892 1343 y @beginspecial 9 @llx 12 @lly 822 @urx 586 @ury 1984 @rhi @setspecial %%BeginDocument: spektrum797_2.prn /defineresource where{pop}{userdict begin/defineresource{userdict/Resources 2 copy 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E | c 0 ne{/colorimage testsystemdict/setcolortransfer testsystemdict /currentcolortransfer testsystemdict/currentcmykcolor testsystemdict and and and not{/c 0 |}if}if}if c @ 1 ne ~ @ 3 ne ~ 4 ne and and{/c 0 |}if c 1 eq g{ /expandbw{expandfactor mul round cvi bwclut ~ get 255 V}b/doclutimage{!/bwclut ~ | bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/expandfactor ~ |[/expandbw ,/exec , @ currenttransfer ~]cvx bind settransfer iw ih bpc[iw 0 0 ih 0 0]s image}b}e c @ 3 eq ~ 4 eq or g{/nullproc{{}}|/concatutil{/exec , 7 -1 $/exec ,}b/defsubclut{ 1 add getinterval |}b/spconcattransfer{/Dclut ~ |/Cclut ~ |/Bclut ~ |/Aclut ~ |/ncompute ~ , | currentcolortransfer[{Aclut ncompute}concatutil]cvx[{Bclut ncompute}concatutil]cvx[{Cclut ncompute}concatutil]cvx[{Dclut ncompute} concatutil]cvx setcolortransfer}b/setuprgbcluts{/bit3x rgbclut length 3 sub | /bit1x bit3x 3 idiv |/rclut rgbclut |/gclut rclut 1 bit3x defsubclut/bclut rclut 2 bit3x defsubclut}b}e c 3 eq g{/3compute{~ bit3x mul round cvi get 255 V}b/doclutimage{/rgbclut ~ | ! setuprgbcluts/3compute rclut gclut bclut @ spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @]cvx nullproc nullproc T 3 colorimage}b}e c 4 eq g{/ftoint{1 ~ sub 255 mul round cvi}b/stuffclut{ cmykindex 3 -1 $ put}b/4compute{~ bit4x mul round cvi get 255 V}b /invalidcolortable? T |/computecmykclut{setuprgbcluts/bit4x rgbclut length 3 idiv 4 mul 4 sub |/cmykclut bit4x 4 add string |/cclut cmykclut |/mclut cclut 1 bit4x defsubclut/yclut cclut 2 bit4x defsubclut/kclut cclut 3 bit4x defsubclut/cmykindex 0 | 0 1 bit1x{@/cmykindex ~ bit1x ~ sub 4 mul | 3 mul @ rclut ~ get 255 V ~ @ gclut ~ get 255 V ~ bclut ~ get 255 V setrgbcolor currentcmykcolor ftoint kclut stuffclut ftoint yclut stuffclut ftoint mclut stuffclut ftoint cclut stuffclut}for}b/doclutimage{/rgbclut ~ | ! invalidcolortable?{computecmykclut}if/4compute cclut mclut yclut kclut spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @ @]cvx nullproc nullproc nullproc T 4 colorimage}b}e c 0 eq g{/a{3 mul 3 getinterval putinterval ~ 3 add ~ 3 copy}b/8lookup/a , |/4lookup{/byte 1 ^ | -4 bitshift a byte 15 and a}b/2lookup{/byte 1 ^ | -6 bitshift a byte -4 bitshift 3 and a byte -2 bitshift 3 and a byte 3 and a}b/colorexpand{mystringexp 0 rgbclut 3 copy 7 -1 $/mylookup , forall ! ! ! ! !}b/createexpandstr{/mystringexp ~ mystring length mul string |}b/doclutimage{/rgbclut ~ | !/mylookup bpc 8 eq{3 createexpandstr/8lookup}{bpc 4 eq{6 createexpandstr/4lookup}{12 createexpandstr/2lookup}?}? , | iw ih bpc[iw 0 0 ih 0 0][s/exec ,/colorexpand ,/exec ,]cvx F 3 colorimage}b}e/colorimage where{! T}{F}? g{/do24image{iw ih 8 [iw 0 0 ih 0 0]s F 3 colorimage}b}DefIf_El{/rgbtogray{/str ~ |/len str length |/smlen len 3 idiv |/rstr str |/gstr str 1 len 1 sub getinterval |/bstr str 2 len 2 sub getinterval | str @ 0 1 smlen 1 sub{@ 3 mul rstr 1 ^ get 0.3 mul gstr 2 ^ get 0.59 mul add bstr 3 -1 $ get 0.11 mul add round cvi put @}for ! 0 smlen getinterval}b/do24image{iw ih 8[iw 0 0 ih 0 0][s/exec ,/rgbtogray ,/exec ,]cvx bind image}b}e/doNimage{bpc 24 eq{do24image}{iw ih bpc[iw 0 0 ih 0 0]s image}?}b}e L2? g{/doclutimage{/rgbclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[ /Indexed colspABC hival rgbclut]setcolorspace myimagedict @ `/Width iw | /Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s | /BitsPerComponent bpc |/Interpolate smoothflag | E image}b/doCMYKclutimage{ /CMYKclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[/Indexed/DeviceCMYK hival CMYKclut]setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc | /Interpolate smoothflag | E image}b/doNimage{bpc 24 eq{colspABC}{colspA}? setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode bpc 24 eq{[0 1 0 1 0 1]}{[0 1]}? |/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc 24 eq{8}{bpc}? |/Interpolate smoothflag | E image}b/doCMYKimage{ /DeviceCMYK setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 1 0 1 0 1 0 1]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent 8 | /Interpolate smoothflag | E image}b}e /GreNewFont{10 dict @ 3 1 $ | @ ` 4 1 $/FontType 3 |/FontMatrix ~ |/FontBBox ~ |/Encoding 256 array | 0 1 255{Encoding ~/.notdef put}for/CharProcs 257 dict | CharProcs/.notdef{}put/Metrics 257 dict | Metrics/.notdef 3 -1 $ put/BuildChar {/char ~ |/fontdict ~ |/charname fontdict/Encoding get char get | fontdict /Metrics get charname get aload ! setcachedevice fontdict ` Encoding char get CharProcs ~ get E exec}| E definefont !}|/AddChar{` Encoding 3 1 $ put CharProcs 3 1 $ put Metrics 3 1 $ put E}| /FEbuf 2 string |/FEglyph 3 string |/FE{(G00)FEglyph copy ! 1 ~{@ 16 lt{ /offset 2 store}{/offset 1 store}? @ 16 FEbuf cvrs FEglyph ~ offset ~ putinterval 1 ^ ~ FEglyph cvn put}for}bind |/Type1Hdr{11 dict `/FontName ~ | /PaintType ~ |/FontType 1 |/FontMatrix[1 3 ^ V 0 0 1 6 ^ V 0 0]| !/Encoding 256 array 0 1 255{1 ^ ~/.notdef put}for 3 ^ 3 ^ FE | ! !/FontBBox{0 0 0 0}| & E currentfile eexec}bind | /pp 1 string |/ss 1 string |/rledecodebinary{/DC 0 |/BC 0 |{DC mystring length ge{exit}if currentfile ss readstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{ mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/rledecodeascii{/DC 0 | /BC 0 |{DC mystring length ge{exit}if currentfile ss readhexstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readhexstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readhexstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/setup1asciidecodeproc{[/rledecodeascii cvx]cvx bind}b /setup1binarydecodeproc{[/rledecodebinary cvx]cvx bind}b userdict/Pscript_Win_Compat 13 dict dup begin/bd{bind def}bind def/ld{load def }bd/CB{pop pop pop pop}bind def/B{pop pop pop pop}bind def/$x matrix def/SS{ /pagesave save def}bind def/RS{/pagesave where{pop pagesave restore}{$x matrix invertmatrix concat}ifelse}bind def/ANSIVec[0/grave 1/acute 2/circumflex 3 /tilde 4/macron 5/breve 6/dotaccent 7/dieresis 8/ring 9/cedilla 10 /hungarumlaut 11/ogonek 12/caron 13/dotlessi 39/quotesingle 96/grave 124/bar 130/quotesinglbase 131/florin 132/quotedblbase 133/ellipsis 134/dagger 135 /daggerdbl 136/circumflex 137/perthousand 138/Scaron 139/guilsinglleft 140/OE 145/quoteleft 146/quoteright 147/quotedblleft 148/quotedblright 149/bullet 150 /endash 151/emdash 152/tilde 153/trademark 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178 xF F0_178 Ji -90.000 469 3539 sR 2.726 0 (r)A 4.032 0 (e)A 1.484 0 (l)A 4.032 0 (a)A 1.516 0 (t)A 1.484 0 (i)A 4.000 0 (v)A -2.516 0 32 4.032 0 (e )D 1.484 0 (i)A 4.032 0 (n)A 1.516 0 (t)A 4.032 0 (en)A 4.000 0 (s)A 1.484 0 (i)A 1.516 0 (t)A -1.484 0 32 3.000 0 (y )D 1.516 0 ([)A 4.032 0 (a)A 2.726 0 (r)A 4.032 0 (b)A 1.516 0 (. )A 4.032 0 (un)A 1.484 0 (i)A 1.516 0 (t)A 4.000 0 (s)A 1.516 0 (])A eR ; : 2045 4420 4705 206 rc 0 0 0 sco F0_178 Ji 2543 4420 M 4.032 0 (e)A 3.000 0 (x)A 4.000 0 (c)A 1.484 0 (i)A 1.516 0 (t)A 4.032 0 (a)A 1.516 0 (t)A 1.484 0 (i)A -2.516 0 32 4.032 0 (on )D 5.484 0 (w)A 4.032 0 (a)A 4.000 0 (v)A 4.032 0 (e)A 1.484 0 (l)A 4.032 0 (eng)A 1.516 0 (t)A -2.516 0 32 4.032 0 (h )D 1.516 0 ([)A 4.032 0 (n)A 5.726 0 (m)A 1.516 0 (])A ; LH pagesave restore /Pscript_Win_Driver /ProcSet findresource dup /terminate get exec Pscript_Win_Compat dup /terminate get exec %%EndDocument @endspecial 2119 1486 a Fr(FIG.)i(2.)48 b(Resonan)n(tly)32 b(enhanced)h(VUV)e(laser)j(ionization)g(sp)r(ec-)2042 1577 y(trum)24 b(of)i(deuterium)f(desorbing)h(from)f(Pd\(100\),)i Fp(T)3578 1585 y Ff(S)3644 1577 y Fr(=)21 b(800)14 b(K.)2119 1830 y(T)-6 b(ABLE)26 b(I.)44 b(The)30 b(p)r(olarization)j(factor)e Fp(\037)f Fr(comp)r(ensates)h(the)f(de-)2042 1922 y(p)r(endence)e(of)i (the)f(excitation)h(probabilit)n(y)f(on)g(the)g(angle)h(b)r(et)n(w)n (een)2042 2013 y(the)f(p)r(olarization)j(of)f(the)e(exciting)h(laser)h (and)f(the)f(transition)i(mo-)2042 2104 y(men)n(t)24 b(of)i(the)g(molecule.)p 2042 2242 2043 4 v 2042 2262 V 2172 2343 a Fp(J)233 b Fr(1)95 b(2)144 b(3)194 b(4)f(5)g(6)g(7)h(8)p 2042 2374 V 2044 2437 a(P)26 b(branc)n(h)96 b(1)f(1)g(1.03)i(1.16)f (1.34)g(1.21)g(1.08)g(1.03)2042 2529 y(R)25 b(branc)n(h)94 b(1)h(1)g(1.01)i(1.07)f(1.16)g(1.12)g(1.05)g(1.02)p 2042 2667 V 2042 2687 V 2042 3053 a Ft(surface)37 b(normal.)68 b(F)-7 b(rom)38 b(sp)r(ectra)g(lik)n(e)g(sho)n(wn)f(in)i(\014g.)f(2)g (the)2042 3148 y(p)r(opulation)30 b Fi(N)9 b Ft(\()p Fi(v)2613 3118 y Fh(00)2679 3148 y Ft(=)23 b(0)o Fi(;)28 b(J)2913 3118 y Fh(00)2955 3148 y Ft(\))j(and)g Fi(N)9 b Ft(\()p Fi(v)3334 3118 y Fh(00)3400 3148 y Ft(=)22 b(1)p Fi(;)27 b(J)3633 3118 y Fh(00)3676 3148 y Ft(\))k(of)f(the)h(ro-) 2042 3244 y(tational)26 b(lev)n(els)g(in)g(the)h(vibrational)f(ground)f (state)i(and)f(in)h(the)2042 3339 y(\014rst)f(excited)h(state)f(can)g (b)r(e)h(obtained.)36 b(As)27 b(men)n(tioned)g(earlier)2042 3435 y(the)f(relativ)n(e)f(ionization)g(probabilit)n(y)g(of)h(eac)n(h)f (initial)i(ro)n(vibra-)2042 3530 y(tional)g(state)g(needs)h(to)f(b)r(e) h(considered.)2125 3626 y(F)-7 b(or)27 b(the)h(deriv)-5 b(ation)27 b(of)h(the)g(state)g(p)r(opulation)f(the)h(in)n(tegral)2042 3721 y(of)j(the)g(ionization)f(lines)h(is)g(considered.)46 b(The)31 b(relativ)n(e)f(p)r(opu-)2042 3816 y(lation)e Fi(N)9 b Ft(\()p Fi(v)2429 3786 y Fh(00)2472 3816 y Fi(;)14 b(J)2563 3786 y Fh(00)2605 3816 y Ft(\))29 b(of)g(the)f(ro)n (vibrational)e(initial)j(state)g(can)f(b)r(e)2042 3912 y(determined)g(from)f(this)h(in)n(tegral)e Fi(I)35 b Ft(b)n(y)2042 4140 y Fi(N)9 b Ft(\()p Fi(v)2193 4106 y Fh(00)2235 4140 y Fi(;)14 b(J)2326 4106 y Fh(00)2369 4140 y Ft(\))23 b Fk(/)g Fi(I)7 b(=)2611 4023 y Fa(\022)2671 4044 y(\014)2671 4094 y(\014)2671 4144 y(\014)2699 4140 y Fi(R)2763 4106 y Fl(n)2804 4080 y Fb(0)2826 4106 y Fl(n)2867 4080 y Fb(00)2762 4160 y Fl(e)2912 4044 y Fa(\014)2912 4094 y(\014)2912 4144 y(\014)2940 4065 y Fm(2)2991 4044 y Fa(\014)2991 4094 y(\014)2991 4144 y(\014)3019 4140 y Fi(R)3083 4106 y Fl(v)3118 4080 y Fb(0)3140 4106 y Fl(v)3175 4080 y Fb(00)3082 4160 y Fl(v)r(ib)3220 4044 y Fa(\014)3220 4094 y(\014)3220 4144 y(\014)3248 4065 y Fm(2)3299 4140 y Fi(S)3350 4152 y Fl(J)3392 4136 y Fb(0)3414 4152 y Fl(J)3456 4136 y Fb(00)3529 4140 y Fi(K)f Ft(\()p Fi(v)3681 4106 y Fh(0)3705 4140 y Fi(;)14 b(J)3796 4106 y Fh(0)3819 4140 y Ft(\))28 b Fi(\037)3931 4023 y Fa(\023)4055 4140 y Ft(\(2\))2042 4422 y(Here,)2259 4327 y Fa(\014)2259 4377 y(\014)2259 4427 y(\014)2287 4422 y Fi(R)2351 4392 y Fl(n)2392 4367 y Fb(0)2414 4392 y Fl(n)2455 4367 y Fb(00)2350 4443 y Fl(e)2500 4327 y Fa(\014)2500 4377 y(\014)2500 4427 y(\014)2528 4347 y Fm(2)2591 4422 y Ft(and)2750 4327 y Fa(\014)2750 4377 y(\014)2750 4427 y(\014)2778 4422 y Fi(R)2842 4392 y Fl(v)2877 4367 y Fb(0)2899 4392 y Fl(v)2934 4367 y Fb(00)2841 4446 y Fl(v)r(ib)2979 4327 y Fa(\014)2979 4377 y(\014)2979 4427 y(\014)3007 4347 y Fm(2)3070 4422 y Ft(denote)d(the)h(electronic)f (transi-)2042 4542 y(tion)c(momen)n(t)g(and)g(the)g(F)-7 b(ranc)n(k-Condon)19 b(factor,)j(resp)r(ectiv)n(ely)-7 b(,)2042 4638 y(and)35 b Fi(S)2262 4650 y Fl(J)2304 4634 y Fb(0)2326 4650 y Fl(J)2368 4634 y Fb(00)2449 4638 y Ft(describ)r(es)f(the)i(H\177)-42 b(onl-London)34 b(factor.)58 b Fi(K)6 b Ft(\()p Fi(v)3914 4608 y Fh(0)3938 4638 y Fi(;)14 b(J)4029 4608 y Fh(0)4052 4638 y Ft(\))2042 4733 y(tak)n(es)31 b(the)h(relativ)n(e)f(detection)h(sensitivit)n(y)g(as)g (determined)g(in)2042 4829 y(the)i(previous)e(section)h(in)n(to)g (accoun)n(t.)53 b(The)34 b(in\015uence)f(of)h(the)2042 4924 y(rotational)27 b(alignmen)n(t)i(of)g(desorbing)e(molecules)i(is)f (describ)r(ed)2042 5020 y(b)n(y)g(the)i(p)r(olarization)d(factor)h Fi(\037)p Ft(.)41 b(This)29 b(factor)f Fi(\037)h Ft(comp)r(ensates)2042 5115 y(for)37 b(aligned)g(molecules)h(the)g(dep)r(endence)h(of)e(the)i (excitation)2042 5211 y(probabilit)n(y)27 b(on)i(the)g(angle)f(b)r(et)n (w)n(een)g(the)h(transition)f(momen)n(t)2042 5306 y(and)f(the)h(p)r (olarization)e(of)i(the)g(exciting)f(laser.)1946 5608 y(4)p eop %%Page: 5 5 5 4 bop -216 1343 a @beginspecial 1 @llx 1 @lly 842 @urx 595 @ury 1842 @rhi @setspecial %%BeginDocument: Rotpopulation-797K.prn /defineresource where{pop}{userdict begin/defineresource{userdict/Resources 2 copy known{get begin}{15 dict dup begin put}ifelse exch readonly exch currentdict 1 index known not{dup 30 dict def}if load 3 -1 roll 2 index put end}bind readonly def/findresource{userdict/Resources get exch get exch get} bind readonly def/resourceforall{pop pop pop pop}bind readonly def /resourcestatus{userdict/Resources 2 copy known{get exch 2 copy known{get exch known{0 -1 true}{pop pop false}ifelse}{pop pop pop false}ifelse}{pop pop false }ifelse}bind readonly def end}ifelse /Pscript_Win_Driver 200 dict dup begin /FatalErrorIf{{initgraphics findfont exch scalefont setfont counttomark 3 div cvi{moveto show}repeat showpage quit}{cleartomark}ifelse}bind def /VM? {vmstatus exch sub exch pop gt { [ (Der Auftrag erfordert mehr Speicher als im Drucker verfügbar ist.) 100 500 (Gehen Sie wie folgt vor, und wiederholen Sie den Vorgang:) 100 485 (Klicken Sie auf Optimale Portierung im Dialogfeld PostScript.) 