%!PS-Adobe-2.0 %%Creator: dvips(k) 5.86 Copyright 1999 Radical Eye Software %%Title: H2Custrain.dvi %%Pages: 9 %%PageOrder: Ascend %%BoundingBox: 0 0 596 842 %%DocumentFonts: Times-Roman Times-Italic Symbol Helvetica-Bold %%DocumentPaperSizes: a4 %%EndComments %DVIPSWebPage: (www.radicaleye.com) %DVIPSCommandLine: dvips H2Custrain.dvi -o H2Custrain.ps %DVIPSParameters: dpi=600, compressed %DVIPSSource: TeX output 2002.08.07:1430 %%BeginProcSet: texc.pro %! /TeXDict 300 dict def TeXDict begin/N{def}def/B{bind def}N/S{exch}N/X{S N}B/A{dup}B/TR{translate}N/isls false N/vsize 11 72 mul N/hsize 8.5 72 mul N/landplus90{false}def/@rigin{isls{[0 landplus90{1 -1}{-1 1}ifelse 0 0 0]concat}if 72 Resolution div 72 VResolution div neg scale isls{ landplus90{VResolution 72 div vsize mul 0 exch}{Resolution -72 div hsize mul 0}ifelse TR}if Resolution VResolution vsize -72 div 1 add mul TR[ matrix currentmatrix{A A round sub abs 0.00001 lt{round}if}forall round exch round exch]setmatrix}N/@landscape{/isls true N}B/@manualfeed{ statusdict/manualfeed true put}B/@copies{/#copies X}B/FMat[1 0 0 -1 0 0] N/FBB[0 0 0 0]N/nn 0 N/IEn 0 N/ctr 0 N/df-tail{/nn 8 dict N nn begin /FontType 3 N/FontMatrix fntrx N/FontBBox FBB N string/base X array /BitMaps X/BuildChar{CharBuilder}N/Encoding IEn N end A{/foo setfont}2 array copy cvx N load 0 nn put/ctr 0 N[}B/sf 0 N/df{/sf 1 N/fntrx FMat N df-tail}B/dfs{div/sf X/fntrx[sf 0 0 sf neg 0 0]N df-tail}B/E{pop nn A definefont setfont}B/Cw{Cd A length 5 sub get}B/Ch{Cd A length 4 sub get }B/Cx{128 Cd A length 3 sub get sub}B/Cy{Cd A length 2 sub get 127 sub} B/Cdx{Cd A length 1 sub get}B/Ci{Cd A type/stringtype ne{ctr get/ctr ctr 1 add N}if}B/id 0 N/rw 0 N/rc 0 N/gp 0 N/cp 0 N/G 0 N/CharBuilder{save 3 1 roll S A/base get 2 index get S/BitMaps get S get/Cd X pop/ctr 0 N Cdx 0 Cx Cy Ch sub Cx Cw add Cy setcachedevice Cw Ch true[1 0 0 -1 -.1 Cx sub Cy .1 sub]/id Ci N/rw Cw 7 add 8 idiv string N/rc 0 N/gp 0 N/cp 0 N{ rc 0 ne{rc 1 sub/rc X rw}{G}ifelse}imagemask restore}B/G{{id gp get/gp gp 1 add N A 18 mod S 18 idiv pl S get exec}loop}B/adv{cp add/cp X}B /chg{rw cp id gp 4 index getinterval putinterval A gp add/gp X adv}B/nd{ /cp 0 N rw exit}B/lsh{rw cp 2 copy get A 0 eq{pop 1}{A 255 eq{pop 254}{ A A add 255 and S 1 and or}ifelse}ifelse put 1 adv}B/rsh{rw cp 2 copy get A 0 eq{pop 128}{A 255 eq{pop 127}{A 2 idiv S 128 and or}ifelse} ifelse put 1 adv}B/clr{rw cp 2 index string putinterval adv}B/set{rw cp fillstr 0 4 index getinterval putinterval adv}B/fillstr 18 string 0 1 17 {2 copy 255 put pop}for N/pl[{adv 1 chg}{adv 1 chg nd}{1 add chg}{1 add chg nd}{adv lsh}{adv lsh nd}{adv rsh}{adv rsh nd}{1 add adv}{/rc X nd}{ 1 add set}{1 add clr}{adv 2 chg}{adv 2 chg nd}{pop nd}]A{bind pop} forall N/D{/cc X A type/stringtype ne{]}if nn/base get cc ctr put nn /BitMaps get S ctr S sf 1 ne{A A length 1 sub A 2 index S get sf div put }if put/ctr ctr 1 add N}B/I{cc 1 add D}B/bop{userdict/bop-hook known{ bop-hook}if/SI save N @rigin 0 0 moveto/V matrix currentmatrix A 1 get A mul exch 0 get A mul add .99 lt{/QV}{/RV}ifelse load def pop pop}N/eop{ SI restore userdict/eop-hook known{eop-hook}if showpage}N/@start{ userdict/start-hook known{start-hook}if pop/VResolution X/Resolution X 1000 div/DVImag X/IEn 256 array N 2 string 0 1 255{IEn S A 360 add 36 4 index cvrs cvn put}for pop 65781.76 div/vsize X 65781.76 div/hsize X}N /p{show}N/RMat[1 0 0 -1 0 0]N/BDot 260 string N/Rx 0 N/Ry 0 N/V{}B/RV/v{ /Ry X/Rx X V}B statusdict begin/product where{pop false[(Display)(NeXT) (LaserWriter 16/600)]{A length