115 470 (Überprüfen Sie im Dialogfeld Geräteoptionen, ob der verfügbare Druckerspeicher richtig angegeben ist.) 115 455 (Verringern Sie die Anzahl der Schriftarten im Dokument.) 115 440 (Drucken Sie das Dokument seitenweise.) 115 425 12 /Times-Roman showpage (%%[ PrinterError: Low Printer VM ]%%) = true FatalErrorIf}if} bind def /|/def load def/,/load load |/~/exch , |/?/ifelse , |/!/pop , |/`/begin , |/^ /index , |/@/dup , |/+/translate , |/$/roll , |/U/userdict , |/M/moveto , |/- /rlineto , |/&/currentdict , |/:/gsave , |/;/grestore , |/F/false , |/T/true , |/N/newpath , |/E/end , |/Ac/arc , |/An/arcn , |/A/ashow , |/D/awidthshow , | /C/closepath , |/V/div , |/O/eofill , |/L/fill , |/I/lineto , |/-C/rcurveto , |/-M/rmoveto , |/+S/scale , |/Ji/setfont , |/Lc/setlinecap , |/Lj/setlinejoin , |/Lw/setlinewidth , |/S/show , |/LH/showpage , |/K/stroke , |/W/widthshow , |/R/rotate , |/b{bind |}bind |/bd{bind |}bind |/xd{~ |}bd/ld{, |}bd/lw/Lw ld /lc/Lc ld/lj/Lj ld/sg/setgray ld/L2? F/languagelevel where{! languagelevel 2 ge{! T}if}if |/g{@ not{U/DefIf_save save put}if U/DefIf_bool 2 ^ put}b /DefIf_El{if U/DefIf_bool get not @{U/DefIf_save get restore}if}b/e{DefIf_El ! }b/self & |/reinitialize{[/TextInit/GraphInit/UtilsInit counttomark{@ where{ self eq}{F}?{cvx exec}{!}?}repeat cleartomark}b/initialize{`{/ADO_mxRot ~ | /TextInitialised? F | reinitialize E}{U/Pscript_Win_Data 200 dict @ ` put /ADO_mxRot ~ |/TextInitialised? F | reinitialize}?}b/terminate{!{& self eq{ exit}{E}?}loop E}b/suspend/terminate , |/resume{` Pscript_Win_Data `}b/snap{ transform 0.25 sub round 0.25 add ~ 0.25 sub round 0.25 add ~ itransform}b /dsnap{dtransform round ~ round ~ idtransform}b<04>cvn{}|/setjn{{statusdict /jobname known{statusdict/jobname 3 -1 $ put}if}stopped cleartomark}b/solid{[] 0 setdash}b/setdsh{0 setdash}b/colspRefresh{}b/rp{4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/rr{1 ^ 0 - 0 ~ - neg 0 - C}b L2? not g{/rf{N rp L}b/fx{1 1 dtransform @ 0 ge{1 sub 1}{1 add -0.25}? 3 -1 $ @ 0 ge{1 sub 1}{1 add -0.25}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{ 4 -2 $ snap + +S fx rf}b/rs{N rp C K}b/rc{N rp clip N}b/sg{setgray}b/sco{ setrgbcolor}b/sgco{{sg}{sco}?}b}e L2? g{/colspA/DeviceGray |/colspABC/DeviceRGB |/setAorABC{{colspA}{colspABC}? setcolorspace}b/rf/rectfill , |/fx{1 1 dtransform @ 0 ge{1 sub 0.5}{1 add -0.5 }? 3 -1 $ @ 0 ge{1 sub 0.5}{1 add -0.5}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{4 -2 $ snap + +S fx rf}b/rs/rectstroke , |/rc/rectclip , |/sg {@ @ setcolor}b/sco{setcolor}b/colspRefresh{colspABC setcolorspace}b/sgco{{sg }{sco}?}b/UtilsInit{F setglobal}b/definecolorrendering{/ColorRendering defineresource !}b/findcolorrendering{@/ColorRendering resourcestatus{! ! /ColorRendering findresource T}{! F}?}b/selectcolorrendering{@/ColorRendering resourcestatus{! !/ColorRendering}{!/DefaultColorRendering/ColorRendering}? findresource setcolorrendering}b}e /bullets{{/bullet}repeat}b/ANSIEncoding[/grave/acute/circumflex/tilde/macron /breve/dotaccent/dieresis/ring/cedilla/hungarumlaut/ogonek/caron/dotlessi 18 bullets StandardEncoding 32 95 getinterval aload ! 3 bullets/quotesinglbase /florin/quotedblbase/ellipsis/dagger/daggerdbl/circumflex/perthousand/Scaron /guilsinglleft/OE 4 bullets/quoteleft/quoteright/quotedblleft/quotedblright /bullet/endash/emdash/tilde/trademark/scaron/guilsinglright/oe 2 bullets /Ydieresis/space/exclamdown/cent/sterling/currency/yen/brokenbar/section /dieresis/copyright/ordfeminine/guillemotleft/logicalnot/hyphen/registered /macron/degree/plusminus/twosuperior/threesuperior/acute/mu/paragraph /periodcentered/cedilla/onesuperior/ordmasculine/guillemotright/onequarter /onehalf/threequarters/questiondown/Agrave/Aacute/Acircumflex/Atilde/Adieresis /Aring/AE/Ccedilla/Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute /Icircumflex/Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute/Thorn/germandbls /agrave/aacute/acircumflex/atilde/adieresis/aring/ae/ccedilla/egrave/eacute /ecircumflex/edieresis/igrave/iacute/icircumflex/idieresis/eth/ntilde/ograve /oacute/ocircumflex/otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex /udieresis/yacute/thorn/ydieresis]| ANSIEncoding @ 39/quotesingle put 96/grave put/ANSIEncodingOld ANSIEncoding 256 array copy | ANSIEncodingOld @[138 153 154 169 172 174 177 178 179 181 185 188 189 190 208 215 221 222 240 247 253 254]{/bullet put @}forall 166/bar put 176/ring put /TextInit{TextInitialised? not{/Pscript_Windows_Font & |/TextInitialised? T | /fM[1 0 0 -1 0 0]|/mFM matrix |/iMat[1 0 0.212557 neg 1 0 0]|}if}b/xUP null | /yUP null |/uW null |/xSP null |/ySP null |/sW null |/copyfont{1 ^ length add dict `{1 ^/FID ne{|}{! !}?}forall & E}b/rF{3 copyfont @ `/Encoding ANSIEncoding &/CharStrings known{CharStrings/Eth known not{! ANSIEncodingOld} if}if | E}b/mF{findfont ~{@/Encoding get @ StandardEncoding eq{! T}{{ ISOLatin1Encoding}stopped{! F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{rF}{3 copyfont}? ` /OrigFontType ~ |/OrigFontName ~ | & E 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/xF{scalefont Pscript_Windows_Font 3 1 $ put}b/xMF{mFM astore makefont Pscript_Windows_Font 3 1 $ put}b/xF2/scalefont , |/xMF2{mFM astore makefont}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/sSU{N/uW ~ |/yUP ~ |/xUP ~ |}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ |/ySP ~ |/xSP ~ |}b/sT{xSP ySP sW sLT}b/sR{: + R 0 0 M}b /sRxy{: matrix astore concat 0 0 M}b/eR/; , | /mBF{@ 4 copyfont `/FontName ~ |/OrigFontType ~ |/OrigFontName ~ | 0 FontMatrix idtransform ! &/PaintType known{PaintType 0 eq{/PaintType 2 | /StrokeWidth ~ |}{PaintType 1 eq PaintType 2 eq or PaintType 3 eq or & /StrokeWidth known and{StrokeWidth add/StrokeWidth ~ |}{!}?}?}{!}? @ & E definefont Pscript_Windows_Font 3 1 $ put}b/xBF{Pscript_Windows_Font ` 1 ^ /FontName get 1 ^ scalefont 3 1 $ scalefont 2 copy ~ | ~ ! | E}b/xMBF{mFM astore Pscript_Windows_Font ` 1 ^/FontName get 1 ^ makefont 3 1 $ makefont 2 copy ~ | ~ ! | E}b/xBF2{/sB0 ~ mBF/sB1 sB0 3 -1 $ xBF sB1}b/xMBF2{/sB0 ~ mBF mFM astore/sB1 sB0 3 -1 $ xMBF sB1}b/sB{: Pscript_Windows_Font currentfont get Ji @ S ; S}b/asB{: Pscript_Windows_Font currentfont get Ji 3 copy A ; A}b/wsB{ : Pscript_Windows_Font currentfont get Ji 4 copy W ; W}b/awsB{: Pscript_Windows_Font currentfont get Ji 6 copy D ; D}b/sBT3{: @ S ; 1 1 -M S}b /asBT3{: 3 copy A ; 1 1 -M A}b/wsBT3{: 4 copy W ; 1 1 -M W}b/awsBT3{: 6 copy D ; 1 1 -M D}b/mIF{iMat 4 3 -1 $ put 2 copyfont `/OrigFontType ~ |/OrigFontName ~ | @ & E definefont iMat makefont Pscript_Windows_Font 3 1 $ put}b /SavedCTM null |/CTMsave{/SavedCTM SavedCTM currentmatrix |}b/CTMrestore{ SavedCTM setmatrix}b/mp null |/ADO_mxRot null |/GDIHMatrix null | /GDIHPatternDict 22 dict | GDIHPatternDict `/PatternType 1 |/PaintType 2 | /Reps L2?{1}{5}? |/XStep 8 Reps mul |/YStep XStep |/BBox[0 0 XStep YStep]| /TilingType 1 |/PaintProc{` 1 Lw[]0 setdash PaintData , exec E}b/FGnd null | /BGnd null |/HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b /HS_BDiagonal{biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? |/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b/vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag {Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E /makehatch{GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0/HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{ /h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5/HS_DiagCross makehatch}b/GDIBWPatternDict 17 dict @ `/PatternType 1 |/PaintType L2?{1}{2}? |/RepsV L2?{1}{6}? |/RepsH L2?{1}{5}? |/BBox[0 0 RepsH 1]|/TilingType 1 | /XStep 1 |/YStep 1 |/Height 8 RepsV mul |/Width 8 |/mx[Width 0 0 Height neg 0 Height]|/FGnd null |/BGnd null |/SetBGndFGnd L2?{{BGnd null ne{BGnd aload ! sgco BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! sgco}if} }{{}}? b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E |/GDIBWPatternMx null |/pfprep{save 4 1 $ /PatternOfTheDay 4 1 $ GDIBWPatternDict `/PaintData ~ |/BGnd ~ |/FGnd ~ | E CTMsave GDIBWPatternMx setmatrix GDIBWPatternDict matrix mp CTMrestore ~ !}b /hrf null |/prf{pfprep ~ 6 1 $ 5 hrf restore}b/GraphInit{GDIHMatrix null eq{ /SavedCTM matrix | : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly | ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E dsnap +S/GDIBWPatternMx matrix currentmatrix readonly | ; ;}if}b/cirp{360 0 An C}b/ellp{CTMsave + +S 0.5 0 M 0 0 0.5 360 0 An C CTMrestore}b/rrp{/rad ~ |/y2 ~ |/x2 ~ |/y1 ~ |/x1 ~ | x2 x1 add 2 V y1 M x1 y1 x1 y2 rad arct x1 y2 x2 y2 rad arct x2 y2 x2 y1 rad arct x2 y1 x1 y1 rad arct C}b/RRp{CTMsave + +S/dyS ~ |/dxS ~ | dxS 2 V 0 M 0 0 0 dyS 0.5 arct 0 dyS dxS dyS 0.5 arct dxS dyS dxS 0 0.5 arct dxS 0 0 0 0.5 arct C CTMrestore}b L2? not g{/arct{arcto ! ! ! !}b/GDIpattfill{@ ` BGnd null ne PaintType 2 eq and{: BGnd aload ! sgco fEOFill{O}{L}? ; FGnd aload ! U/fGray 2 ^ put{2}{4}? -1 $}if E @ patterncalc : 4 ^/PaintType get 2 eq{fGray{6 -1 $ sg}{8 -3 $ sco}? }if fEOFill{eoclip}{clip}? N patternfill ; N}b/hrf{/fGray 1 ^ 6 eq | -4 $ N rp C/fEOFill F | GDIpattfill}b/hfMain{/fEOFill ~ |/fGray ~ | GDIpattfill}b/hf{T hfMain}b/hfW{F hfMain}b/hs{currentpoint strokepath M hfW}b/pfMain{/fEOFill ~ | pfprep GDIpattfill restore N}b/pf{T pfMain}b/pfW{F pfMain}b/ps{currentpoint strokepath M pfW}b/mpstr 1 string |/mp{~ @ length 12 add dict copy ` /PatternCTM matrix currentmatrix |/PatternMatrix ~ |/PatWidth XStep mpstr length mul |/PatHeight YStep |/FontType 3 |/Encoding 256 array | 3 string 0 1 255{Encoding ~ @ 3 ^ cvs cvn put}for !/FontMatrix matrix |/FontBBox BBox | /BuildChar{! @ ` XStep 0 FontBBox aload ! setcachedevice/PaintProc , E : exec ;}b & E ~ @ 3 -1 $ definefont}b/patterncalc{` : PatternCTM setmatrix PatternMatrix concat BBox aload ! ! ! + pathbbox ; PatHeight V ceiling 4 1 $ PatWidth V ceiling 4 1 $ PatHeight V floor 4 1 $ PatWidth V floor 4 1 $ 2 ^ sub cvi abs ~ 3 ^ sub cvi abs ~ 4 2 $ PatHeight mul ~ PatWidth mul ~ E}b /patternfill{5 -1 $ @ ` Ji PatternCTM setmatrix PatternMatrix concat 0 2 ^ 2 ^ M 0 1 mpstr length 1 sub{1 ^ mpstr 3 1 $ put}for ! 