product length le{A length product exch 0 exch getinterval eq{pop true exit}if}{pop}ifelse}forall}{false}ifelse end{{gsave TR -.1 .1 TR 1 1 scale Rx Ry false RMat{BDot}imagemask grestore}}{{gsave TR -.1 .1 TR Rx Ry scale 1 1 false RMat{BDot} imagemask grestore}}ifelse B/QV{gsave newpath transform round exch round exch itransform moveto Rx 0 rlineto 0 Ry neg rlineto Rx neg 0 rlineto fill grestore}B/a{moveto}B/delta 0 N/tail{A/delta X 0 rmoveto}B/M{S p delta add tail}B/b{S p tail}B/c{-4 M}B/d{-3 M}B/e{-2 M}B/f{-1 M}B/g{0 M} B/h{1 M}B/i{2 M}B/j{3 M}B/k{4 M}B/w{0 rmoveto}B/l{p -4 w}B/m{p -3 w}B/n{ p -2 w}B/o{p -1 w}B/q{p 1 w}B/r{p 2 w}B/s{p 3 w}B/t{p 4 w}B/x{0 S rmoveto}B/y{3 2 roll p a}B/bos{/SS save N}B/eos{SS restore}B end %%EndProcSet %%BeginProcSet: 8r.enc % @@psencodingfile@{ % author = "S. 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y(in)n(terest)d (since)h(it)g(migh)n(t)f(lead)h(to)f(the)h(impro)n(v)n(emen)n(t)f(of)g (cata-)-150 2261 y(lysts)k(in)h(a)g(systematic)f(w)n(a)n(y)f([1,)k(2)o (])e(.)58 b(In)35 b(particular,)g(the)g(ef-)-150 2356 y(fect)25 b(of)f(strain)g(on)g(the)h(surface)e(reactivit)n(y)h(has)g (curren)n(tly)f(b)r(een)-150 2452 y(the)28 b(sub)5 b(ject)28 b(of)f(sev)n(eral)f(studies)i([3)o({9)o(].)38 b(Substrate)27 b(strain)g(can)-150 2547 y(strongly)39 b(mo)r(dify)j(the)f(surface)f (reactivit)n(y)-7 b(,)43 b(as)d(has)g(recen)n(tly)-150 2643 y(b)r(een)26 b(sho)n(wn)g(exp)r(erimen)n(tally)f([3)o(,)i(4)o(].) 37 b(By)25 b(implemen)n(ting)i(sub-)-150 2738 y(surface)39 b(argon)f(bubbles)j(at)f(a)f(Ru\(0001\))g(surface,)k(laterally)-150 2834 y(stretc)n(hed)27 b(and)h(compressed)e(surface)h(regions)f(ha)n(v) n(e)g(b)r(een)i(cre-)-150 2929 y(ated.)35 b(STM)24 b(images)f (con\014rmed)g(that)h(o)n(xygen)e(atoms)g(and)i(CO)-150 3025 y(molecules)30 b(adsorb)g(preferen)n(tially)g(in)h(the)g(regions)f 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y(on)j(the)i(surfaces)d(compared)h(to)h(lo)n(w-index)e(single)i (crystal)e(sur-)-150 4196 y(faces.)36 b(Just)28 b(recen)n(tly)f(it)h (has)f(b)r(een)h(demonstrated)f(that)h(there)-150 4291 y(is)34 b(a)f(strong)f(correlation)g(b)r(et)n(w)n(een)h(the)h (catalytic)f(activit)n(y)g(of)-150 4387 y(binary)25 b(Cu/ZnO)g (catalysts)f(and)i(the)g(strain)f(of)h(copp)r(er)f(in)h(the)-150 4482 y(Cu/ZnO)36 b(system)i([7)o(].)66 b(Indeed,)41 b(densit)n(y)c (functional)g(theory)-150 4578 y(\(DFT\))43 b(calculations)e(of)h(the)h (adsorption)d(and)i(disso)r(ciation)-150 4673 y(of)36 b(O)18 4685 y Fm(2)90 4673 y Fu(on)g(Cu\(111\))f(b)n(y)h(Xu)g(and)g(Ma) n(vrik)-5 b(akis)33 b([6])j(con\014rmed)-150 4769 y(that)22 b(a)g(lattice)g(expansion)g(of)g(the)g(Cu\(111\))g(substrate)f(leads)h (to)-150 4864 y(higher)29 b(binding)h(energies)f(of)h(atomic)f(and)h (molecular)f(o)n(xygen)-150 4960 y(and)23 b(to)g(lo)n(w)n(er)e(O)381 4972 y Fm(2)441 4960 y Fu(disso)r(ciation)h(barriers.)33 b(Subsequen)n(t)23 b(molec-)-150 5055 y(ular)j(b)r(eam)h(exp)r(erimen)n (ts)g(found)g(that)h(uniaxial)e(tensile)h(stress)p -150 5224 300 4 v -150 5402 a Fl(\003)-114 5425 y Fp(Electronic)d(address:) 31 b Fk(agross@ph.tum.de)2042 1736 y Fu(enhances)36 b(the)g(disso)r (ciativ)n(e)f(adsorption)g(of)i(O)3592 1748 y Fm(2)3665 1736 y Fu(on)f(Cu\(100\))2042 1831 y(for)24 b(initial)i(kinetic)f (energies)f(b)r(elo)n(w)h(250)e(meV)j(but)f(suppresses)2042 1927 y(it)j(for)f(higher)g(kinetic)h(energies)e([9].)2125 2043 y(On)34 b(second)h(though)n(ts,)h(the)f(results)f(of)h(the)g(DFT)g (calcula-)2042 2138 y(tions)43 b(with)h(resp)r(ect)f(to)g(the)h(strain) f(e\013ects)g(in)h(the)g(o)n(xygen)2042 