2 ^{currentpoint 5 ^{mpstr S}repeat YStep add M}repeat ! ! ! ! E}b}e L2? g{/mp/makepattern , |/hrf{6 eq setAorABC setpattern rectfill}b/hf{ setAorABC setpattern O}b/hfW{setAorABC setpattern L}b/hs{setAorABC setpattern K}b/pf{pfprep setpattern O restore N}b/pfW{pfprep setpattern L restore N}b/ps{ pfprep setpattern K restore N}b}e /iw 0 |/ih 0 |/im_save 0 |/s 0 |/polarity 0 |/smoothflag 0 |/mystring 0 |/bpc 0 |/setup1asciiproc{[currentfile mystring/readhexstring cvx/! cvx]cvx bind}b /setup1binaryproc{[currentfile mystring/readstring cvx/! cvx]cvx bind}b /setup2asciiproc{currentfile/ASCII85Decode filter/RunLengthDecode filter}b /setup2binaryproc{currentfile/RunLengthDecode filter}b/mycolorspace{colspABC}| /myimagedict{/myimagedict 10 dict | myimagedict @ `/ImageType 1 | /MultipleDataSource F | E}b/imageprocarray[/setup1binaryproc/setup1asciiproc /setup2binaryproc/setup2asciiproc/setup1binarydecodeproc/setup1asciidecodeproc ]|/L2Polarity{{[1 0]}{[0 1]}?}b/Q{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/X{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/Z{im_save restore}b/Y{sgco myimagedict @ ` /Width iw |/Height ih |/Decode polarity |/ImageMatrix[iw 0 0 ih 0 0]| /DataSource s |/BitsPerComponent 1 |/Interpolate smoothflag | E imagemask}b L2? not g{/setup2asciiproc{[/Level2ImagesError , aload ! T FatalErrorIf}b /setup2binaryproc/setup2asciiproc , |/L2Polarity{}|/Y{sgco iw ih polarity[iw 0 0 ih 0 0]s imagemask}b}e L2? not g{/testsystemdict{where{systemdict eq{T}{F}?}{F}?}b/c 1 |/colorimage where{! T}{F}?{/c 0 statusdict `/processcolors where{! ! processcolors}{ /deviceinfo where{! deviceinfo/Colors known{!{deviceinfo/Colors get}}if}if}? E | c 0 ne{/colorimage testsystemdict/setcolortransfer testsystemdict /currentcolortransfer testsystemdict/currentcmykcolor testsystemdict and and and not{/c 0 |}if}if}if c @ 1 ne ~ @ 3 ne ~ 4 ne and and{/c 0 |}if c 1 eq g{ /expandbw{expandfactor mul round cvi bwclut ~ get 255 V}b/doclutimage{!/bwclut ~ | bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/expandfactor ~ |[/expandbw ,/exec , @ currenttransfer ~]cvx bind settransfer iw ih bpc[iw 0 0 ih 0 0]s image}b}e c @ 3 eq ~ 4 eq or g{/nullproc{{}}|/concatutil{/exec , 7 -1 $/exec ,}b/defsubclut{ 1 add getinterval |}b/spconcattransfer{/Dclut ~ |/Cclut ~ |/Bclut ~ |/Aclut ~ |/ncompute ~ , | currentcolortransfer[{Aclut ncompute}concatutil]cvx[{Bclut ncompute}concatutil]cvx[{Cclut ncompute}concatutil]cvx[{Dclut ncompute} concatutil]cvx setcolortransfer}b/setuprgbcluts{/bit3x rgbclut length 3 sub | /bit1x bit3x 3 idiv |/rclut rgbclut |/gclut rclut 1 bit3x defsubclut/bclut rclut 2 bit3x defsubclut}b}e c 3 eq g{/3compute{~ bit3x mul round cvi get 255 V}b/doclutimage{/rgbclut ~ | ! setuprgbcluts/3compute rclut gclut bclut @ spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @]cvx nullproc nullproc T 3 colorimage}b}e c 4 eq g{/ftoint{1 ~ sub 255 mul round cvi}b/stuffclut{ cmykindex 3 -1 $ put}b/4compute{~ bit4x mul round cvi get 255 V}b /invalidcolortable? T |/computecmykclut{setuprgbcluts/bit4x rgbclut length 3 idiv 4 mul 4 sub |/cmykclut bit4x 4 add string |/cclut cmykclut |/mclut cclut 1 bit4x defsubclut/yclut cclut 2 bit4x defsubclut/kclut cclut 3 bit4x defsubclut/cmykindex 0 | 0 1 bit1x{@/cmykindex ~ bit1x ~ sub 4 mul | 3 mul @ rclut ~ get 255 V ~ @ gclut ~ get 255 V ~ bclut ~ get 255 V setrgbcolor currentcmykcolor ftoint kclut stuffclut ftoint yclut stuffclut ftoint mclut stuffclut ftoint cclut stuffclut}for}b/doclutimage{/rgbclut ~ | ! invalidcolortable?{computecmykclut}if/4compute cclut mclut yclut kclut spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @ @]cvx nullproc nullproc nullproc T 4 colorimage}b}e c 0 eq g{/a{3 mul 3 getinterval putinterval ~ 3 add ~ 3 copy}b/8lookup/a , |/4lookup{/byte 1 ^ | -4 bitshift a byte 15 and a}b/2lookup{/byte 1 ^ | -6 bitshift a byte -4 bitshift 3 and a byte -2 bitshift 3 and a byte 3 and a}b/colorexpand{mystringexp 0 rgbclut 3 copy 7 -1 $/mylookup , forall ! ! ! ! !}b/createexpandstr{/mystringexp ~ mystring length mul string |}b/doclutimage{/rgbclut ~ | !/mylookup bpc 8 eq{3 createexpandstr/8lookup}{bpc 4 eq{6 createexpandstr/4lookup}{12 createexpandstr/2lookup}?}? , | iw ih bpc[iw 0 0 ih 0 0][s/exec ,/colorexpand ,/exec ,]cvx F 3 colorimage}b}e/colorimage where{! T}{F}? g{/do24image{iw ih 8 [iw 0 0 ih 0 0]s F 3 colorimage}b}DefIf_El{/rgbtogray{/str ~ |/len str length |/smlen len 3 idiv |/rstr str |/gstr str 1 len 1 sub getinterval |/bstr str 2 len 2 sub getinterval | str @ 0 1 smlen 1 sub{@ 3 mul rstr 1 ^ get 0.3 mul gstr 2 ^ get 0.59 mul add bstr 3 -1 $ get 0.11 mul add round cvi put @}for ! 0 smlen getinterval}b/do24image{iw ih 8[iw 0 0 ih 0 0][s/exec ,/rgbtogray ,/exec ,]cvx bind image}b}e/doNimage{bpc 24 eq{do24image}{iw ih bpc[iw 0 0 ih 0 0]s image}?}b}e L2? g{/doclutimage{/rgbclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[ /Indexed colspABC hival rgbclut]setcolorspace myimagedict @ `/Width iw | /Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s | /BitsPerComponent bpc |/Interpolate smoothflag | E image}b/doCMYKclutimage{ /CMYKclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[/Indexed/DeviceCMYK hival CMYKclut]setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc | /Interpolate smoothflag | E image}b/doNimage{bpc 24 eq{colspABC}{colspA}? setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode bpc 24 eq{[0 1 0 1 0 1]}{[0 1]}? |/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc 24 eq{8}{bpc}? |/Interpolate smoothflag | E image}b/doCMYKimage{ /DeviceCMYK setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 1 0 1 0 1 0 1]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent 8 | /Interpolate smoothflag | E image}b}e /GreNewFont{10 dict @ 3 1 $ | @ ` 4 1 $/FontType 3 |/FontMatrix ~ |/FontBBox ~ |/Encoding 256 array | 0 1 255{Encoding ~/.notdef put}for/CharProcs 257 dict | CharProcs/.notdef{}put/Metrics 257 dict | Metrics/.notdef 3 -1 $ put/BuildChar {/char ~ |/fontdict ~ |/charname fontdict/Encoding get char get | fontdict /Metrics get charname get aload ! setcachedevice fontdict ` Encoding char get CharProcs ~ get E exec}| E definefont !}|/AddChar{` Encoding 3 1 $ put CharProcs 3 1 $ put Metrics 3 1 $ put E}| /FEbuf 2 string |/FEglyph 3 string |/FE{(G00)FEglyph copy ! 1 ~{@ 16 lt{ /offset 2 store}{/offset 1 store}? @ 16 FEbuf cvrs FEglyph ~ offset ~ putinterval 1 ^ ~ FEglyph cvn put}for}bind |/Type1Hdr{11 dict `/FontName ~ | /PaintType ~ |/FontType 1 |/FontMatrix[1 3 ^ V 0 0 1 6 ^ V 0 0]| !/Encoding 256 array 0 1 255{1 ^ ~/.notdef put}for 3 ^ 3 ^ FE | ! !/FontBBox{0 0 0 0}| & E currentfile eexec}bind | /pp 1 string |/ss 1 string |/rledecodebinary{/DC 0 |/BC 0 |{DC mystring length ge{exit}if currentfile ss readstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{ mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/rledecodeascii{/DC 0 | /BC 0 |{DC mystring length ge{exit}if currentfile ss readhexstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readhexstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readhexstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/setup1asciidecodeproc{[/rledecodeascii cvx]cvx bind}b /setup1binarydecodeproc{[/rledecodebinary cvx]cvx bind}b userdict/Pscript_Win_Compat 13 dict dup begin/bd{bind def}bind def/ld{load def }bd/CB{pop pop pop pop}bind def/B{pop pop pop pop}bind def/$x matrix def/SS{ /pagesave save def}bind def/RS{/pagesave where{pop pagesave restore}{$x matrix invertmatrix concat}ifelse}bind def/ANSIVec[0/grave 1/acute 2/circumflex 3 /tilde 4/macron 5/breve 6/dotaccent 7/dieresis 8/ring 9/cedilla 10 /hungarumlaut 11/ogonek 12/caron 13/dotlessi 39/quotesingle 96/grave 124/bar 130/quotesinglbase 131/florin 132/quotedblbase 133/ellipsis 134/dagger 135 /daggerdbl 136/circumflex 137/perthousand 138/Scaron 139/guilsinglleft 140/OE 145/quoteleft 146/quoteright 147/quotedblleft 148/quotedblright 149/bullet 150 /endash 151/emdash 152/tilde 153/trademark 154/scaron 155/guilsinglright 156 /oe 159/Ydieresis 160/space 161/exclamdown 164/currency 165/yen 166/brokenbar 167/section 168/dieresis 169/copyright 170/ordfeminine 171/guillemotleft 172 /logicalnot 173/hyphen 174/registered 175/macron 176/degree 177/plusminus 178 /twosuperior 179/threesuperior 180/acute 181/mu 182/paragraph 183 /periodcentered 184/cedilla 185/onesuperior 186/ordmasculine 187 /guillemotright 188/onequarter 189/onehalf 190/threequarters 191/questiondown 192/Agrave 193/Aacute 194/Acircumflex 195/Atilde 196/Adieresis 197/Aring 198 /AE 199/Ccedilla 200/Egrave 201/Eacute 202/Ecircumflex 203/Edieresis 204 /Igrave 205/Iacute 206/Icircumflex 207/Idieresis 208/Eth 209/Ntilde 210/Ograve 211/Oacute 212/Ocircumflex 213/Otilde 214/Odieresis 215/multiply 216/Oslash 217/Ugrave 218/Uacute 219/Ucircumflex 220/Udieresis 221/Yacute 222/Thorn 223 /germandbls 224/agrave 225/aacute 226/acircumflex 227/atilde 228/adieresis 229 /aring 230/ae 231/ccedilla 232/egrave 233/eacute 234/ecircumflex 235/edieresis 236/igrave 237/iacute 238/icircumflex 239/idieresis 240/eth 241/ntilde 242 /ograve 243/oacute 244/ocircumflex 245/otilde 246/odieresis 247/divide 248 /oslash 249/ugrave 250/uacute 251/ucircumflex 252/udieresis 253/yacute 254 /thorn 255/ydieresis]def currentdict{dup type/operatortype eq{[exch]cvx def}{ pop pop}ifelse}forall/initialize{currentdict exch begin begin}bind def /terminate{/@FL where not{pop end end}{pop}ifelse}bind def/suspend/terminate load def/resume/initialize load def/M/moveto load def end put/Courier findfont 10 scalefont setfont end /ProcSet defineresource pop Pscript_Win_Compat dup /initialize get exec [ 0 1.000 -1.000 0 0 0 ] false /Pscript_Win_Driver /ProcSet findresource dup /initialize get exec /mysetup [ 0.120 0 0 -0.120 0.960 594.960 ] | userdict begin /pagesave save def end mysetup concat colspRefresh : 1.000 1.000 1.000 sco 0 0 4958 7016 rf ; 887 641 N M 5813 3537 rr 887 641 N M 5814 3538 rr 16 Lw 0 Lc 0 Lj solid 0 0 0 sco K 887 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Fp(T)1474 1585 y Ff(S)1571 1577 y Fr(=)52 b(800)14 b(K.)-150 1668 y(Filled)39 b(squares)f(denote)g(molecules)h(in)f(\()p Fp(v)1154 1637 y Fo(00)1236 1668 y Fr(=)k(0\))c(and)g(triangles)-150 1760 y(in)30 b(\()p Fp(v)14 1728 y Fo(00)82 1760 y Fr(=)e(1\).)46 b(Also)30 b(theoretical)h(v)l(alues)f(for)g(H)1278 1768 y Fq(2)1342 1760 y Fr(molecules)g(in)g(the)-150 1851 y(states)25 b Fp(v)107 1819 y Fo(00)169 1851 y Fr(=)c(0)j(and)g Fp(v)500 1819 y Fo(00)562 1851 y Fr(=)d(1,)k(resp)r(ectiv)n(ely)-6 b(,)25 b(are)g(sho)n(wn)f(\(op)r(en)g(sym-)-150 1942 y(b)r(ols\).)-67 2210 y Ft(In)30 b(order)f(to)h(deriv)n(e)g(state)g(p)r (opulations)g(the)g(in)n(tensit)n(y)g Fi(I)35 b Ft(=)-150 2306 y(\()p Fi(I)-82 2321 y Fh(k)-18 2306 y Ft(+)24 b Fi(I)107 2318 y Fh(?)164 2306 y Ft(\))p Fi(=)p Ft(2)37 b(has)g(to)g(b)r(e)h(kno)n(wn.)65 b(Here)37 b Fi(I)1275 2321 y Fh(k)1351 2306 y Ft(and)h Fi(I)1559 2318 y Fh(?)1652 2306 y Ft(denote)-150 2401 y(ion)e(in)n(tensities)g(for)g(the)g(p)r (olarization)f(of)h(the)h(exciting)f(laser)-150 2497 y(b)r(eing)g(parallel)f(and)g(p)r(erp)r(endicular)h(to)f(the)h(surface) f(normal)-146 2592 y(^)-46 b Fi(n)p Ft(,)27 b(resp)r(ectiv)n(ely)-7 b(.)36 b(In)27 b(the)g(presen)n(t)f(exp)r(erimen)n(t)h(ion)f(in)n (tensities)-150 2688 y Fi(I)-114 2703 y Fh(k)-48 2688 y Ft(are)h(measured.)36 b Fi(I)529 2700 y Fh(?)613 2688 y Ft(can)27 b(b)r(e)h(related)f(to)h Fi(I)1293 2703 y Fh(k)1359 2688 y Ft(b)n(y)527 2921 y Fi(I)563 2933 y Fh(?)642 2921 y Ft(=)23 b Fi(I)766 2936 y Fh(k)842 2865 y Ft(1)18 b Fk(\000)g Fi(P)p 842 2902 208 4 v 842 2978 a Ft(1)g(+)g Fi(P)1786 2921 y Ft(\(3\))-150 3134 y(where)23 b Fi(P)36 b Ft(denotes)23 b(the)h(anisotrop)n(y)-7 b(.)34 b Fi(P)h Ft(can)23 b(b)r(e)h(obtained)g(from)-150 3245 y(the)g(quadrup)r(ole)g(alignmen)n(t)f(factor)g Fi(A)1097 3202 y Fm(\(2\))1097 3267 y(0)1211 3245 y Ft(whic)n(h)h(has)f(b)r(een)i (de-)-150 3341 y(termined)j(in)g(an)f(earlier)g(exp)r(erimen)n(t)1072 3311 y Fm(47)1142 3341 y Ft(.)37 b(The)28 b(correction)e(fac-)-150 3436 y(tor)h Fi(\037)h Ft(is)f(th)n(us)h(giv)n(en)f(b)n(y)598 3653 y Fi(\037)c Ft(=)854 3597 y(1)p 771 3634 V 771 3710 a(1)18 b(+)g Fi(P)1786 3653 y Ft(\(4\))-150 3866 y(The)23 b(alignmen)n(t)f(of)h(the)g(molecules)f(a\013ects)g(the)i(in)n(tensit)n (y)e(mea-)-150 3962 y(suremen)n(ts)28 b(for)g(the)h(same)f Fi(J)777 3932 y Fh(00)849 3962 y Ft(via)g(the)h(P-)f(and)h(R-branc)n(h) e(dif-)-150 4057 y(feren)n(tly)-7 b(,)26 b(b)r(ecause)f(the)h (connection)g(b)r(et)n(w)n(een)f(the)h(quadrup)r(ole)-150 4168 y(alignmen)n(t)48 b(factor)f Fi(A)576 4125 y Fm(\(2\))576 4190 y(0)713 4168 y Ft(and)h(the)h(anisotrop)n(y)d Fi(P)60 b Ft(dep)r(ends)-150 4264 y(also)29 b(on)h(the)h(transition)635 4234 y Fm(48)705 4264 y Ft(.)45 b(The)31 b(appropriate)d(v)-5 b(alues)30 b(for)g(the)-150 4359 y(anisotrop)n(y)24 b(factors)h Fi(P)37 b Ft(for)26 b(di\013eren)n(t)g(rotational)e(states)h(as)h(de-) -150 4470 y(riv)n(ed)35 b(from)f(measured)h(alignmen)n(t)g(v)-5 b(alues)35 b Fi(A)1357 4427 y Fm(\(2\))1357 4493 y(0)1446 4440 y(47)1552 4470 y Ft(are)f(listed)-150 4566 y(in)e(table)h(I.)50 b(F)-7 b(or)32 b(rotational)e(states)i(larger)e(than)j Fi(J)1542 4536 y Fh(00)1615 4566 y Ft(=)d(8)i(ex-)-150 4661 y(p)r(erimen)n(tal)g(data)g(for)f(the)i(alignmen)n(t)e(are)h(not)g (a)n(v)-5 b(ailable,)32 b(w)n(e)-150 4757 y(th)n(us)f(set)g Fi(\037)d Ft(=)g(1)i(for)h(these)f(states.)46 b(In)31 b(the)h(vibrationally)d(ex-)-150 4852 y(ited)36 b(state)g(no)f (rotational)f(alignmen)n(t)i(w)n(as)f(observ)n(ed)f(within)-150 4948 y(the)28 b(exp)r(erimen)n(tal)f(error)667 4918 y Fm(47)735 4948 y Ft(.)