2234 y(adsorption)33 b(energies)g(and)i(barrier)e(heigh)n(ts)h(on)g(Cu\(111\))g(are)2042 2329 y(rather)f(surprising.)55 b(The)35 b Fn(d)p Fu(-band)f(of)g(copp)r (er)g(is)g(\014lled)g(whic)n(h)2042 2425 y(means)19 b(that)g(a)g(shift) h(of)f(the)h Fn(d)p Fu(-band)f(cen)n(ter)g(up)r(on)g(lattice)h(strain) 2042 2520 y(should)25 b(not)g(b)r(e)h(exp)r(ected.)37 b(Hence)25 b(the)h(usual)f(explanation)g(for)2042 2616 y(the)38 b(higher)g(reactivit)n(y)f(of)h(expanded)g(surfaces)f([5)o(,)k (11)o(])e(do)r(es)2042 2711 y(not)34 b(seem)g(to)h(b)r(e)g(applicable)e (to)i(copp)r(er)f(surfaces.)56 b(In)35 b(order)2042 2806 y(to)30 b(in)n(v)n(estigate)e(the)j(e\013ect)g(of)f(surface)f(strain)g (on)h(the)g(reactiv-)2042 2902 y(it)n(y)i(of)g(copp)r(er)g(surfaces)f (in)i(more)e(detail,)j(w)n(e)e(ha)n(v)n(e)f(extended)2042 2997 y(the)22 b(previous)f(study)h(b)n(y)g(Xu)h(and)e(Ma)n(vrik)-5 b(akis)21 b(b)n(y)g(determining)2042 3093 y(the)33 b(binding)g (energies)f(and)h(disso)r(ciation)f(barriers)f(of)i(h)n(ydro-)2042 3188 y(gen)h(on)g(clean)f(and)i(o)n(xygen)d(co)n(v)n(ered)h(copp)r(er)g (surfaces.)56 b(The)2042 3284 y(h)n(ydrogen/copp)r(er)23 b(system)i(has)g(serv)n(ed)f(as)h(a)g(b)r(enc)n(hmark)g(sys-)2042 3379 y(tem)38 b(for)f(the)i(study)f(of)f(the)i(in)n(teraction)e(of)g (molecules)h(with)2042 3475 y(surfaces,)28 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b(the)h(O\(2)p Fj(\002)p Fu(2\)/Cu\(100\))d(surface.)2125 4662 y(F)-7 b(or)33 b(all)h(considered)f(surfaces,)i(w)n(e)e(\014nd)i (an)f(upshift)h(of)f(the)2042 4757 y(cen)n(ter)d(of)g(the)h Fn(d)p Fu(-band)f(up)r(on)h(lattice)f(expansion.)47 b(Still)32 b(there)2042 4853 y(is)g(no)g(general)f(trend)h(in)h(the)g(h)n(ydrogen) e(adsorption)f(energies)2042 4948 y(as)25 b(a)h(function)h(of)f (lattice)g(strain)g(at)g(the)g(high-symmetry)f(sites)2042 5044 y(of)39 b(the)h(lo)n(w-index)e(Cu)i(surface)e(in)i(con)n(trast)e (to)h(the)h(predic-)2042 5139 y(tions)c(of)h(the)g Fn(d)p Fu(-band)f(mo)r(del)h([5].)64 b(In)37 b(order)e(to)i(understand)2042 5235 y(the)h(unexp)r(ected)g(b)r(eha)n(vior,)g(the)g Fn(d)p Fu(-band)f(cen)n(ter)g(shift)h Fi(up)l(on)2042 5330 y(adsorption)k Fu(has)33 b(also)g(to)h(b)r(e)h(tak)n(en)e(in)n(to) h(accoun)n(t.)55 b(F)-7 b(urther-)2042 5425 y(more,)30 b(the)g(disso)r(ciation)f(barriers)f(on)i(Cu\(111\))f(and)h(Cu\(100\))p eop %%Page: 2 2 2 1 bop 4043 -299 a Fu(2)-150 -83 y(also)29 b(sho)n(w)h(an)g(opp)r (osite)g(b)r(eha)n(vior)e(as)i(a)g(function)h(of)f(the)h(lat-)-150 12 y(tice)c(strain.)36 b(On)27 b(the)h(other)e(hand,)i(the)f(c)n(hange) f(in)h(the)h(h)n(ydro-)-150 108 y(gen)i(adsorption)e(energies)h(and)h (disso)r(ciation)e(barriers)g(on)i(the)-150 203 y(o)n(xygen-preco)n(v)n (ered)18 b(Cu\(100\))j(surface)h(can)f(b)r(e)i(simply)f(related)-150 299 y(to)29 b(the)h(increasing)e(h)n(ydrogen-o)n(xygen)e(distance)k(up) r(on)f(lattice)-150 394 y(expansion.)-67 495 y(This)i(article)f(is)g (structured)h(as)f(follo)n(ws.)45 b(After)31 b(a)g(brief)g(de-)-150 590 y(scription)19 b(of)g(the)h(theoretical)f(metho)r(dology)f(used)h (in)h(this)g(w)n(ork)-150 686 y(w)n(e)h(\014rst)g(discuss)f(the)i (electronic)e(structure)h(of)g(copp)r(er)g(surfaces)-150 781 y(as)g(a)h(function)g(of)g(the)h(lattice)f(strain)f(and)h(describ)r (e)g(the)g(predic-)-150 876 y(tions)30 b(of)g(the)g Fn(d)p Fu(-band)g(mo)r(del.)44 b(Then)30 b(the)h(calculated)e(adsorp-)-150 972 y(tion)i(energies)f(and)h(disso)r(ciation)g(barriers)e(will)i(b)r (e)h(presen)n(ted)-150 1067 y(in)k(detail)g(together)f(with)h(a)f (careful)h(analysis)e(of)i(the)g(under-)-150 1163 y(lying)k(electronic) f(structure.)74 b(The)40 b(pap)r(er)f(ends)h(with)h(some)-150 1258 y(concluding)27 b(remarks.)552 1560 y Fo(I)r(I.)89 b(METHODS)-67 1778 y Fu(The)30 b(DFT)g(calculations)e(ha)n(v)n(e)h(b)r (een)h(p)r(erformed)f(using)g(the)-150 1874 y(Vienna)35 b Fi(ab)i(initio)42 b Fu(sim)n(ulation)34 b(pac)n(k)-5 b(age)34 b(\(V)-9 b(ASP\))36 b([28)o(].)59 b(The)-150 1969 y(exc)n(hange-correlation)31 b(e\013ects)j(ha)n(v)n(e)g(b)r(een)g (describ)r(ed)h(within)-150 2065 y(the)24 b(generalized)d(gradien)n(t)h (appro)n(ximation)g(\(GGA\))i(using)f(the)-150 2160 y(P)n(erdew-W)-7 b(ang)30 b(\(PW-91\))i(functional)h([29)o(].)52 b(The)32 b(ionic)h(cores)-150 2255 y(are)22 b(represen)n(ted)g(b)n(y)h (ultrasoft)f(pseudop)r(oten)n(tials)g([30])h(as)f(con-)-150 2351 y(structed)d(b)n(y)f(G.)i(Kresse)d(and)i(J.)g(Hafner)f([31)o(].)34 b(A)20 b(cut-o\013)f(energy)-150 2446 y(of)32 b(235)f(eV)h(has)f(b)r (een)i(found)f(to)g(b)r(e)g(su\016cien)n(t)g(for)g(con)n(v)n(erged)-150 2542 y(results,)44 b(but)e(results)e(requiring)g(high)h(accuracy)e(ha)n (v)n(e)h(b)r(een)-150 2637 y(c)n(hec)n(k)n(ed)34 b(with)i(a)e(350)g(eV) h(cut-o\013.)60 b(The)35 b(calculated)g(equilib-)-150 2733 y(rium)g(lattice)g(constan)n(t,)h Fn(a)728 2745 y Fm(Cu)851 2733 y Fu(=)f(3)p Fn(:)p Fu(642)1175 2718 y(\027)1175 2733 y(A,)h(agrees)d(to)i(within)-150 2828 y(1\045)27 b(with)h(the)g(exp)r(erimen)n(tal)g(v)-5 b(alue)27 b(of)h(3.610)1342 2813 y(\027)1342 2828 y(A.)-67 2929 y(The)k(Cu)g(surfaces)f(are)g(mo)r(deled)i(b)n(y)e(a)h(slab)g(of)g (four)f(la)n(y)n(ers)-150 3024 y(for)38 b(the)h(\(111\))e(surface)h (and)g(\014v)n(e)g(la)n(y)n(ers)e(for)i(the)h(\(100\))f(and)-150 3120 y(\(110\))33 b(surfaces.)54 b(All)34 b(slabs)f(are)f(separated)g (b)n(y)i(12)1551 3105 y(\027)1551 3120 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0.3542 0.1768 l 0.3565 0.1768 l 0.3588 0.1768 l 0.3611 0.1769 l 0.3634 0.1770 l 0.3657 0.1772 l 0.3679 0.1776 l 0.3702 0.1782 l 0.3725 0.1791 l 0.3748 0.1803 l 0.3771 0.1818 l 0.3794 0.1838 l 0.3817 0.1861 l 0.3840 0.1888 l 0.3863 0.1920 l 0.3886 0.1955 l 0.3909 0.1993 l 0.3932 0.2034 l 0.3955 0.2078 l 0.3978 0.2122 l 0.4001 0.2167 l 0.4024 0.2212 l 0.4047 0.2255 l 0.4070 0.2296 l 0.4092 0.2334 l 0.4115 0.2369 l 0.4138 0.2399 l 0.4161 0.2424 l 0.4184 0.2444 l 0.4207 0.2460 l 0.4230 0.2471 l 0.4253 0.2477 l 0.4276 0.2480 l 0.4299 0.2481 l 0.4322 0.2479 l 0.4345 0.2478 l 0.4368 0.2478 l 0.4391 0.2480 l 0.4414 0.2486 l 0.4437 0.2498 l 0.4460 0.2516 l 0.4482 0.2541 l 0.4505 0.2574 l 0.4528 0.2615 l 0.4551 0.2664 l 0.4574 0.2719 l 0.4597 0.2781 l 0.4620 0.2847 l 0.4643 0.2917 l 0.4666 0.2987 l 0.4689 0.3057 l 0.4712 0.3124 l 0.4735 0.3187 l 0.4758 0.3244 l 0.4781 0.3293 l 0.4804 0.3333 l 0.4827 0.3363 l 0.4850 0.3384 l 0.4872 0.3393 l 0.4895 0.3391 l 0.4918 0.3380 l 0.4941 0.3358 l 0.4964 0.3328 l 0.4987 0.3289 l 0.5010 0.3244 l 0.5033 0.3195 l 0.5056 0.3142 l 0.5079 0.3088 l 0.5102 0.3037 l 0.5125 0.2991 l 0.5148 0.2952 l 0.5171 0.2924 l 0.5194 0.2908 l 0.5217 0.2904 l 0.5240 0.2916 l 0.5262 0.2942 l 0.5285 0.2982 l 0.5308 0.3037 l 0.5331 0.3105 l 0.5354 0.3184 l 0.5377 0.3271 l 0.5400 0.3365 l 0.5423 0.3464 l 0.5446 0.3567 l 0.5469 0.3673 l 0.5492 0.3780 l 0.5515 0.3888 l 0.5538 0.3999 l 0.5561 0.4112 l 0.5584 0.4228 l 0.5607 0.4349 l 0.5630 0.4475 l 0.5652 0.4608 l 0.5675 0.4749 l 0.5698 0.4897 l 0.5721 0.5052 l 0.5744 0.5212 l 0.5767 0.5377 l 0.5790 0.5547 l 0.5813 0.5720 l 0.5836 0.5897 l 0.5859 0.6074 l 0.5882 0.6249 l 0.5905 0.6419 l 0.5928 0.6580 l 0.5951 0.6727 l 0.5974 0.6857 l 0.5997 0.6963 l 0.6020 0.7042 l 0.6043 