-67 5043 y(Rotational)j(state)i(p)r(opulations)f (for)g(D)1204 5055 y Fm(2)1273 5043 y Ft(desorbing)f(from)h(a)-150 5139 y(clean)39 b(Pd\(100\))f(surface)g(at)h Fi(T)53 b Ft(=)42 b(800)14 b(K)37 b(are)h(sho)n(wn)g(in)i(\014g.)-150 5234 y(3)35 b(for)f(b)r(oth)h(vibrational)f(states)h Fi(v)981 5204 y Fh(00)1059 5234 y Ft(=)g(0)f(and)h Fi(v)1447 5204 y Fh(00)1525 5234 y Ft(=)g(1,)h(indi-)-150 5330 y(cated)e(b)n(y)h(\014lled)g(squares)e(and)i(triangles,)g(resp)r(ectiv) n(ely)-7 b(.)57 b(The)2042 -83 y(p)r(opulation)29 b(data)f(displa)n(y)n (ed)g(in)h(Fig.)g(3)g(are)f(a)n(v)n(eraged)e(for)j(the)2042 12 y(P-)34 b(and)g(R-branc)n(h)g(measuremen)n(ts.)57 b(The)35 b(ortho-)e(and)i(para-)2042 108 y(D)2105 120 y Fm(2)2174 108 y Ft(\014t)d(to)g(common)f(curv)n(es,)h(implying)g (that)g(they)g(are)e(p)r(opu-)2042 203 y(lated)35 b(statistically)-7 b(.)60 b(F)-7 b(or)35 b(an)g(ensem)n(ble)g(in)g(thermal)g(equilib-)2042 299 y(rium)25 b(a)g(Boltzmann)g(plot)g(as)g(sho)n(wn)f(in)i(Fig.)f(3)g (should)g(exhibit)2042 394 y(a)40 b(linear)g(dep)r(endence)h(with)g(a)f (slop)r(e)g(of)g(\()p Fk(\000)p Ft(1)p Fi(=k)3664 406 y Fl(B)3721 394 y Fi(T)3770 406 y Fm(rot)3858 394 y Ft(\).)76 b(As)2042 490 y(is)39 b(eviden)n(t,)k(the)d(rotational)e(state)i(p)r (opulation)f(data)g(of)h(the)2042 585 y(vibrational)c(ground)g(state)h (do)g(not)g(resem)n(ble)g(a)g(Boltzmann)2042 681 y(distribution,)h (although)e(the)h(deviation)f(from)g(a)g(Boltzmann)2042 776 y(distribution)28 b(seems)g(to)g(b)r(e)h(small.)39 b(But)29 b(to)f(illustrate)g(it)h(more)2042 872 y(clearly)39 b(a)i(Boltzmann)f(\014t)h(to)f(the)i(p)r(opulation)e(data)g(of)h(the) 2042 967 y(states)36 b Fi(J)2341 937 y Fh(00)2421 967 y Ft(=)h(5)f(to)h(12)e(is)h(sho)n(wn)g(as)g(a)g(thin)h(line)f(yielding) h(a)2042 1063 y(rotational)30 b(temp)r(erature)i(of)f Fi(T)3054 1075 y Fl(r)r(ot)3179 1063 y Ft(=)e(906)14 b(K.)48 b(The)32 b(o)n(v)n(erp)r(opu-)2042 1158 y(lation)19 b(of)h(lo)n(w)g(rotational)e(states)i Fi(J)3157 1128 y Fh(00)3222 1158 y Ft(=)j(0)c(to)h(4)g(can)f(th)n(us)h(clearly)2042 1254 y(b)r(e)34 b(indicated.)55 b(It)34 b(is)f(p)r(ossible)h(to)f (\014t)h(the)g(p)r(opulation)g(distri-)2042 1349 y(bution)j(b)n(y)f(t)n (w)n(o)g(Boltzmann)g(temp)r(eratures)g(of)h Fi(T)3704 1361 y Fm(1)3779 1349 y Ft(=)g(352)14 b(K)2042 1445 y(and)26 b Fi(T)2251 1457 y Fm(2)2311 1445 y Ft(=)d(910)14 b(K,)24 b(as)i(sho)n(wn)g(b)n(y)g(the)h(dashed)f(curv)n(e)f(in)i(Fig.)g(3.)2042 1540 y(This)k(comp)r(osed)g(\014t)h(th)n(us)f(rev)n(eals)f(a)h(strong)f (rotational)g(co)r(ol-)2042 1636 y(ing)36 b(e\013ect)h(for)e(D)2615 1648 y Fm(2)2689 1636 y Ft(in)i(lo)n(w-)p Fi(J)3000 1605 y Fh(00)3078 1636 y Ft(states,)h(while)e(the)h(higher)f Fi(J)4042 1605 y Fh(00)2042 1731 y Ft(are)25 b(more)g(or)h(less)f(in)i (thermal)f(equilibrium)g(with)g(the)h(surface.)2042 1826 y(Similar)h(distributions)h(are)f(observ)n(ed)g(at)g(all)h(surface)f (temp)r(er-)2042 1922 y(atures)37 b(in)n(v)n(estigated.)67 b(Fits)38 b(to)g(the)h(data)e(of)h(the)h(rotational)2042 2017 y(states)27 b Fi(J)2332 1987 y Fh(00)2398 2017 y Ft(=)c(5)k(to)h(12)f(yield)h(rotational)e(temp)r(eratures)h(higher)2042 2113 y(than)j(the)h(corresp)r(onding)d(surface)h(temp)r(erature,)i Fi(T)3751 2125 y Fl(r)r(ot)3872 2113 y Fi(>)c(T)4013 2125 y Fl(S)4061 2113 y Ft(.)2042 2208 y(This)21 b(can)f(b)r(e)i (rationalized)d(b)n(y)i(the)g(follo)n(wing)f(mo)r(del.)35 b(As)21 b(men-)2042 2304 y(tioned,)35 b(molecules)f(in)g(lo)n(w-)p Fi(J)3015 2274 y Fh(00)3090 2304 y Ft(states,)h Fi(J)3411 2274 y Fh(00)3487 2304 y Fk(\024)p Ft(3)f(or)f(4,)i(can)e(ef-)2042 2399 y(fectivly)26 b(b)r(e)g(steered)g(to)f(an)h(unactiv)-5 b(ated)26 b(adsorption)e(p)r(osition)2042 2495 y(within)h(the)h (surface)e(unit)i(cell.)36 b(Similarly)-7 b(,)25 b(molecules)f(in)i (high-)2042 2590 y Fi(J)2096 2560 y Fh(00)2174 2590 y Ft(states)35 b(ha)n(v)n(e)g(su\016cien)n(t)h(rotational)e(energy)h(to)g (o)n(v)n(ercome)2042 2686 y(after)28 b(rotational-translational)c (coupling)k(an)n(y)g(barrier)e(in)j(the)2042 2781 y(disso)r(ciativ)n(e) 24 b(adsorption)h(p)r(oten)n(tial)h(on)f(Pd\(100\).)36 b(Th)n(us)25 b(their)2042 2877 y(stic)n(king)32 b(probabilit)n(y)f(is)i (high.)51 b(Molecules)32 b(in)h Fi(J)3643 2847 y Fh(00)3717 2877 y Ft(=)e(5,)i(ho)n(w-)2042 2972 y(ev)n(er,)h(cannot)f(b)r(e)g 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Ft(=)c(519)14 b(cm)2707 4279 y Fh(\000)p Fm(1)2822 4309 y Ft(or)27 b Fi(<)9 b(E)3059 4321 y Fl(r)r(ot)3162 4309 y Fi(>)-5 b(=k)3307 4321 y Fl(B)3387 4309 y Ft(=)23 b(747)14 b(K.)2125 4404 y(The)35 b(stronger)f(rotational)g(co)r(oling)h (for)g(h)n(ydrogen)f(desorb-)2042 4500 y(ing)27 b(from)h(clean)f (Pd\(100\))g(rep)r(orted)g(earlier)3472 4470 y Fm(38)3569 4500 y Ft(w)n(as)f(caused)h(b)n(y)2042 4595 y(a)d(restriction)f(to)h (rotational)e(states)i Fi(J)31 b Fk(\024)23 b Ft(5)h(due)g(to)g (insu\016cien)n(t)2042 4691 y(sensitivit)n(y)33 b(to)h(detect)g(higher) f Fi(J)3120 4661 y Fh(00)3196 4691 y Ft(states.)54 b(In)34 b(addition,)h(this)2042 4786 y(result)19 b(w)n(as)g(in\015uenced)h(b)n (y)f(the)h(fact)g(that)g(the)g(rotational)e(align-)2042 4882 y(men)n(t)33 b(of)g(the)g(desorbing)f(molecules)g(w)n(as)g(not)h (kno)n(wn,)g(whic)n(h)2042 4977 y(in\015uences)27 b(mainly)h(lo)n(w-)p Fi(J)2900 4947 y Fh(00)2969 4977 y Ft(states)f(for)g(H)3394 4989 y Fm(2)3432 4977 y Ft(/Pd.)2125 5073 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F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{rF}{3 copyfont}? ` /OrigFontType ~ |/OrigFontName ~ | & E 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/xF{scalefont Pscript_Windows_Font 3 1 $ put}b/xMF{mFM astore makefont Pscript_Windows_Font 3 1 $ put}b/xF2/scalefont , |/xMF2{mFM astore makefont}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/sSU{N/uW ~ |/yUP ~ |/xUP ~ |}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ |/ySP ~ |/xSP ~ |}b/sT{xSP ySP sW sLT}b/sR{: + R 0 0 M}b /sRxy{: matrix astore concat 0 0 M}b/eR/; , | /mBF{@ 4 copyfont `/FontName ~ |/OrigFontType ~ |/OrigFontName ~ | 0 FontMatrix idtransform ! &/PaintType known{PaintType 0 eq{/PaintType 2 | /StrokeWidth ~ |}{PaintType 1 eq PaintType 2 eq or PaintType 3 eq or & /StrokeWidth known and{StrokeWidth add/StrokeWidth ~ |}{!}?}?}{!}? @ & E definefont Pscript_Windows_Font 3 1 $ put}b/xBF{Pscript_Windows_Font ` 1 ^ /FontName get 1 ^ scalefont 3 1 $ scalefont 2 copy ~ | ~ ! | E}b/xMBF{mFM astore Pscript_Windows_Font ` 1 ^/FontName get 1 ^ makefont 3 1 $ makefont 2 copy ~ | ~ ! | E}b/xBF2{/sB0 ~ mBF/sB1 sB0 3 -1 $ xBF sB1}b/xMBF2{/sB0 ~ mBF mFM astore/sB1 sB0 3 -1 $ xMBF sB1}b/sB{: Pscript_Windows_Font currentfont get Ji @ S ; S}b/asB{: Pscript_Windows_Font currentfont get Ji 3 copy A ; A}b/wsB{ : Pscript_Windows_Font currentfont get Ji 4 copy W ; W}b/awsB{: Pscript_Windows_Font currentfont get Ji 6 copy D ; D}b/sBT3{: @ S ; 1 1 -M S}b /asBT3{: 3 copy A ; 1 1 -M A}b/wsBT3{: 4 copy W ; 1 1 -M W}b/awsBT3{: 6 copy D ; 1 1 -M D}b/mIF{iMat 4 3 -1 $ put 2 copyfont `/OrigFontType ~ |/OrigFontName ~ | @ & E definefont iMat makefont Pscript_Windows_Font 3 1 $ put}b /SavedCTM null |/CTMsave{/SavedCTM SavedCTM currentmatrix |}b/CTMrestore{ SavedCTM setmatrix}b/mp null |/ADO_mxRot null |/GDIHMatrix null | /GDIHPatternDict 22 dict | GDIHPatternDict `/PatternType 1 |/PaintType 2 | /Reps L2?{1}{5}? |/XStep 8 Reps mul |/YStep XStep |/BBox[0 0 XStep YStep]| /TilingType 1 |/PaintProc{` 1 Lw[]0 setdash PaintData , exec E}b/FGnd null | /BGnd null |/HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b /HS_BDiagonal{biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? |/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b/vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag {Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E /makehatch{GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0/HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{ /h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5/HS_DiagCross makehatch}b/GDIBWPatternDict 17 dict @ `/PatternType 1 |/PaintType L2?{1}{2}? |/RepsV L2?{1}{6}? |/RepsH L2?{1}{5}? |/BBox[0 0 RepsH 1]|/TilingType 1 | /XStep 1 |/YStep 1 |/Height 8 RepsV mul |/Width 8 |/mx[Width 0 0 Height neg 0 Height]|/FGnd null |/BGnd null |/SetBGndFGnd L2?{{BGnd null ne{BGnd aload ! sgco BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! sgco}if} }{{}}? b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E |/GDIBWPatternMx null |/pfprep{save 4 1 $ /PatternOfTheDay 4 1 $ GDIBWPatternDict `/PaintData ~ |/BGnd ~ |/FGnd ~ | E CTMsave GDIBWPatternMx setmatrix GDIBWPatternDict matrix mp CTMrestore ~ !}b /hrf null |/prf{pfprep ~ 6 1 $ 5 hrf restore}b/GraphInit{GDIHMatrix null eq{ /SavedCTM matrix | : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly | ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E dsnap +S/GDIBWPatternMx matrix currentmatrix readonly | ; ;}if}b/cirp{360 0 An C}b/ellp{CTMsave + +S 0.5 0 M 0 0 0.5 360 0 An C CTMrestore}b/rrp{/rad ~ |/y2 ~ |/x2 ~ |/y1 ~ |/x1 ~ | x2 x1 add 2 V y1 M x1 y1 x1 y2 rad arct x1 y2 x2 y2 rad arct x2 y2 x2 y1 rad arct x2 y1 x1 y1 rad arct C}b/RRp{CTMsave + +S/dyS ~ |/dxS ~ | dxS 2 V 0 M 0 0 0 dyS 0.5 arct 0 dyS dxS dyS 0.5 arct dxS dyS dxS 0 0.5 arct dxS 0 0 0 0.5 arct C CTMrestore}b L2? not g{/arct{arcto ! ! ! !}b/GDIpattfill{@ ` BGnd null ne PaintType 2 eq and{: BGnd aload ! sgco fEOFill{O}{L}? ; FGnd aload ! U/fGray 2 ^ put{2}{4}? -1 $}if E @ patterncalc : 4 ^/PaintType get 2 eq{fGray{6 -1 $ sg}{8 -3 $ sco}? }if fEOFill{eoclip}{clip}? N patternfill ; N}b/hrf{/fGray 1 ^ 6 eq | -4 $ N rp C/fEOFill F | GDIpattfill}b/hfMain{/fEOFill ~ |/fGray ~ | GDIpattfill}b/hf{T hfMain}b/hfW{F hfMain}b/hs{currentpoint strokepath M hfW}b/pfMain{/fEOFill ~ | pfprep GDIpattfill restore N}b/pf{T pfMain}b/pfW{F pfMain}b/ps{currentpoint strokepath M pfW}b/mpstr 1 string |/mp{~ @ length 12 add dict copy ` /PatternCTM matrix currentmatrix |/PatternMatrix ~ |/PatWidth XStep mpstr length mul |/PatHeight YStep |/FontType 3 |/Encoding 256 array | 3 string 0 1 255{Encoding ~ @ 3 ^ cvs cvn put}for !/FontMatrix matrix |/FontBBox BBox | /BuildChar{! @ ` XStep 0 FontBBox aload ! setcachedevice/PaintProc , E : exec ;}b & E ~ @ 3 -1 $ definefont}b/patterncalc{` : PatternCTM setmatrix PatternMatrix concat BBox aload ! ! ! + pathbbox ; PatHeight V ceiling 4 1 $ PatWidth V ceiling 4 1 $ PatHeight V floor 4 1 $ PatWidth V floor 4 1 $ 2 ^ sub cvi abs ~ 3 ^ sub cvi abs ~ 4 2 $ PatHeight mul ~ PatWidth mul ~ E}b /patternfill{5 -1 $ @ ` Ji PatternCTM setmatrix PatternMatrix concat 0 2 ^ 2 ^ M 0 1 mpstr length 1 sub{1 ^ mpstr 3 1 $ put}for ! 