0.7091 l 0.6065 0.7105 l 0.6088 0.7083 l 0.6111 0.7024 l 0.6134 0.6931 l 0.6157 0.6807 l 0.6180 0.6657 l 0.6203 0.6486 l 0.6226 0.6302 l 0.6249 0.6112 l 0.6272 0.5926 l 0.6295 0.5748 l 0.6318 0.5582 l 0.6341 0.5432 l 0.6364 0.5302 l 0.6387 0.5193 l 0.6410 0.5102 l 0.6433 0.5029 l 0.6455 0.4972 l 0.6478 0.4929 l 0.6501 0.4899 l 0.6524 0.4878 l 0.6547 0.4867 l 0.6570 0.4867 l 0.6593 0.4880 l 0.6616 0.4909 l 0.6639 0.4955 l 0.6662 0.5020 l 0.6685 0.5106 l 0.6708 0.5213 l 0.6731 0.5340 l 0.6754 0.5484 l 0.6777 0.5641 l 0.6800 0.5808 l 0.6823 0.5978 l 0.6845 0.6147 l 0.6868 0.6309 l 0.6891 0.6458 l 0.6914 0.6592 l 0.6937 0.6710 l 0.6960 0.6812 l 0.6983 0.6896 l 0.7006 0.6967 l 0.7029 0.7028 l 0.7052 0.7083 l 0.7075 0.7136 l 0.7098 0.7187 l 0.7121 0.7241 l 0.7144 0.7299 l 0.7167 0.7360 l 0.7190 0.7418 l 0.7213 0.7468 l 0.7235 0.7506 l 0.7258 0.7522 l 0.7281 0.7510 l 0.7304 0.7462 l 0.7327 0.7369 l 0.7350 0.7231 l 0.7373 0.7044 l 0.7396 0.6809 l 0.7419 0.6526 l 0.7442 0.6203 l 0.7465 0.5847 l 0.7488 0.5468 l 0.7511 0.5073 l 0.7534 0.4674 l 0.7557 0.4280 l 0.7580 0.3901 l 0.7603 0.3545 l 0.7626 0.3216 l 0.7648 0.2918 l 0.7671 0.2655 l 0.7694 0.2426 l 0.7717 0.2233 l 0.7740 0.2073 l 0.7763 0.1947 l 0.7786 0.1850 l 0.7809 0.1779 l 0.7832 0.1729 l 0.7855 0.1697 l 0.7878 0.1680 l 0.7901 0.1675 l 0.7924 0.1679 l 0.7947 0.1690 l 0.7970 0.1706 l 0.7993 0.1723 l 0.8016 0.1740 l 0.8038 0.1755 l 0.8061 0.1767 l 0.8084 0.1774 l 0.8107 0.1777 l 0.8130 0.1774 l 0.8153 0.1767 l 0.8176 0.1756 l 0.8199 0.1743 l 0.8222 0.1728 l 0.8245 0.1714 l 0.8268 0.1701 l 0.8291 0.1690 l 0.8314 0.1684 l 0.8337 0.1680 l 0.8360 0.1682 l 0.8383 0.1687 l 0.8406 0.1695 l 0.8428 0.1705 l 0.8451 0.1716 l 0.8474 0.1728 l 0.8497 0.1737 l 0.8520 0.1745 l 0.8543 0.1750 l 0.8566 0.1751 l 0.8589 0.1748 l 0.8612 0.1742 l 0.8635 0.1733 l 0.8658 0.1721 l 0.8681 0.1706 l 0.8704 0.1690 l 0.8727 0.1674 l 0.8750 0.1658 l 0.8773 0.1643 l 0.8796 0.1630 l 0.8818 0.1619 l 0.8841 0.1611 l 0.8864 0.1606 l 0.8887 0.1605 l 0.8910 0.1606 l 0.8933 0.1611 l 0.8956 0.1618 l 0.8979 0.1628 l 0.9002 0.1640 l 0.9025 0.1653 l 0.9048 0.1667 l 0.9071 0.1679 l 0.9094 0.1690 l 0.9117 0.1699 l 0.9140 0.1705 l 0.9163 0.1708 l 0.9186 0.1707 l 0.9209 0.1703 l 0.9231 0.1696 l 0.9254 0.1685 l 0.9277 0.1673 l 0.9300 0.1659 l 0.9323 0.1645 l 0.9346 0.1631 l 0.9369 0.1618 l 0.9392 0.1607 l 0.9415 0.1599 l 0.9438 0.1593 l 0.9461 0.1590 l 0.9484 0.1590 l 0.9507 0.1594 l 0.9530 0.1599 l 0.9553 0.1607 l 0.9576 0.1616 l 0.9599 0.1626 l 0.9621 0.1636 l 0.9644 0.1646 l 0.9667 0.1655 l 0.9690 0.1662 l 0.9713 0.1668 l 0.9736 0.1671 l 0.9759 0.1672 l 0.9782 0.1670 l 0.9805 0.1667 l 0.9828 0.1661 l 0.9851 0.1654 l 0.9874 0.1645 l 0.9897 0.1635 l 0.9920 0.1625 l 0.9943 0.1614 l 0.9966 0.1604 l 0.9989 0.1594 l 1.0001 0.1589 l s [] 0 SD 0.0015 SLW n 0.1500 0.1500 m 1.0000 0.1500 l s n 0.1500 0.8500 m 1.0000 0.8500 l s [] 0 SD 0.0037 SLW n 0.2154 0.1500 m 0.2154 0.1600 l s n 0.2154 0.8500 m 0.2154 0.8400 l s n 0.3462 0.1500 m 0.3462 0.1600 l s n 0.3462 0.8500 m 0.3462 0.8400 l s n 0.4769 0.1500 m 0.4769 0.1600 l s n 0.4769 0.8500 m 0.4769 0.8400 l s n 0.6077 0.1500 m 0.6077 0.1600 l s n 0.6077 0.8500 m 0.6077 0.8400 l s n 0.7385 0.1500 m 0.7385 0.1600 l s n 0.7385 0.8500 m 0.7385 0.8400 l s n 0.8692 0.1500 m 0.8692 0.1600 l s n 0.8692 0.8500 m 0.8692 0.8400 l s n 1.0000 0.1500 m 1.0000 0.1600 l s n 1.0000 0.8500 m 1.0000 0.8400 l s [] 0 SD 0.0045 SLW n 0.1500 0.1500 m 0.1500 0.1700 l s n 0.1500 0.8500 m 0.1500 0.8300 l s n 0.2808 0.1500 m 0.2808 0.1700 l s n 0.2808 0.8500 m 0.2808 0.8300 