2 ^{currentpoint 5 ^{mpstr S}repeat YStep add M}repeat ! ! ! ! E}b}e L2? g{/mp/makepattern , |/hrf{6 eq setAorABC setpattern rectfill}b/hf{ setAorABC setpattern O}b/hfW{setAorABC setpattern L}b/hs{setAorABC setpattern K}b/pf{pfprep setpattern O restore N}b/pfW{pfprep setpattern L restore N}b/ps{ pfprep setpattern K restore N}b}e /iw 0 |/ih 0 |/im_save 0 |/s 0 |/polarity 0 |/smoothflag 0 |/mystring 0 |/bpc 0 |/setup1asciiproc{[currentfile mystring/readhexstring cvx/! cvx]cvx bind}b /setup1binaryproc{[currentfile mystring/readstring cvx/! cvx]cvx bind}b /setup2asciiproc{currentfile/ASCII85Decode filter/RunLengthDecode filter}b /setup2binaryproc{currentfile/RunLengthDecode filter}b/mycolorspace{colspABC}| /myimagedict{/myimagedict 10 dict | myimagedict @ `/ImageType 1 | /MultipleDataSource F | E}b/imageprocarray[/setup1binaryproc/setup1asciiproc /setup2binaryproc/setup2asciiproc/setup1binarydecodeproc/setup1asciidecodeproc ]|/L2Polarity{{[1 0]}{[0 1]}?}b/Q{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/X{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/Z{im_save restore}b/Y{sgco myimagedict @ ` /Width iw |/Height ih |/Decode polarity |/ImageMatrix[iw 0 0 ih 0 0]| /DataSource s |/BitsPerComponent 1 |/Interpolate smoothflag | E imagemask}b L2? not g{/setup2asciiproc{[/Level2ImagesError , aload ! T FatalErrorIf}b /setup2binaryproc/setup2asciiproc , |/L2Polarity{}|/Y{sgco iw ih polarity[iw 0 0 ih 0 0]s imagemask}b}e L2? not g{/testsystemdict{where{systemdict eq{T}{F}?}{F}?}b/c 1 |/colorimage where{! T}{F}?{/c 0 statusdict `/processcolors where{! ! processcolors}{ /deviceinfo where{! deviceinfo/Colors known{!{deviceinfo/Colors get}}if}if}? E | c 0 ne{/colorimage testsystemdict/setcolortransfer testsystemdict /currentcolortransfer testsystemdict/currentcmykcolor testsystemdict and and and not{/c 0 |}if}if}if c @ 1 ne ~ @ 3 ne ~ 4 ne and and{/c 0 |}if c 1 eq g{ /expandbw{expandfactor mul round cvi bwclut ~ get 255 V}b/doclutimage{!/bwclut ~ | bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/expandfactor ~ |[/expandbw ,/exec , @ currenttransfer ~]cvx bind settransfer iw ih bpc[iw 0 0 ih 0 0]s image}b}e c @ 3 eq ~ 4 eq or g{/nullproc{{}}|/concatutil{/exec , 7 -1 $/exec ,}b/defsubclut{ 1 add getinterval |}b/spconcattransfer{/Dclut ~ |/Cclut ~ |/Bclut ~ |/Aclut ~ |/ncompute ~ , | currentcolortransfer[{Aclut ncompute}concatutil]cvx[{Bclut ncompute}concatutil]cvx[{Cclut ncompute}concatutil]cvx[{Dclut ncompute} concatutil]cvx setcolortransfer}b/setuprgbcluts{/bit3x rgbclut length 3 sub | /bit1x bit3x 3 idiv |/rclut rgbclut |/gclut rclut 1 bit3x defsubclut/bclut rclut 2 bit3x defsubclut}b}e c 3 eq g{/3compute{~ bit3x mul round cvi get 255 V}b/doclutimage{/rgbclut ~ | ! setuprgbcluts/3compute rclut gclut bclut @ spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @]cvx nullproc nullproc T 3 colorimage}b}e c 4 eq g{/ftoint{1 ~ sub 255 mul round cvi}b/stuffclut{ cmykindex 3 -1 $ put}b/4compute{~ bit4x mul round cvi get 255 V}b /invalidcolortable? T |/computecmykclut{setuprgbcluts/bit4x rgbclut length 3 idiv 4 mul 4 sub |/cmykclut bit4x 4 add string |/cclut cmykclut |/mclut cclut 1 bit4x defsubclut/yclut cclut 2 bit4x defsubclut/kclut cclut 3 bit4x defsubclut/cmykindex 0 | 0 1 bit1x{@/cmykindex ~ bit1x ~ sub 4 mul | 3 mul @ rclut ~ get 255 V ~ @ gclut ~ get 255 V ~ bclut ~ get 255 V setrgbcolor currentcmykcolor ftoint kclut stuffclut ftoint yclut stuffclut ftoint mclut stuffclut ftoint cclut stuffclut}for}b/doclutimage{/rgbclut ~ | ! invalidcolortable?{computecmykclut}if/4compute cclut mclut yclut kclut spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @ @]cvx nullproc nullproc nullproc T 4 colorimage}b}e c 0 eq g{/a{3 mul 3 getinterval putinterval ~ 3 add ~ 3 copy}b/8lookup/a , |/4lookup{/byte 1 ^ | -4 bitshift a byte 15 and a}b/2lookup{/byte 1 ^ | -6 bitshift a byte -4 bitshift 3 and a byte -2 bitshift 3 and a byte 3 and a}b/colorexpand{mystringexp 0 rgbclut 3 copy 7 -1 $/mylookup , forall ! ! ! ! !}b/createexpandstr{/mystringexp ~ mystring length mul string |}b/doclutimage{/rgbclut ~ | !/mylookup bpc 8 eq{3 createexpandstr/8lookup}{bpc 4 eq{6 createexpandstr/4lookup}{12 createexpandstr/2lookup}?}? , | iw ih bpc[iw 0 0 ih 0 0][s/exec ,/colorexpand ,/exec ,]cvx F 3 colorimage}b}e/colorimage where{! T}{F}? g{/do24image{iw ih 8 [iw 0 0 ih 0 0]s F 3 colorimage}b}DefIf_El{/rgbtogray{/str ~ |/len str length |/smlen len 3 idiv |/rstr str |/gstr str 1 len 1 sub getinterval |/bstr str 2 len 2 sub getinterval | str @ 0 1 smlen 1 sub{@ 3 mul rstr 1 ^ get 0.3 mul gstr 2 ^ get 0.59 mul add bstr 3 -1 $ get 0.11 mul add round cvi put @}for ! 0 smlen getinterval}b/do24image{iw ih 8[iw 0 0 ih 0 0][s/exec ,/rgbtogray ,/exec ,]cvx bind image}b}e/doNimage{bpc 24 eq{do24image}{iw ih bpc[iw 0 0 ih 0 0]s image}?}b}e L2? g{/doclutimage{/rgbclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[ /Indexed colspABC hival rgbclut]setcolorspace myimagedict @ `/Width iw | /Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s | /BitsPerComponent bpc |/Interpolate smoothflag | E image}b/doCMYKclutimage{ /CMYKclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[/Indexed/DeviceCMYK hival CMYKclut]setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc | /Interpolate smoothflag | E image}b/doNimage{bpc 24 eq{colspABC}{colspA}? setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode bpc 24 eq{[0 1 0 1 0 1]}{[0 1]}? |/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc 24 eq{8}{bpc}? |/Interpolate smoothflag | E image}b/doCMYKimage{ /DeviceCMYK setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 1 0 1 0 1 0 1]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent 8 | /Interpolate smoothflag | E image}b}e /GreNewFont{10 dict @ 3 1 $ | @ ` 4 1 $/FontType 3 |/FontMatrix ~ |/FontBBox ~ |/Encoding 256 array | 0 1 255{Encoding ~/.notdef put}for/CharProcs 257 dict | CharProcs/.notdef{}put/Metrics 257 dict | Metrics/.notdef 3 -1 $ put/BuildChar {/char ~ |/fontdict ~ |/charname fontdict/Encoding get char get | fontdict /Metrics get charname get aload ! setcachedevice fontdict ` Encoding char get CharProcs ~ get E exec}| E definefont !}|/AddChar{` Encoding 3 1 $ put CharProcs 3 1 $ put Metrics 3 1 $ put E}| /FEbuf 2 string |/FEglyph 3 string |/FE{(G00)FEglyph copy ! 1 ~{@ 16 lt{ /offset 2 store}{/offset 1 store}? @ 16 FEbuf cvrs FEglyph ~ offset ~ putinterval 1 ^ ~ FEglyph cvn put}for}bind |/Type1Hdr{11 dict `/FontName ~ | /PaintType ~ |/FontType 1 |/FontMatrix[1 3 ^ V 0 0 1 6 ^ V 0 0]| !/Encoding 256 array 0 1 255{1 ^ ~/.notdef put}for 3 ^ 3 ^ FE | ! !/FontBBox{0 0 0 0}| & E currentfile eexec}bind | /pp 1 string |/ss 1 string |/rledecodebinary{/DC 0 |/BC 0 |{DC mystring length ge{exit}if currentfile ss readstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{ mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/rledecodeascii{/DC 0 | /BC 0 |{DC mystring length ge{exit}if currentfile ss readhexstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readhexstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readhexstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/setup1asciidecodeproc{[/rledecodeascii cvx]cvx bind}b /setup1binarydecodeproc{[/rledecodebinary cvx]cvx bind}b userdict/Pscript_Win_Compat 13 dict dup begin/bd{bind def}bind def/ld{load def }bd/CB{pop pop pop pop}bind def/B{pop pop pop pop}bind def/$x matrix def/SS{ /pagesave save def}bind def/RS{/pagesave where{pop pagesave restore}{$x matrix invertmatrix concat}ifelse}bind def/ANSIVec[0/grave 1/acute 2/circumflex 3 /tilde 4/macron 5/breve 6/dotaccent 7/dieresis 8/ring 9/cedilla 10 /hungarumlaut 11/ogonek 12/caron 13/dotlessi 39/quotesingle 96/grave 124/bar 130/quotesinglbase 131/florin 132/quotedblbase 133/ellipsis 134/dagger 135 /daggerdbl 136/circumflex 137/perthousand 138/Scaron 139/guilsinglleft 140/OE 145/quoteleft 146/quoteright 147/quotedblleft 148/quotedblright 149/bullet 150 /endash 151/emdash 152/tilde 153/trademark 154/scaron 155/guilsinglright 156 /oe 159/Ydieresis 160/space 161/exclamdown 164/currency 165/yen 166/brokenbar 167/section 168/dieresis 169/copyright 170/ordfeminine 171/guillemotleft 172 /logicalnot 173/hyphen 174/registered 175/macron 176/degree 177/plusminus 178 /twosuperior 179/threesuperior 180/acute 181/mu 182/paragraph 183 /periodcentered 184/cedilla 185/onesuperior 186/ordmasculine 187 /guillemotright 188/onequarter 189/onehalf 190/threequarters 191/questiondown 192/Agrave 193/Aacute 194/Acircumflex 195/Atilde 196/Adieresis 197/Aring 198 /AE 199/Ccedilla 200/Egrave 201/Eacute 202/Ecircumflex 203/Edieresis 204 /Igrave 205/Iacute 206/Icircumflex 207/Idieresis 208/Eth 209/Ntilde 210/Ograve 211/Oacute 212/Ocircumflex 213/Otilde 214/Odieresis 215/multiply 216/Oslash 217/Ugrave 218/Uacute 219/Ucircumflex 220/Udieresis 221/Yacute 222/Thorn 223 /germandbls 224/agrave 225/aacute 226/acircumflex 227/atilde 228/adieresis 229 /aring 230/ae 231/ccedilla 232/egrave 233/eacute 234/ecircumflex 235/edieresis 236/igrave 237/iacute 238/icircumflex 239/idieresis 240/eth 241/ntilde 242 /ograve 243/oacute 244/ocircumflex 245/otilde 246/odieresis 247/divide 248 /oslash 249/ugrave 250/uacute 251/ucircumflex 252/udieresis 253/yacute 254 /thorn 255/ydieresis]def currentdict{dup type/operatortype eq{[exch]cvx def}{ pop pop}ifelse}forall/initialize{currentdict exch begin begin}bind def /terminate{/@FL where not{pop end end}{pop}ifelse}bind def/suspend/terminate load def/resume/initialize load def/M/moveto load def end put/Courier findfont 10 scalefont setfont end /ProcSet defineresource pop Pscript_Win_Compat dup /initialize get exec [ 0 1.000 -1.000 0 0 0 ] false /Pscript_Win_Driver /ProcSet findresource dup /initialize get exec /mysetup [ 0.120 0 0 -0.120 0.960 594.960 ] | userdict begin /pagesave save def end mysetup concat colspRefresh : 1.000 1.000 1.000 sco 0 0 4958 7016 rf ; 1034 315 N M 5736 3705 rr 1034 315 N M 5737 3706 rr 16 Lw 0 Lc 0 Lj solid 0 0 0 sco K 1034 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T | /fM[1 0 0 -1 0 0]|/mFM matrix |/iMat[1 0 0.212557 neg 1 0 0]|}if}b/xUP null | /yUP null |/uW null |/xSP null |/ySP null |/sW null |/copyfont{1 ^ length add dict `{1 ^/FID ne{|}{! !}?}forall & E}b/rF{3 copyfont @ `/Encoding ANSIEncoding &/CharStrings known{CharStrings/Eth known not{! ANSIEncodingOld} if}if | E}b/mF{findfont ~{@/Encoding get @ StandardEncoding eq{! T}{{ ISOLatin1Encoding}stopped{! F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{rF}{3 copyfont}? ` /OrigFontType ~ |/OrigFontName ~ | & E 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/xF{scalefont Pscript_Windows_Font 3 1 $ put}b/xMF{mFM astore makefont Pscript_Windows_Font 3 1 $ put}b/xF2/scalefont , |/xMF2{mFM astore makefont}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/sSU{N/uW ~ |/yUP ~ |/xUP ~ |}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ |/ySP ~ |/xSP ~ |}b/sT{xSP ySP sW sLT}b/sR{: + R 0 0 M}b /sRxy{: matrix astore concat 0 0 M}b/eR/; , | /mBF{@ 4 copyfont `/FontName ~ |/OrigFontType ~ |/OrigFontName ~ | 0 FontMatrix idtransform ! &/PaintType known{PaintType 0 eq{/PaintType 2 | /StrokeWidth ~ |}{PaintType 1 eq PaintType 2 eq or PaintType 3 eq or & /StrokeWidth known and{StrokeWidth add/StrokeWidth ~ |}{!}?}?}{!}? @ & E definefont Pscript_Windows_Font 3 1 $ put}b/xBF{Pscript_Windows_Font ` 1 ^ /FontName get 1 ^ scalefont 3 1 $ scalefont 2 copy ~ | ~ ! | E}b/xMBF{mFM astore Pscript_Windows_Font ` 1 ^/FontName get 1 ^ makefont 3 1 $ makefont 2 copy ~ | ~ ! | E}b/xBF2{/sB0 ~ mBF/sB1 sB0 3 -1 $ xBF sB1}b/xMBF2{/sB0 ~ mBF mFM astore/sB1 sB0 3 -1 $ xMBF sB1}b/sB{: Pscript_Windows_Font currentfont get Ji @ S ; S}b/asB{: Pscript_Windows_Font currentfont get Ji 3 copy A ; A}b/wsB{ : Pscript_Windows_Font currentfont get Ji 4 copy W ; W}b/awsB{: Pscript_Windows_Font currentfont get Ji 6 copy D ; D}b/sBT3{: @ S ; 1 1 -M S}b /asBT3{: 3 copy A ; 1 1 -M A}b/wsBT3{: 4 copy W ; 1 1 -M W}b/awsBT3{: 6 copy D ; 1 1 -M D}b/mIF{iMat 4 3 -1 $ put 2 copyfont `/OrigFontType ~ |/OrigFontName ~ | @ & E definefont iMat makefont Pscript_Windows_Font 3 1 $ put}b /SavedCTM null |/CTMsave{/SavedCTM SavedCTM currentmatrix |}b/CTMrestore{ SavedCTM setmatrix}b/mp null |/ADO_mxRot null |/GDIHMatrix null | /GDIHPatternDict 22 dict | GDIHPatternDict `/PatternType 1 |/PaintType 2 | /Reps L2?