l s n 0.4115 0.1500 m 0.4115 0.1700 l s n 0.4115 0.8500 m 0.4115 0.8300 l s n 0.5423 0.1500 m 0.5423 0.1700 l s n 0.5423 0.8500 m 0.5423 0.8300 l s n 0.6731 0.1500 m 0.6731 0.1700 l s n 0.6731 0.8500 m 0.6731 0.8300 l s n 0.8038 0.1500 m 0.8038 0.1700 l s n 0.8038 0.8500 m 0.8038 0.8300 l s n 0.9346 0.1500 m 0.9346 0.1700 l s n 0.9346 0.8500 m 0.9346 0.8300 l s /Times-Roman findfont dup length dict begin {1 index /FID ne {def} {pop pop} ifelse} forall /Encoding DefEncoding def currentdict end /Font0 exch definefont pop /Font0 FFSF 0.1288 0.0955 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-6) show GR /Font0 FFSF 0.2604 0.0955 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-5) show GR /Font0 FFSF 0.3902 0.0959 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-4) show GR /Font0 FFSF 0.5219 0.0959 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-3) show GR /Font0 FFSF 0.6517 0.0959 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-2) show GR /Font0 FFSF 0.7844 0.0959 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-1) show GR /Font0 FFSF 0.9221 0.0959 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (0) show GR /Font0 FFSF 0.3577 0.0422 m GS [0.0560 0.0000 0.0000 0.0560 0 0] CC (Energy ) show GR /Symbol findfont /Font12 exch definefont pop /Font12 FFSF 0.5334 0.0422 m GS [0.0560 0.0000 0.0000 0.0560 0 0] CC ( e - e) show GR /Font0 FFSF 0.6554 0.0198 m GS [0.0396 0.0000 0.0000 0.0396 0 0] CC (F) show GR /Font0 FFSF 0.6774 0.0422 m GS [0.0560 0.0000 0.0000 0.0560 0 0] CC ( \(eV\)) show GR [] 0 SD 0.0015 SLW n 0.1500 0.1500 m 0.1500 0.8500 l s n 1.0000 0.1500 m 1.0000 0.8500 l s [] 0 SD 0.0037 SLW n 0.1500 0.2000 m 0.1600 0.2000 l s n 1.0000 0.2000 m 0.9900 0.2000 l s n 0.1500 0.3000 m 0.1600 0.3000 l s n 1.0000 0.3000 m 0.9900 0.3000 l s n 0.1500 0.4000 m 0.1600 0.4000 l s n 1.0000 0.4000 m 0.9900 0.4000 l s n 0.1500 0.5000 m 0.1600 0.5000 l s n 1.0000 0.5000 m 0.9900 0.5000 l s n 0.1500 0.6000 m 0.1600 0.6000 l s n 1.0000 0.6000 m 0.9900 0.6000 l s n 0.1500 0.7000 m 0.1600 0.7000 l s n 1.0000 0.7000 m 0.9900 0.7000 l s n 0.1500 0.8000 m 0.1600 0.8000 l s n 1.0000 0.8000 m 0.9900 0.8000 l s [] 0 SD 0.0045 SLW n 0.1500 0.1500 m 0.1700 0.1500 l s n 1.0000 0.1500 m 0.9800 0.1500 l s n 0.1500 0.2500 m 0.1700 0.2500 l s n 1.0000 0.2500 m 0.9800 0.2500 l s n 0.1500 0.3500 m 0.1700 0.3500 l s n 1.0000 0.3500 m 0.9800 0.3500 l s n 0.1500 0.4500 m 0.1700 0.4500 l s n 1.0000 0.4500 m 0.9800 0.4500 l s n 0.1500 0.5500 m 0.1700 0.5500 l s n 1.0000 0.5500 m 0.9800 0.5500 l s n 0.1500 0.6500 m 0.1700 0.6500 l s n 1.0000 0.6500 m 0.9800 0.6500 l s n 0.1500 0.7500 m 0.1700 0.7500 l s n 1.0000 0.7500 m 0.9800 0.7500 l s n 0.1500 0.8500 m 0.1700 0.8500 l s n 1.0000 0.8500 m 0.9800 0.8500 l s /Font0 FFSF 0.0824 0.1427 m GS [0.0000 0.0526 -0.0526 0.0000 0 0] CC (Local density of states \(arb. units\)) show GR n 0.1500 0.1500 m 0.1500 0.8500 l 1.0000 0.8500 l 1.0000 0.1500 l 0.1500 0.1500 l c s [] 0 SD 0.0023 SLW n 0.2000 0.7000 m 0.2000 0.5153 l 0.4410 0.5153 l 0.4410 0.7000 l 0.2000 0.7000 l c s /Font0 FFSF 0.3280 0.6459 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (-3%) show GR [0.0262 0.0112 ] 0 SD 0.0037 SLW n 0.2200 0.6625 m 0.3000 0.6625 l s /Font0 FFSF 0.3288 0.5910 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (0%) show GR [] 0 SD 0.0045 SLW n 0.2200 0.6076 m 0.3000 0.6076 l s /Font0 FFSF 0.3284 0.5361 m GS [0.0504 0.0000 0.0000 0.0504 0 0] CC (+2%) show GR [0.0037 0.0112 0.0187 0.0112 0.0037 0.0112 ] 0 SD 0.0037 SLW n 0.2200 0.5527 m 0.3000 0.5527 l s /Font0 FFSF 0.2135 0.3856 m GS [0.0560 0.0000 0.0000 0.0560 0 0] CC (Cu\(111\)) show GR /Font0 FFSF 0.2026 0.7173 m GS [0.0440 0.0000 0.0000 0.0440 0 0] CC (Lattice strain) show GR %%Trailer %%BoundingBox: 27 11 614 526 %%EOF %%EndDocument @endspecial -150 1455 a Fr(FIG.)23 b(1:)34 b(Lo)r(cal)24 b Fq(d)p Fr(-band)e(densit)n(y)h(of)h(states)f(of)h(the)f(Cu\(111\))h (surface)-150 1542 y(as)i(a)g(function)g(of)h(the)e(lattice)h(strain.) -150 1792 y Fu(simpli\014es)i(to)239 2004 y Fn(\016)s(E)345 1961 y Fm(H)394 1969 y Ff(2)427 1961 y Fe(=)p Fm(Cu)340 2029 y Fe(d)600 2004 y Fu(=)50 b Fj(\000)p Fu(2)927 1948 y Fn(V)994 1918 y Fm(2)p 831 1985 298 4 v 831 2061 a Fn(")870 2073 y Fe(\033)910 2057 y Fd(\003)908 2090 y Ff(u)968 2061 y Fj(\000)18 b Fn(")1090 2073 y Fe(d)1184 2004 y Fu(+)46 b Fn(\013V)1415 1970 y Fm(2)1480 2004 y Fn(:)283 b Fu(\(4\))-67 2225 y(In)34 b(the)g(original)e(presen)n (tation)g(of)h(the)h Fn(d)p Fu(-band)g(mo)r(del)f([10)o(])-150 2320 y(a)f(form)n(ula)g(equiv)-5 b(alen)n(t)32 b(to)h(eq.)f(3)g(w)n(as) g(also)f(used)i(to)f(estimate)-150 2416 y(the)i Fn(d)p Fu(-band)f(con)n(tribution)g(to)g(the)g(atomic)g(adsorption)f(ener-) -150 2511 y(gies)c(whic)n(h)h(con)n(tained)f(the)h(factor)f(\(1)19 b Fj(\000)g Fn(f)9 b Fu(\))28 b(in)h(the)h(attractiv)n(e)-150 2607 y(term.)73 b(Ho)n(w)n(ev)n(er,)41 b(later)e(it)h(turned)f(out)h ([32)o(,)j(33)o(])d(that)g(irre-)-150 2702 y(sp)r(ectiv)n(e)27 b(of)h(the)g(\014lling)f(factor)g(there)g(is)g(a)h(linear)e (relationship)-150 2798 y(b)r(et)n(w)n(een)36 b(the)g Fn(d)p Fu(-band)f(cen)n(ter)g(shift)i Fn(\016)s(")1146 2810 y Fe(d)1220 2798 y Fu(and)f(the)g(c)n(hange)e(in)-150 2893 y(the)f(c)n(hemisorption)f(strength)g Fn(\016)s(E)976 2863 y Fm(H)971 2917 y Fe(d)1062 2893 y Fu(of)h(atomic)f(h)n(ydrogen)g (on)-150 2989 y(metal)c(surfaces,)424 3201 y Fn(\016)s(E)530 3166 y Fm(H)525 3221 y Fe(d)606 3201 y Fu(=)23 b Fj(\000)888 3144 y Fn(V)955 3114 y Fm(2)p 768 3181 345 4 v 768 3258 a Fj(j)p Fn(\017)825 3270 y Fe(d)882 3258 y Fj(\000)18 b Fn(\017)999 3270 y Fm(H)1052 3258 y Fj(j)1075 3234 y Fm(2)1150 3201 y Fn(\016)s(")1229 3213 y Fe(d)1295 3201 y Fn(:)468 b Fu(\(5\))-150 3408 y(This)25 b(can)f(b)r(e)h 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0.2794 0.1400 l 0.2817 0.1400 l 0.2839 0.1401 l 0.2861 0.1401 l 0.2884 0.1401 l 0.2906 0.1401 l 0.2928 0.1401 l 0.2951 0.1401 l 0.2973 0.1401 l 0.2995 0.1401 l 0.3018 0.1401 l 0.3040 0.1401 l 0.3062 0.1401 l 0.3085 0.1401 l 0.3107 0.1401 l 0.3129 0.1401 l 0.3152 0.1401 l 0.3174 0.1401 l 0.3196 0.1402 l 0.3218 0.1402 l 0.3241 0.1403 l 0.3263 0.1403 l 0.3285 0.1404 l 0.3308 0.1404 l 0.3330 0.1404 l 0.3352 0.1405 l 0.3375 0.1405 l 0.3397 0.1405 l 0.3419 0.1405 l 0.3442 0.1405 l 0.3464 0.1405 l 0.3486 0.1405 l 0.3509 0.1405 l 0.3531 0.1405 l 0.3553 0.1405 l 0.3576 0.1405 l 0.3598 0.1406 l 0.3620 0.1406 l 0.3642 0.1407 l 0.3665 0.1408 l 0.3687 0.1408 l 0.3709 0.1409 l 0.3732 0.1409 l 0.3754 0.1409 l 0.3776 0.1409 l 0.3799 0.1409 l 0.3821 0.1409 l 0.3843 0.1408 l 0.3866 0.1408 l 0.3888 0.1408 l 0.3910 0.1408 l 0.3933 0.1408 l 0.3955 0.1409 l 0.3977 0.1409 l 0.4000 0.1409 l 0.4022 0.1409 l 0.4044 0.1409 l 0.4067 0.1408 l 0.4089 0.1408 l 0.4111 0.1407 l 0.4133 0.1406 l 0.4156 0.1406 l 0.4178 0.1405 l 0.4200 0.1405 l 0.4223 0.1405 l 0.4245 0.1405 l 0.4267 0.1406 l 0.4290 0.1407 l 0.4312 0.1408 l 0.4334 0.1409 l 0.4357 0.1410 l 0.4379 0.1411 l 0.4401 0.1412 l 0.4424 0.1413 l 0.4446 0.1414 l 0.4468 0.1415 l 0.4491 0.1416 l 0.4513 0.1417 l 0.4535 0.1418 l 0.4558 0.1419 l 0.4580 0.1420 l 0.4602 0.1421 l 0.4624 0.1421 