{1}{5}? |/XStep 8 Reps mul |/YStep XStep |/BBox[0 0 XStep YStep]| /TilingType 1 |/PaintProc{` 1 Lw[]0 setdash PaintData , exec E}b/FGnd null | /BGnd null |/HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b /HS_BDiagonal{biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? |/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b/vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag {Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E /makehatch{GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0/HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{ /h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5/HS_DiagCross makehatch}b/GDIBWPatternDict 17 dict @ `/PatternType 1 |/PaintType L2?{1}{2}? |/RepsV L2?{1}{6}? |/RepsH L2?{1}{5}? |/BBox[0 0 RepsH 1]|/TilingType 1 | /XStep 1 |/YStep 1 |/Height 8 RepsV mul |/Width 8 |/mx[Width 0 0 Height neg 0 Height]|/FGnd null |/BGnd null |/SetBGndFGnd L2?{{BGnd null ne{BGnd aload ! sgco BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! sgco}if} }{{}}? b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E |/GDIBWPatternMx null |/pfprep{save 4 1 $ /PatternOfTheDay 4 1 $ GDIBWPatternDict `/PaintData ~ |/BGnd ~ |/FGnd ~ | E CTMsave GDIBWPatternMx setmatrix GDIBWPatternDict matrix mp CTMrestore ~ !}b /hrf null |/prf{pfprep ~ 6 1 $ 5 hrf restore}b/GraphInit{GDIHMatrix null eq{ /SavedCTM matrix | : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly | ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E dsnap +S/GDIBWPatternMx matrix currentmatrix readonly | ; ;}if}b/cirp{360 0 An C}b/ellp{CTMsave + +S 0.5 0 M 0 0 0.5 360 0 An C CTMrestore}b/rrp{/rad ~ |/y2 ~ |/x2 ~ |/y1 ~ |/x1 ~ | x2 x1 add 2 V y1 M x1 y1 x1 y2 rad arct x1 y2 x2 y2 rad arct x2 y2 x2 y1 rad arct x2 y1 x1 y1 rad arct C}b/RRp{CTMsave + +S/dyS ~ |/dxS ~ | dxS 2 V 0 M 0 0 0 dyS 0.5 arct 0 dyS dxS dyS 0.5 arct dxS dyS dxS 0 0.5 arct dxS 0 0 0 0.5 arct C CTMrestore}b L2? not g{/arct{arcto ! ! ! !}b/GDIpattfill{@ ` BGnd null ne PaintType 2 eq and{: BGnd aload ! sgco fEOFill{O}{L}? ; FGnd aload ! U/fGray 2 ^ put{2}{4}? -1 $}if E @ patterncalc : 4 ^/PaintType get 2 eq{fGray{6 -1 $ sg}{8 -3 $ sco}? }if fEOFill{eoclip}{clip}? N patternfill ; N}b/hrf{/fGray 1 ^ 6 eq | -4 $ N rp C/fEOFill F | GDIpattfill}b/hfMain{/fEOFill ~ |/fGray ~ | GDIpattfill}b/hf{T hfMain}b/hfW{F hfMain}b/hs{currentpoint strokepath M hfW}b/pfMain{/fEOFill ~ | pfprep GDIpattfill restore N}b/pf{T pfMain}b/pfW{F pfMain}b/ps{currentpoint strokepath M pfW}b/mpstr 1 string |/mp{~ @ length 12 add dict copy ` /PatternCTM matrix currentmatrix |/PatternMatrix ~ |/PatWidth XStep mpstr length mul |/PatHeight YStep |/FontType 3 |/Encoding 256 array | 3 string 0 1 255{Encoding ~ @ 3 ^ cvs cvn put}for !/FontMatrix matrix |/FontBBox BBox | /BuildChar{! @ ` XStep 0 FontBBox aload ! setcachedevice/PaintProc , E : exec ;}b & E ~ @ 3 -1 $ definefont}b/patterncalc{` : PatternCTM setmatrix PatternMatrix concat BBox aload ! ! ! + pathbbox ; PatHeight V ceiling 4 1 $ PatWidth V ceiling 4 1 $ PatHeight V floor 4 1 $ PatWidth V floor 4 1 $ 2 ^ sub cvi abs ~ 3 ^ sub cvi abs ~ 4 2 $ PatHeight mul ~ PatWidth mul ~ E}b /patternfill{5 -1 $ @ ` Ji PatternCTM setmatrix PatternMatrix concat 0 2 ^ 2 ^ M 0 1 mpstr length 1 sub{1 ^ mpstr 3 1 $ put}for ! 2 ^{currentpoint 5 ^{mpstr S}repeat YStep add M}repeat ! ! ! ! E}b}e L2? g{/mp/makepattern , |/hrf{6 eq setAorABC setpattern rectfill}b/hf{ setAorABC setpattern O}b/hfW{setAorABC setpattern L}b/hs{setAorABC setpattern K}b/pf{pfprep setpattern O restore N}b/pfW{pfprep setpattern L restore N}b/ps{ pfprep setpattern K restore N}b}e /iw 0 |/ih 0 |/im_save 0 |/s 0 |/polarity 0 |/smoothflag 0 |/mystring 0 |/bpc 0 |/setup1asciiproc{[currentfile mystring/readhexstring cvx/! cvx]cvx bind}b /setup1binaryproc{[currentfile mystring/readstring cvx/! cvx]cvx bind}b /setup2asciiproc{currentfile/ASCII85Decode filter/RunLengthDecode filter}b /setup2binaryproc{currentfile/RunLengthDecode filter}b/mycolorspace{colspABC}| /myimagedict{/myimagedict 10 dict | myimagedict @ `/ImageType 1 | /MultipleDataSource F | E}b/imageprocarray[/setup1binaryproc/setup1asciiproc /setup2binaryproc/setup2asciiproc/setup1binarydecodeproc/setup1asciidecodeproc ]|/L2Polarity{{[1 0]}{[0 1]}?}b/Q{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/X{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/Z{im_save restore}b/Y{sgco myimagedict @ ` /Width iw |/Height ih |/Decode polarity |/ImageMatrix[iw 0 0 ih 0 0]| /DataSource s |/BitsPerComponent 1 |/Interpolate smoothflag | E imagemask}b L2? not g{/setup2asciiproc{[/Level2ImagesError , aload ! T FatalErrorIf}b /setup2binaryproc/setup2asciiproc , |/L2Polarity{}|/Y{sgco iw ih polarity[iw 0 0 ih 0 0]s imagemask}b}e L2? not g{/testsystemdict{where{systemdict eq{T}{F}?}{F}?}b/c 1 |/colorimage where{! T}{F}?{/c 0 statusdict `/processcolors where{! ! processcolors}{ /deviceinfo where{! deviceinfo/Colors known{!{deviceinfo/Colors get}}if}if}? E | c 0 ne{/colorimage testsystemdict/setcolortransfer testsystemdict /currentcolortransfer testsystemdict/currentcmykcolor testsystemdict and and and not{/c 0 |}if}if}if c @ 1 ne ~ @ 3 ne ~ 4 ne and and{/c 0 |}if c 1 eq g{ /expandbw{expandfactor mul round cvi bwclut ~ get 255 V}b/doclutimage{!/bwclut ~ | bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/expandfactor ~ |[/expandbw ,/exec , @ currenttransfer ~]cvx bind settransfer iw ih bpc[iw 0 0 ih 0 0]s image}b}e c @ 3 eq ~ 4 eq or g{/nullproc{{}}|/concatutil{/exec , 7 -1 $/exec ,}b/defsubclut{ 1 add getinterval |}b/spconcattransfer{/Dclut ~ |/Cclut ~ |/Bclut ~ |/Aclut ~ |/ncompute ~ , | currentcolortransfer[{Aclut ncompute}concatutil]cvx[{Bclut ncompute}concatutil]cvx[{Cclut ncompute}concatutil]cvx[{Dclut ncompute} concatutil]cvx setcolortransfer}b/setuprgbcluts{/bit3x rgbclut length 3 sub | /bit1x bit3x 3 idiv |/rclut rgbclut |/gclut rclut 1 bit3x defsubclut/bclut rclut 2 bit3x defsubclut}b}e c 3 eq g{/3compute{~ bit3x mul round cvi get 255 V}b/doclutimage{/rgbclut ~ | ! setuprgbcluts/3compute rclut gclut bclut @ spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @]cvx nullproc nullproc T 3 colorimage}b}e c 4 eq g{/ftoint{1 ~ sub 255 mul round cvi}b/stuffclut{ cmykindex 3 -1 $ put}b/4compute{~ bit4x mul round cvi get 255 V}b /invalidcolortable? T |/computecmykclut{setuprgbcluts/bit4x rgbclut length 3 idiv 4 mul 4 sub |/cmykclut bit4x 4 add string |/cclut cmykclut |/mclut cclut 1 bit4x defsubclut/yclut cclut 2 bit4x defsubclut/kclut cclut 3 bit4x defsubclut/cmykindex 0 | 0 1 bit1x{@/cmykindex ~ bit1x ~ sub 4 mul | 3 mul @ rclut ~ get 255 V ~ @ gclut ~ get 255 V ~ bclut ~ get 255 V setrgbcolor currentcmykcolor ftoint kclut stuffclut ftoint yclut stuffclut ftoint mclut stuffclut ftoint cclut stuffclut}for}b/doclutimage{/rgbclut ~ | ! invalidcolortable?{computecmykclut}if/4compute cclut mclut yclut kclut spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @ @]cvx nullproc nullproc nullproc T 4 colorimage}b}e c 0 eq g{/a{3 mul 3 getinterval putinterval ~ 3 add ~ 3 copy}b/8lookup/a , |/4lookup{/byte 1 ^ | -4 bitshift a byte 15 and a}b/2lookup{/byte 1 ^ | -6 bitshift a byte -4 bitshift 3 and a byte -2 bitshift 3 and a byte 3 and a}b/colorexpand{mystringexp 0 rgbclut 3 copy 7 -1 $/mylookup , forall ! ! ! ! !}b/createexpandstr{/mystringexp ~ mystring length mul string |}b/doclutimage{/rgbclut ~ | !/mylookup bpc 8 eq{3 createexpandstr/8lookup}{bpc 4 eq{6 createexpandstr/4lookup}{12 createexpandstr/2lookup}?}? , | iw ih bpc[iw 0 0 ih 0 0][s/exec ,/colorexpand ,/exec ,]cvx F 3 colorimage}b}e/colorimage where{! T}{F}? g{/do24image{iw ih 8 [iw 0 0 ih 0 0]s F 3 colorimage}b}DefIf_El{/rgbtogray{/str ~ |/len str length |/smlen len 3 idiv |/rstr str |/gstr str 1 len 1 sub getinterval |/bstr str 2 len 2 sub getinterval | str @ 0 1 smlen 1 sub{@ 3 mul rstr 1 ^ get 0.3 mul gstr 2 ^ get 0.59 mul add bstr 3 -1 $ get 0.11 mul add round cvi put @}for ! 0 smlen getinterval}b/do24image{iw ih 8[iw 0 0 ih 0 0][s/exec ,/rgbtogray ,/exec ,]cvx bind image}b}e/doNimage{bpc 24 eq{do24image}{iw ih bpc[iw 0 0 ih 0 0]s image}?}b}e L2? g{/doclutimage{/rgbclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[ /Indexed colspABC hival rgbclut]setcolorspace myimagedict @ `/Width iw | /Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s | /BitsPerComponent bpc |/Interpolate smoothflag | E image}b/doCMYKclutimage{ /CMYKclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[/Indexed/DeviceCMYK hival CMYKclut]setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc | /Interpolate smoothflag | E image}b/doNimage{bpc 24 eq{colspABC}{colspA}? setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode bpc 24 eq{[0 1 0 1 0 1]}{[0 1]}? |/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc 24 eq{8}{bpc}? |/Interpolate smoothflag | E image}b/doCMYKimage{ /DeviceCMYK setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 1 0 1 0 1 0 1]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent 8 | /Interpolate smoothflag | E image}b}e /GreNewFont{10 dict @ 3 1 $ | @ ` 4 1 $/FontType 3 |/FontMatrix ~ |/FontBBox ~ |/Encoding 256 array | 0 1 255{Encoding ~/.notdef put}for/CharProcs 257 dict | CharProcs/.notdef{}put/Metrics 257 dict | Metrics/.notdef 3 -1 $ put/BuildChar {/char ~ |/fontdict ~ |/charname fontdict/Encoding get char get | fontdict /Metrics get charname get aload ! setcachedevice fontdict ` Encoding char get CharProcs ~ get E exec}| E definefont !}|/AddChar{` Encoding 3 1 $ put CharProcs 3 1 $ put Metrics 3 1 $ put E}| /FEbuf 2 string |/FEglyph 3 string |/FE{(G00)FEglyph copy ! 1 ~{@ 16 lt{ /offset 2 store}{/offset 1 store}? @ 16 FEbuf cvrs FEglyph ~ offset ~ putinterval 1 ^ ~ FEglyph cvn put}for}bind |/Type1Hdr{11 dict `/FontName ~ | /PaintType ~ |/FontType 1 |/FontMatrix[1 3 ^ V 0 0 1 6 ^ V 0 0]| !/Encoding 256 array 0 1 255{1 ^ ~/.notdef put}for 3 ^ 3 ^ FE | ! !/FontBBox{0 0 0 0}| & E currentfile eexec}bind | /pp 1 string |/ss 1 string |/rledecodebinary{/DC 0 |/BC 0 |{DC mystring length ge{exit}if currentfile ss readstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{ mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/rledecodeascii{/DC 0 | /BC 0 |{DC mystring length ge{exit}if currentfile ss readhexstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readhexstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readhexstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/setup1asciidecodeproc{[/rledecodeascii cvx]cvx bind}b /setup1binarydecodeproc{[/rledecodebinary cvx]cvx bind}b userdict/Pscript_Win_Compat 13 dict dup begin/bd{bind def}bind def/ld{load def }bd/CB{pop pop pop pop}bind def/B{pop pop pop pop}bind def/$x matrix def/SS{ /pagesave save def}bind def/RS{/pagesave where{pop pagesave restore}{$x matrix invertmatrix concat}ifelse}bind def/ANSIVec[0/grave 1/acute 2/circumflex 3 /tilde 4/macron 5/breve 6/dotaccent 7/dieresis 8/ring 9/cedilla 10 /hungarumlaut 11/ogonek 12/caron 13/dotlessi 39/quotesingle 96/grave 124/bar 130/quotesinglbase 131/florin 132/quotedblbase 133/ellipsis 134/dagger 135 /daggerdbl 136/circumflex 137/perthousand 138/Scaron 139/guilsinglleft 140/OE 145/quoteleft 146/quoteright 147/quotedblleft 148/quotedblright 149/bullet 150 /endash 151/emdash 152/tilde 153/trademark 154/scaron 155/guilsinglright 156 /oe 159/Ydieresis 160/space 161/exclamdown 164/currency 165/yen 166/brokenbar 167/section 168/dieresis 169/copyright 170/ordfeminine 171/guillemotleft 172 /logicalnot 173/hyphen 174/registered 175/macron 176/degree 177/plusminus 178 /twosuperior 179/threesuperior 180/acute 181/mu 182/paragraph 183 /periodcentered 184/cedilla 185/onesuperior 186/ordmasculine 187 /guillemotright 188/onequarter 189/onehalf 190/threequarters 191/questiondown 192/Agrave 193/Aacute 194/Acircumflex 195/Atilde 196/Adieresis 197/Aring 198 /AE 199/Ccedilla 200/Egrave 201/Eacute 202/Ecircumflex 203/Edieresis 204 /Igrave 205/Iacute 206/Icircumflex 207/Idieresis 208/Eth 209/Ntilde 210/Ograve 211/Oacute 212/Ocircumflex 213/Otilde 214/Odieresis 215/multiply 216/Oslash 217/Ugrave 218/Uacute 219/Ucircumflex 220/Udieresis 221/Yacute 222/Thorn 223 /germandbls 224/agrave 225/aacute 226/acircumflex 227/atilde 228/adieresis 229 /aring 230/ae 231/ccedilla 232/egrave 233/eacute 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F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{rF}{3 copyfont}? ` /OrigFontType ~ |/OrigFontName ~ | & E 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/xF{scalefont Pscript_Windows_Font 3 1 $ put}b/xMF{mFM astore makefont Pscript_Windows_Font 3 1 $ put}b/xF2/scalefont , |/xMF2{mFM astore makefont}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/sSU{N/uW ~ |/yUP ~ |/xUP ~ |}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ |/ySP ~ |/xSP ~ |}b/sT{xSP ySP sW sLT}b/sR{: + R 0 0 M}b /sRxy{: matrix astore concat 0 0 M}b/eR/; , | /mBF{@ 4 copyfont `/FontName ~ |/OrigFontType ~ |/OrigFontName ~ | 0 FontMatrix idtransform ! &/PaintType known{PaintType 0 eq{/PaintType 2 | /StrokeWidth ~ |}{PaintType 1 eq PaintType 2 eq or PaintType 3 eq or & /StrokeWidth known and{StrokeWidth add/StrokeWidth ~ |}{!}?}?}{!}? @ & E definefont Pscript_Windows_Font 3 1 $ put}b/xBF{Pscript_Windows_Font ` 1 ^ /FontName get 1 ^ scalefont 3 1 $ scalefont 2 copy ~ | ~ ! | E}b/xMBF{mFM astore Pscript_Windows_Font ` 1 ^/FontName get 1 ^ makefont 3 1 $ makefont 2 copy ~ | ~ ! | E}b/xBF2{/sB0 ~ mBF/sB1 sB0 3 -1 $ xBF sB1}b/xMBF2{/sB0 ~ mBF mFM astore/sB1 sB0 3 -1 $ xMBF sB1}b/sB{: Pscript_Windows_Font currentfont get Ji @ S ; S}b/asB{: Pscript_Windows_Font currentfont get Ji 3 copy A ; A}b/wsB{ : Pscript_Windows_Font currentfont get Ji 4 copy W ; W}b/awsB{: Pscript_Windows_Font currentfont get Ji 6 copy D ; D}b/sBT3{: @ S ; 1 1 -M S}b /asBT3{: 3 copy A ; 1 1 -M A}b/wsBT3{: 4 copy W ; 1 1 -M W}b/awsBT3{: 6 copy D ; 1 1 -M D}b/mIF{iMat 4 3 -1 $ put 2 copyfont `/OrigFontType ~ |/OrigFontName ~ | @ & E definefont iMat makefont Pscript_Windows_Font 3 1 $ put}b /SavedCTM null |/CTMsave{/SavedCTM SavedCTM currentmatrix |}b/CTMrestore{ SavedCTM setmatrix}b/mp null |/ADO_mxRot null |/GDIHMatrix null | /GDIHPatternDict 22 dict | GDIHPatternDict `/PatternType 1 |/PaintType 2 | /Reps L2?{1}{5}? |/XStep 8 Reps mul |/YStep XStep |/BBox[0 0 XStep YStep]| /TilingType 1 |/PaintProc{` 1 Lw[]0 setdash PaintData , exec E}b/FGnd null | /BGnd null |/HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b /HS_BDiagonal{biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? |/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b/vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag {Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E /makehatch{GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0/HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{ /h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5/HS_DiagCross makehatch}b/GDIBWPatternDict 17 dict @ `/PatternType 1 |/PaintType L2?{1}{2}? |/RepsV L2?{1}{6}? |/RepsH L2?{1}{5}? |/BBox[0 0 RepsH 1]|/TilingType 1 | /XStep 1 |/YStep 1 |/Height 8 RepsV mul |/Width 8 |/mx[Width 0 0 Height neg 0 Height]|/FGnd null |/BGnd null |/SetBGndFGnd L2?{{BGnd null ne{BGnd aload ! sgco BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! sgco}if} }{{}}? b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E |/GDIBWPatternMx null |/pfprep{save 4 1 $ /PatternOfTheDay 4 1 $ GDIBWPatternDict `/PaintData ~ |/BGnd ~ |/FGnd ~ | E CTMsave GDIBWPatternMx setmatrix GDIBWPatternDict matrix mp CTMrestore ~ !}b /hrf null |/prf{pfprep ~ 6 1 $ 5 hrf restore}b/GraphInit{GDIHMatrix null eq{ /SavedCTM matrix | : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly | ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E dsnap +S/GDIBWPatternMx matrix currentmatrix readonly | ; ;}if}b/cirp{360 0 An C}b/ellp{CTMsave + +S 0.5 0 M 0 0 0.5 360 0 An C CTMrestore}b/rrp{/rad ~ |/y2 ~ |/x2 ~ |/y1 ~ |/x1 ~ | x2 x1 add 2 V y1 M x1 y1 x1 y2 rad arct x1 y2 x2 y2 rad arct x2 y2 x2 y1 rad arct x2 y1 x1 y1 rad arct C}b/RRp{CTMsave + +S/dyS ~ |/dxS ~ | dxS 2 V 0 M 0 0 0 dyS 0.5 arct 0 dyS dxS dyS 0.5 arct dxS dyS dxS 0 0.5 arct dxS 0 0 0 0.5 arct C CTMrestore}b L2? not g{/arct{arcto ! ! ! !}b/GDIpattfill{@ ` BGnd null ne PaintType 2 eq and{: BGnd aload ! sgco fEOFill{O}{L}? ; FGnd aload ! U/fGray 2 ^ put{2}{4}? -1 $}if E @ patterncalc : 4 ^/PaintType get 2 eq{fGray{6 -1 $ sg}{8 -3 $ sco}? }if fEOFill{eoclip}{clip}? N patternfill ; N}b/hrf{/fGray 1 ^ 6 eq | -4 $ N rp C/fEOFill F | GDIpattfill}b/hfMain{/fEOFill ~ |/fGray ~ | GDIpattfill}b/hf{T hfMain}b/hfW{F hfMain}b/hs{currentpoint strokepath M hfW}b/pfMain{/fEOFill ~ | pfprep GDIpattfill restore N}b/pf{T pfMain}b/pfW{F pfMain}b/ps{currentpoint strokepath M pfW}b/mpstr 1 string |/mp{~ @ length 12 add dict copy ` /PatternCTM matrix currentmatrix |/PatternMatrix ~ |/PatWidth XStep mpstr length mul |/PatHeight YStep |/FontType 3 |/Encoding 256 array | 3 string 0 1 255{Encoding ~ @ 3 ^ cvs cvn put}for !/FontMatrix matrix |/FontBBox BBox | /BuildChar{! @ ` XStep 0 FontBBox aload ! setcachedevice/PaintProc , E : exec ;}b & E ~ @ 3 -1 $ definefont}b/patterncalc{` : PatternCTM setmatrix PatternMatrix concat BBox aload ! ! ! + pathbbox ; PatHeight V ceiling 4 1 $ PatWidth V ceiling 4 1 $ PatHeight V floor 4 1 $ PatWidth V floor 4 1 $ 2 ^ sub cvi abs ~ 3 ^ sub cvi abs ~ 4 2 $ PatHeight mul ~ PatWidth mul ~ E}b /patternfill{5 -1 $ @ ` Ji PatternCTM setmatrix PatternMatrix concat 0 2 ^ 2 ^ M 0 1 mpstr length 1 sub{1 ^ mpstr 3 1 $ put}for ! 2 ^{currentpoint 5 ^{mpstr S}repeat YStep add M}repeat ! ! ! ! E}b}e L2? g{/mp/makepattern , |/hrf{6 eq setAorABC setpattern rectfill}b/hf{ setAorABC setpattern O}b/hfW{setAorABC setpattern L}b/hs{setAorABC setpattern K}b/pf{pfprep setpattern O restore N}b/pfW{pfprep setpattern L restore N}b/ps{ pfprep setpattern K restore N}b}e /iw 0 |/ih 0 |/im_save 0 |/s 0 |/polarity 0 |/smoothflag 0 |/mystring 0 |/bpc 0 |/setup1asciiproc{[currentfile mystring/readhexstring cvx/! cvx]cvx bind}b /setup1binaryproc{[currentfile mystring/readstring cvx/! cvx]cvx bind}b /setup2asciiproc{currentfile/ASCII85Decode filter/RunLengthDecode filter}b /setup2binaryproc{currentfile/RunLengthDecode filter}b/mycolorspace{colspABC}| /myimagedict{/myimagedict 10 dict | myimagedict @ `/ImageType 1 | /MultipleDataSource F | E}b/imageprocarray[/setup1binaryproc/setup1asciiproc /setup2binaryproc/setup2asciiproc/setup1binarydecodeproc/setup1asciidecodeproc ]|/L2Polarity{{[1 0]}{[0 1]}?}b/Q{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/X{/im_save save | imageprocarray ~ get/s ~ , | L2Polarity/polarity ~ |/smoothflag ~ | snap +/dx 2 ^ |/dy 1 ^ | +S/mystring ~ string |/bpc ~ |/ih ~ |/iw ~ |}b/Z{im_save restore}b/Y{sgco myimagedict @ ` /Width iw |/Height ih |/Decode polarity |/ImageMatrix[iw 0 0 ih 0 0]| /DataSource s |/BitsPerComponent 1 |/Interpolate smoothflag | E imagemask}b L2? not g{/setup2asciiproc{[/Level2ImagesError , aload ! T FatalErrorIf}b /setup2binaryproc/setup2asciiproc , |/L2Polarity{}|/Y{sgco iw ih polarity[iw 0 0 ih 0 0]s imagemask}b}e L2? not g{/testsystemdict{where{systemdict eq{T}{F}?}{F}?}b/c 1 |/colorimage where{! T}{F}?{/c 0 statusdict `/processcolors where{! ! processcolors}{ /deviceinfo where{! deviceinfo/Colors known{!{deviceinfo/Colors get}}if}if}? E | c 0 ne{/colorimage testsystemdict/setcolortransfer testsystemdict /currentcolortransfer testsystemdict/currentcmykcolor testsystemdict and and and not{/c 0 |}if}if}if c @ 1 ne ~ @ 3 ne ~ 4 ne and and{/c 0 |}if c 1 eq g{ /expandbw{expandfactor mul round cvi bwclut ~ get 255 V}b/doclutimage{!/bwclut ~ | bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/expandfactor ~ |[/expandbw ,/exec , @ currenttransfer ~]cvx bind settransfer iw ih bpc[iw 0 0 ih 0 0]s image}b}e c @ 3 eq ~ 4 eq or g{/nullproc{{}}|/concatutil{/exec , 7 -1 $/exec ,}b/defsubclut{ 1 add getinterval |}b/spconcattransfer{/Dclut ~ |/Cclut ~ |/Bclut ~ |/Aclut ~ |/ncompute ~ , | currentcolortransfer[{Aclut ncompute}concatutil]cvx[{Bclut ncompute}concatutil]cvx[{Cclut ncompute}concatutil]cvx[{Dclut ncompute} concatutil]cvx setcolortransfer}b/setuprgbcluts{/bit3x rgbclut length 3 sub | /bit1x bit3x 3 idiv |/rclut rgbclut |/gclut rclut 1 bit3x defsubclut/bclut rclut 2 bit3x defsubclut}b}e c 3 eq g{/3compute{~ bit3x mul round cvi get 255 V}b/doclutimage{/rgbclut ~ | ! setuprgbcluts/3compute rclut gclut bclut @ spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @]cvx nullproc nullproc T 3 colorimage}b}e c 4 eq g{/ftoint{1 ~ sub 255 mul round cvi}b/stuffclut{ cmykindex 3 -1 $ put}b/4compute{~ bit4x mul round cvi get 255 V}b /invalidcolortable? T |/computecmykclut{setuprgbcluts/bit4x rgbclut length 3 idiv 4 mul 4 sub |/cmykclut bit4x 4 add string |/cclut cmykclut |/mclut cclut 1 bit4x defsubclut/yclut cclut 2 bit4x defsubclut/kclut cclut 3 bit4x defsubclut/cmykindex 0 | 0 1 bit1x{@/cmykindex ~ bit1x ~ sub 4 mul | 3 mul @ rclut ~ get 255 V ~ @ gclut ~ get 255 V ~ bclut ~ get 255 V setrgbcolor currentcmykcolor ftoint kclut stuffclut ftoint yclut stuffclut ftoint mclut stuffclut ftoint cclut stuffclut}for}b/doclutimage{/rgbclut ~ | ! invalidcolortable?{computecmykclut}if/4compute cclut mclut yclut kclut spconcattransfer iw ih bpc[iw 0 0 ih 0 0][s/exec ,/@ , @ @]cvx nullproc nullproc nullproc T 4 colorimage}b}e c 0 eq g{/a{3 mul 3 getinterval putinterval ~ 3 add ~ 3 copy}b/8lookup/a , |/4lookup{/byte 1 ^ | -4 bitshift a byte 15 and a}b/2lookup{/byte 1 ^ | -6 bitshift a byte -4 bitshift 3 and a byte -2 bitshift 3 and a byte 3 and a}b/colorexpand{mystringexp 0 rgbclut 3 copy 7 -1 $/mylookup , forall ! ! ! ! !}b/createexpandstr{/mystringexp ~ mystring length mul string |}b/doclutimage{/rgbclut ~ | !/mylookup bpc 8 eq{3 createexpandstr/8lookup}{bpc 4 eq{6 createexpandstr/4lookup}{12 createexpandstr/2lookup}?}? , | iw ih bpc[iw 0 0 ih 0 0][s/exec ,/colorexpand ,/exec ,]cvx F 3 colorimage}b}e/colorimage where{! T}{F}? g{/do24image{iw ih 8 [iw 0 0 ih 0 0]s F 3 colorimage}b}DefIf_El{/rgbtogray{/str ~ |/len str length |/smlen len 3 idiv |/rstr str |/gstr str 1 len 1 sub getinterval |/bstr str 2 len 2 sub getinterval | str @ 0 1 smlen 1 sub{@ 3 mul rstr 1 ^ get 0.3 mul gstr 2 ^ get 0.59 mul add bstr 3 -1 $ get 0.11 mul add round cvi put @}for ! 0 smlen getinterval}b/do24image{iw ih 8[iw 0 0 ih 0 0][s/exec ,/rgbtogray ,/exec ,]cvx bind image}b}e/doNimage{bpc 24 eq{do24image}{iw ih bpc[iw 0 0 ih 0 0]s image}?}b}e L2? g{/doclutimage{/rgbclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[ /Indexed colspABC hival rgbclut]setcolorspace myimagedict @ `/Width iw | /Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s | /BitsPerComponent bpc |/Interpolate smoothflag | E image}b/doCMYKclutimage{ /CMYKclut ~ | ! bpc @ 8 eq{! 255}{4 eq{15}{3}?}?/hival ~ |[/Indexed/DeviceCMYK hival CMYKclut]setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 hival]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc | /Interpolate smoothflag | E image}b/doNimage{bpc 24 eq{colspABC}{colspA}? setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode bpc 24 eq{[0 1 0 1 0 1]}{[0 1]}? |/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent bpc 24 eq{8}{bpc}? |/Interpolate smoothflag | E image}b/doCMYKimage{ /DeviceCMYK setcolorspace myimagedict @ `/Width iw |/Height ih |/Decode[0 1 0 1 0 1 0 1]|/ImageMatrix[iw 0 0 ih 0 0]|/DataSource s |/BitsPerComponent 8 | /Interpolate smoothflag | E image}b}e /GreNewFont{10 dict @ 3 1 $ | @ ` 4 1 $/FontType 3 |/FontMatrix ~ |/FontBBox ~ |/Encoding 256 array | 0 1 255{Encoding ~/.notdef put}for/CharProcs 257 dict | CharProcs/.notdef{}put/Metrics 257 dict | Metrics/.notdef 3 -1 $ put/BuildChar {/char ~ |/fontdict ~ |/charname fontdict/Encoding get char get | fontdict /Metrics get charname get aload ! setcachedevice fontdict ` Encoding char get CharProcs ~ get E exec}| E definefont !}|/AddChar{` Encoding 3 1 $ put CharProcs 3 1 $ put Metrics 3 1 $ put E}| /FEbuf 2 string |/FEglyph 3 string |/FE{(G00)FEglyph copy ! 1 ~{@ 16 lt{ /offset 2 store}{/offset 1 store}? @ 16 FEbuf cvrs FEglyph ~ offset ~ putinterval 1 ^ ~ FEglyph cvn put}for}bind |/Type1Hdr{11 dict `/FontName ~ | /PaintType ~ |/FontType 1 |/FontMatrix[1 3 ^ V 0 0 1 6 ^ V 0 0]| !/Encoding 256 array 0 1 255{1 ^ ~/.notdef put}for 3 ^ 3 ^ FE | ! !/FontBBox{0 0 0 0}| & E currentfile eexec}bind | /pp 1 string |/ss 1 string |/rledecodebinary{/DC 0 |/BC 0 |{DC mystring length ge{exit}if currentfile ss readstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{ mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/rledecodeascii{/DC 0 | /BC 0 |{DC mystring length ge{exit}if currentfile ss readhexstring ! 0 get/BC ~ | BC 127 le{/BC BC 1 add | DC 1 DC BC add 1 sub{mystring ~ currentfile ss readhexstring ! 0 get put}for}{/BC 257 BC sub | currentfile ss readhexstring ! 0 get/pp ~ | DC 1 DC BC add 1 sub{mystring ~ pp put}for}?/DC DC BC add |}loop mystring}b/setup1asciidecodeproc{[/rledecodeascii cvx]cvx bind}b /setup1binarydecodeproc{[/rledecodebinary cvx]cvx bind}b userdict/Pscript_Win_Compat 13 dict dup begin/bd{bind def}bind def/ld{load def }bd/CB{pop pop pop pop}bind def/B{pop pop pop pop}bind def/$x matrix def/SS{ /pagesave save def}bind def/RS{/pagesave where{pop pagesave restore}{$x matrix invertmatrix concat}ifelse}bind def/ANSIVec[0/grave 1/acute 2/circumflex 3 /tilde 4/macron 5/breve 6/dotaccent 7/dieresis 8/ring 9/cedilla 10 /hungarumlaut 11/ogonek 12/caron 13/dotlessi 39/quotesingle 96/grave 124/bar 130/quotesinglbase 131/florin 132/quotedblbase 133/ellipsis 134/dagger 135 /daggerdbl 136/circumflex 137/perthousand 138/Scaron 139/guilsinglleft 140/OE 145/quoteleft 146/quoteright 147/quotedblleft 148/quotedblright 149/bullet 150 /endash 151/emdash 152/tilde 153/trademark 154/scaron 155/guilsinglright 156 /oe 159/Ydieresis 160/space 161/exclamdown 164/currency 165/yen 166/brokenbar 167/section 168/dieresis 169/copyright 170/ordfeminine 171/guillemotleft 172 /logicalnot 173/hyphen 174/registered 175/macron 176/degree 177/plusminus 178 /twosuperior 179/threesuperior 180/acute 181/mu 182/paragraph 183 /periodcentered 184/cedilla 185/onesuperior 186/ordmasculine 187 /guillemotright 188/onequarter 189/onehalf 190/threequarters 191/questiondown 192/Agrave 193/Aacute 194/Acircumflex 195/Atilde 196/Adieresis 197/Aring 198 /AE 199/Ccedilla 200/Egrave 201/Eacute 202/Ecircumflex 203/Edieresis 204 /Igrave 205/Iacute 206/Icircumflex 207/Idieresis 208/Eth 209/Ntilde 210/Ograve 211/Oacute 212/Ocircumflex 213/Otilde 214/Odieresis 215/multiply 216/Oslash 217/Ugrave 218/Uacute 219/Ucircumflex 220/Udieresis 221/Yacute 222/Thorn 223 /germandbls 224/agrave 225/aacute 226/acircumflex 227/atilde 228/adieresis 229 /aring 230/ae 231/ccedilla 232/egrave 233/eacute 234/ecircumflex 235/edieresis 236/igrave 237/iacute 238/icircumflex 239/idieresis 240/eth 241/ntilde 242 /ograve 243/oacute 244/ocircumflex 245/otilde 246/odieresis 247/divide 248 /oslash 249/ugrave 250/uacute 251/ucircumflex 252/udieresis 253/yacute 254 /thorn 255/ydieresis]def currentdict{dup type/operatortype eq{[exch]cvx def}{ pop pop}ifelse}forall/initialize{currentdict exch begin begin}bind def /terminate{/@FL where not{pop end end}{pop}ifelse}bind def/suspend/terminate load def/resume/initialize load def/M/moveto load def end put/Courier findfont 10 scalefont setfont end /ProcSet defineresource pop Pscript_Win_Compat dup /initialize get exec [ 0 1.000 -1.000 0 0 0 ] false /Pscript_Win_Driver /ProcSet findresource dup /initialize get exec /mysetup [ 0.120 0 0 -0.120 0.960 594.960 ] | userdict begin /pagesave save def end mysetup concat colspRefresh : 1.000 1.000 1.000 sco 0 0 4958 7016 rf ; 999 677 N M 5581 3464 rr 999 677 N M 5582 3465 rr 16 Lw 0 Lc 0 Lj solid 0 0 0 sco K 999 677 N M 0 3464 - 1 Lc 1 Lj 0 0 0 sco K 999 4141 N M 59 0 - 0 0 0 sco K 999 3448 N M 59 0 - 0 0 0 sco K 999 2755 N M 59 0 - 0 0 0 sco K 999 2063 N M 59 0 - 0 0 0 sco K 999 1370 N M 59 0 - 0 0 0 sco K 999 677 N M 59 0 - 0 0 0 sco K 999 4141 N M 5581 0 - 0 0 0 sco K 999 4141 N M 0 -44 - 0 0 0 sco K 1464 4141 N M 0 -44 - 0 0 0 sco K 1929 4141 N M 0 -44 - 0 0 0 sco K 2394 4141 N M 0 -44 - 0 0 0 sco K 2859 4141 N M 0 -44 - 0 0 0 sco K 3324 4141 N M 0 -44 - 0 0 0 sco K 3790 4141 N M 0 -44 - 0 0 0 sco K 4255 4141 N M 0 -44 - 0 0 0 sco K 4720 4141 N M 0 -44 - 0 0 0 sco K 5185 4141 N M 0 -44 - 0 0 0 sco K 5650 4141 N M 0 -44 - 0 0 0 sco K 6115 4141 N M 0 -44 - 0 0 0 sco K 6580 4141 N M 0 -44 - 0 0 0 sco K 999 4141 N M 0 -59 - 0 0 0 sco K 1929 4141 N M 0 -59 - 0 0 0 sco K 2859 4141 N M 0 -59 - 0 0 0 sco K 3790 4141 N M 0 -59 - 0 0 0 sco K 4720 4141 N M 0 -59 - 0 0 0 sco K 5650 4141 N M 0 -59 - 0 0 0 sco K 6580 4141 N M 0 -59 - 0 0 0 sco K 6577 3971 N M -97 -56 - 1 17 - 97 56 - -1 -17 - C : 0 0 0 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Fr(J.A.)k(White,)g(D.M.)g(Bird,)h(M.C.)g(P)n(a)n(yne,)f(I.)f(Stic)n(h,) h(Ph)n(ys.)g(Rev.)2129 2155 y(Lett.)26 b Fn(73)p Fr(,)g(1404)h (\(1994\).)2047 2214 y Fq(10)2129 2246 y Fr(G.)18 b(Wiesenekk)n(er,)i (G.J.)g(Kro)r(es,)g(E.J.)g(Baerends,)h(J.)d(Chem.)g(Ph)n(ys.)2129 2338 y Fn(104)p Fr(,)26 b(7344)h(\(1996\).)2047 2397 y Fq(11)2129 2429 y Fr(R.A.)37 b(Olsen,)j(G.J.)e(Kro)r(es,)j(E.J.)e (Baerends,)i(J.)d(Chem.)e(Ph)n(ys.)2129 2520 y Fn(111)p Fr(,)26 b(11155)i(\(1999\).)2047 2580 y Fq(12)2129 2612 y Fr(A.)g(Gro\031,)i(S.)e(Wilk)n(e,)h(and)e(M.)i(Sc)n(he\017er,)g(Ph)n (ys.)f(Rev.)f(Lett.)h Fn(75)p Fr(,)2129 2703 y(2718)f(\(1995\).)2047 2762 y Fq(13)2129 2794 y Fr(A.)e(Gro\031)i(and)e(M.)i(Sc)n(he\017er,)e (Ph)n(ys.)h(Rev.)f(B)h Fn(57)p Fr(,)g(2493)h(\(1998\).)2047 2854 y Fq(14)2129 2886 y Fr(A.)g(Eic)n(hler,)j(J.)e(Hafner,)h(A.)f (Gro\031,)i(M.)e(Sc)n(he\013er,)h(Ph)n(ys.)e(Rev.)h(B)2129 2977 y Fn(59)p Fr(,)e(13297)i(\(1999\).)2047 3036 y Fq(15)2129 3068 y 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Fr(J.)f(Dai,)g(and)g(J.C.)h(Ligh)n(t,)f(J.)g (Chem.)g(Ph)n(ys.)f Fn(108)p Fr(,)i(7816)g(\(1998\).)2047 4041 y Fq(22)2129 4073 y Fr(R.A.)38 b(Olsen,)43 b(G.J.)d(Kro)r(es,)j (O.M.L\034vvik,)f(E.J.)e(Baerends,)j(J.)2129 4164 y(Chem.)25 b(Ph)n(ys.)g Fn(107)p Fr(,)i(10652)h(\(1997\).)2047 4224 y Fq(23)2129 4255 y Fr(K.D.)h(Rendulic,)h(G.)g(Anger)g(and)f(A.)g (Winkler,)i(Surf.)e(Sci.)h Fn(208)p Fr(,)2129 4347 y(404)d(\(1989\).) 2047 4406 y Fq(24)2129 4438 y Fr(K.D.)18 b(Rendulic,)h(A.)f(Winkler,)i (Surf.)e(Sci.)g Fn(299/300)p Fr(,)j(261)e(\(1994\).)2047 4498 y Fq(25)2129 4529 y Fr(M.)26 b(Gostein,)h(G.O.)f(Sitz,)g(J.)g (Chem.)g(Ph)n(ys.)f Fn(106)p Fr(,)i(7378)g(\(1997\).)2047 4589 y Fq(26)2129 4621 y Fr(G.)f(Comsa,)h(R.)e(Da)n(vid,)h(and)f(B.-J.) i(Sc)n(h)n(umac)n(her,)d(Surf.)i(Sci.)g Fn(95)p Fr(,)2129 4712 y(L210)h(\(1980\).)2047 4772 y Fq(27)2129 4803 y Fr(C.T.)39 b(Rettner,)i(D.J.)d(Auerbac)n(h,)i(C.)f(T)-6 b(ully)g(,)41 b(A.W.)d(Kleyn,)i(J.)2129 4895 y(Chem.)25 b(Ph)n(ys.)g Fn(100)p Fr(,)i(13021)h(\(1996\).)2047 4954 y Fq(28)2129 4986 y Fr(L.)i(Sc)n(hr\177)-38 b(oter,)32 b(S.)e(K)r(\177)-41 b(uc)n(henho\013,)31 b(R.)f(Da)n(vid,)h(W.)g (Brenig,)h(and)e(H.)2129 5077 y(Zac)n(harias,)d(Surf.)f(Sci.)g Fn(261)p Fr(,)g(243)h(\(1992\).)2047 5137 y Fq(29)2129 5169 y Fr(D.)22 b(W)-6 b(etzig,)24 b(M.)g(Rutk)n(o)n(wski,)f(H.)f(Zac)n (harias,)j(ph)n(ys.)d(stat.)i(sol.)g(\(a\))2129 5260 y Fn(159)p Fr(,)i(263)h(\(1997\).)2047 5320 y Fq(30)2129 5351 y Fr(B.E.)33 b(Ha)n(yden,)g(C.L.A.)g(Lamon)n(t,)g(Ph)n(ys.)f(Rev.) g(Lett.)g Fn(63)p Fr(,)j(1823)1946 5608 y Ft(8)p eop %%Page: 9 9 9 8 bop -63 -83 a Fr(\(1989\).)-145 -23 y Fq(31)-63 8 y Fr(G.)28 b(Anger,)f(A.)g(Winkler,)h(and)f(K.D.)g(Rendulic,)h(Surf.)f (Sci.)g Fn(220)p Fr(,)-63 100 y(1)f(\(1989\).)-145 159 y Fq(32)-63 191 y Fr(H.F.)c(Berger)h(and)f(K.D.)g(Rendulic,)g(Surf.)h (Sci.)f Fn(253)p Fr(,)i(325)f(\(1991\).)-145 251 y Fq(33)-63 282 y Fr(C.T.)29 b(Rettner,)f(D.J.)g(Auerbac)n(h,)g(H.A.)g(Mic)n (helsen,)h(Ph)n(ys.)f(Rev.)-63 374 y(Lett.)e Fn(68)p Fr(,)g(1164)h(\(1992\).)-145 433 y Fq(34)-63 465 y Fr(H.A.)32 b(Mic)n(helsen,)k(C.T.)e(Rettner,)f(D.J.)g(Auerbac)n(h,)h(Surf.)f (Sci.,)-63 556 y Fn(272)p Fr(,)26 b(65)h(\(1992\))-145 616 y Fq(35)-63 648 y Fr(C.T.)37 b(Rettner,)g(H.A.)e(Mic)n(helsen,)k (D.J.)d(Auerbac)n(h,)i(J.)e(Chem.)-63 739 y(Ph)n(ys.)25 b Fn(102)p Fr(,)i(4625)g(\(1996\))-145 798 y Fq(36)-63 830 y Fr(E.)22 b(W)-6 b(atts,)23 b(and)e(G.O.)h(Sitz,)h(J.)f(Chem.)g (Ph)n(ys.)f Fn(111)p Fr(,)j(9791)f(\(1999\).)-145 890 y Fq(37)-63 922 y Fr(L.)f(Sc)n(hr\177)-38 b(oter,)23 b(Chr.)g(T)-6 b(rame,)23 b(R.)f(Da)n(vid,)g(H.)g(Zac)n(harias,)j(Surf.) d(Sci.)-63 1013 y Fn(272)p Fr(,)k(229)h(\(1992\))-145 1072 y Fq(38)-63 1104 y Fr(L.)34 b(Sc)n(hr\177)-38 b(oter,)36 b(R.)e(Da)n(vid,)h(and)f(H.)g(Zac)n(harias,)j(Surf.)d(Sci.)g Fn(258)p Fr(,)-63 1196 y(259)27 b(\(1991\).)-145 1255 y Fq(39)-63 1287 y Fr(L.)g(Sc)n(hr\177)-38 b(oter,)28 b(H.)e(Zac)n(harias,)j(and)e(R.)g(Da)n(vid,)g(Ph)n(ys.)g(Rev.)f(Lett.) -63 1378 y Fn(62)p Fr(,)g(571)h(\(1989\).)-145 1438 y Fq(40)-63 1469 y Fr(A.)39 b(Gro\031)h(and)f(M.)h(Sc)n(he\017er,)i (Chem.)d(Ph)n(ys.)g(Lett.)g Fn(256)p Fr(,)k(417)-63 1561 y(\(1996\).)-145 1620 y Fq(41)-63 1652 y Fr(G.)28 b(Comsa,)h(R.)f(Da)n (vid)f(and)h(B.)g(J.)h(Sc)n(h)n(umac)n(her,)d(Surf.)i(Sci.)h Fn(85)p Fr(,)-63 1743 y(45)d(\(1979\).)-145 1803 y Fq(42)-63 1835 y Fr(E.)18 b(F)-6 b(romm,)18 b(E.)g(Gebhard,)h Fs(Gase)j(und)e (Kohlensto\013e)i(in)e(Metal)t(len)p Fr(,)-63 1926 y(Springer,)26 b(Berlin,)h(1976.)-145 1986 y Fq(43)-63 2017 y Fr(G.)d(Hilb)r(er,)h(A.) e(Lago)i(and)e(R.)h(W)-6 b(allenstein,)25 b(J.)f(Opt.)f(So)r(c.)i(Am)d (B)-63 2109 y Fn(4)p Fr(,)k(1753)h(\(1987\).)-145 2168 y Fq(44)-63 2200 y Fr(W.)f(Meier,)i(H.)f(Rottk)n(e,)f(H.)g(Zac)n (harias,)i(K.H.)e(W)-6 b(elge,)28 b(J.)f(Chem.)-63 2291 y(Ph)n(ys.)e Fn(83)p Fr(,)i(4360)g(\(1985\).)-145 2351 y Fq(45)-63 2383 y Fr(W.)h(Meier,)i(H.)d(Rottk)n(e,)h(H.)g(Zac)n (harias,)i(Inst.)d(Ph)n(ys.)h(Conf.)h(Ser.)-63 2474 y(No.)d Fn(94)p Fr(,)g(93)h(\(1988\).)-145 2534 y Fq(46)-63 2565 y Fr(W.)f(Brenig,)h(T.)f(Brunner,)f(A.)h(Gro\031,)h(and)e(R.)g(Russ,)h (Z.)g(Ph)n(ys.)f(B)-63 2657 y Fn(93)p Fr(,)h(91)h(\(1993\).)-145 2716 y Fq(47)-63 2748 y Fr(D.)44 b(W)-6 b(etzig,)49 b(R.)43 b(Dopheide,)48 b(M.)d(Rutk)n(o)n(wski,)j(R.)43 b(Da)n(vid,)48 b(H.)-63 2839 y(Zac)n(harias,)27 b(Ph)n(ys.)f(Rev.)f(Lett.)h Fn(76)p Fr(,)g(463)h(\(1996\).)-145 2899 y Fq(48)-63 2931 y Fr(C.)14 b(H.)22 b(Greene,)i(R.)13 b(N.)23 b(Zare,)h(J.)f(Chem.) g(Ph)n(ys.,)g Fn(78)p Fr(,)h(6741)h(\(1983\).)-145 2990 y Fq(49)-63 3022 y Fr(D.)47 b(W)-6 b(etzig,)54 b(M.)48 b(Rutk)n(o)n(wski,)53 b(W.)47 b(Ettereic)n(h,)54 b(R.Da)n(vid,)e(H.)-63 3113 y(Zac)n(harias,)27 b(Surf.)f(Sci.)g Fn(402)p Fr(,)h(232)f (\(1998\).)-145 3173 y Fq(50)-63 3205 y Fr(M.)33 b(Beutl,)i(M.)e (Riedler,)h(K.D.)e(Rendulic,)i(Chem.)e(Ph)n(ys.)g(Lett.)-63 3296 y Fn(247)p Fr(,)26 b(249)h(\(1995\).)-145 3356 y Fq(51)-63 3387 y Fr(A.)c(Gro\031,)i(S.)e(Wilk)n(e,)h(M.)g(Sc)n (he\017er,)f(Surf.)g(Sci.)h Fn(357)p Fr(,)g(614)h(\(1996\).)-145 3447 y Fq(52)-63 3479 y Fr(M.)33 b(Beutl,)i(M.)e(Riedler,)h(K.D.)e (Rendulic,)i(Chem.)e(Ph)n(ys.)g(Lett.)-63 3570 y Fn(256)p Fr(,)26 b(33)h(\(1996\).)-145 3630 y Fq(53)-63 3661 y Fr(G.R.)h(Darling)h(and)f(S.)g(Hollo)n(w)n(a)n(y)-6 b(,)30 b(Rep.)e(Prog.)h(Ph)n(ys.)f Fn(58)p Fr(,)i(1595)-63 3753 y(\(1995\).)-145 3812 y Fq(54)-63 3844 y Fr(A.)25 b(Gro\031)i(and)e(M.) i(Sc)n(he\017er,)e(Prog.)i(Surf.)f(Sci.)g Fn(53)p Fr(,)h(187)f (\(1996\).)1946 5608 y Ft(9)p eop %%Trailer end userdict /end-hook known{end-hook}if %%EOF