l 0.4647 0.1421 l 0.4669 0.1420 l 0.4691 0.1419 l 0.4714 0.1418 l 0.4736 0.1417 l 0.4758 0.1417 l 0.4781 0.1417 l 0.4803 0.1418 l 0.4825 0.1419 l 0.4848 0.1421 l 0.4870 0.1423 l 0.4892 0.1424 l 0.4915 0.1425 l 0.4937 0.1425 l 0.4959 0.1424 l 0.4982 0.1423 l 0.5004 0.1421 l 0.5026 0.1419 l 0.5049 0.1418 l 0.5071 0.1417 l 0.5093 0.1417 l 0.5115 0.1418 l 0.5138 0.1420 l 0.5160 0.1423 l 0.5182 0.1427 l 0.5205 0.1432 l 0.5227 0.1437 l 0.5249 0.1441 l 0.5272 0.1445 l 0.5294 0.1449 l 0.5316 0.1452 l 0.5339 0.1456 l 0.5361 0.1458 l 0.5383 0.1461 l 0.5406 0.1464 l 0.5428 0.1466 l 0.5450 0.1468 l 0.5473 0.1469 l 0.5495 0.1470 l 0.5517 0.1471 l 0.5540 0.1473 l 0.5562 0.1475 l 0.5584 0.1479 l 0.5606 0.1486 l 0.5629 0.1496 l 0.5651 0.1510 l 0.5673 0.1527 l 0.5696 0.1547 l 0.5718 0.1570 l 0.5740 0.1594 l 0.5763 0.1618 l 0.5785 0.1641 l 0.5807 0.1663 l 0.5830 0.1683 l 0.5852 0.1700 l 0.5874 0.1715 l 0.5897 0.1727 l 0.5919 0.1738 l 0.5941 0.1749 l 0.5964 0.1761 l 0.5986 0.1777 l 0.6008 0.1800 l 0.6030 0.1832 l 0.6053 0.1872 l 0.6075 0.1921 l 0.6097 0.1975 l 0.6120 0.2033 l 0.6142 0.2089 l 0.6164 0.2140 l 0.6187 0.2184 l 0.6209 0.2219 l 0.6231 0.2245 l 0.6254 0.2262 l 0.6276 0.2273 l 0.6298 0.2278 l 0.6321 0.2279 l 0.6343 0.2277 l 0.6365 0.2273 l 0.6388 0.2269 l 0.6410 0.2267 l 0.6432 0.2268 l 0.6455 0.2277 l 0.6477 0.2295 l 0.6499 0.2324 l 0.6521 0.2364 l 0.6544 0.2414 l 0.6566 0.2469 l 0.6588 0.2526 l 0.6611 0.2579 l 0.6633 0.2625 l 0.6655 0.2661 l 0.6678 0.2684 l 0.6700 0.2695 l 0.6722 0.2696 l 0.6745 0.2686 l 0.6767 0.2668 l 0.6789 0.2642 l 0.6812 0.2610 l 0.6834 0.2577 l 0.6856 0.2546 l 0.6879 0.2521 l 0.6901 0.2507 l 0.6923 0.2510 l 0.6946 0.2533 l 0.6968 0.2582 l 0.6990 0.2656 l 0.7012 0.2753 l 0.7035 0.2870 l 0.7057 0.3001 l 0.7079 0.3141 l 0.7102 0.3284 l 0.7124 0.3430 l 0.7146 0.3581 l 0.7169 0.3741 l 0.7191 0.3917 l 0.7213 0.4115 l 0.7236 0.4339 l 0.7258 0.4583 l 0.7280 0.4841 l 0.7303 0.5096 l 0.7325 0.5329 l 0.7347 0.5519 l 0.7370 0.5651 l 0.7392 0.5709 l 0.7414 0.5688 l 0.7437 0.5590 l 0.7459 0.5422 l 0.7481 0.5200 l 0.7503 0.4943 l 0.7526 0.4677 l 0.7548 0.4430 l 0.7570 0.4225 l 0.7593 0.4078 l 0.7615 0.4004 l 0.7637 0.4001 l 0.7660 0.4067 l 0.7682 0.4185 l 0.7704 0.4330 l 0.7727 0.4481 l 0.7749 0.4621 l 0.7771 0.4738 l 0.7794 0.4833 l 0.7816 0.4915 l 0.7838 0.4995 l 0.7861 0.5088 l 0.7883 0.5209 l 0.7905 0.5360 l 0.7927 0.5543 l 0.7950 0.5752 l 0.7972 0.5973 l 0.7994 0.6196 l 0.8017 0.6410 l 0.8039 0.6606 l 0.8061 0.6783 l 0.8084 0.6944 l 0.8106 0.7096 l 0.8128 0.7246 l 0.8151 0.7400 l 0.8173 0.7555 l 0.8195 0.7704 l 0.8218 0.7828 l 0.8240 0.7902 l 0.8262 0.7900 l 0.8285 0.7797 l 0.8307 0.7573 l 0.8329 0.7228 l 0.8352 0.6767 l 0.8374 0.6210 l 0.8396 0.5592 l 0.8418 0.4947 l 0.8441 0.4314 l 0.8463 0.3727 l 0.8485 0.3209 l 0.8508 0.2775 l 0.8530 0.2431 l 0.8552 0.2170 l 0.8575 0.1982 l 0.8597 0.1854 l 0.8619 0.1771 l 0.8642 0.1720 l 0.8664 0.1692 l 0.8686 0.1678 l 0.8709 0.1673 l 0.8731 0.1673 l 0.8753 0.1676 l 0.8776 0.1679 l 0.8798 0.1682 l 0.8820 0.1684 l 0.8843 0.1684 l 0.8865 0.1684 l 0.8887 0.1684 l 0.8909 0.1685 l 0.8932 0.1687 l 0.8954 0.1690 l 0.8976 0.1693 l 0.8999 0.1694 l 0.9021 0.1694 l 0.9043 0.1691 l 0.9066 0.1683 l 0.9088 0.1671 l 0.9110 0.1654 l 0.9133 0.1632 l 0.9155 0.1607 l 0.9177 0.1580 l 0.9200 0.1555 l 0.9222 0.1533 l 0.9244 0.1517 l 0.9267 0.1508 l 0.9289 0.1507 l 0.9311 0.1514 l 0.9334 0.1527 l 0.9356 0.1543 l 0.9378 0.1560 l 0.9400 0.1575 l 0.9423 0.1586 l 0.9445 0.1593 l 0.9467 0.1594 l 0.9490 0.1590 l 0.9512 0.1583 l 0.9534 0.1574 l 0.9557 0.1563 l 0.9579 0.1552 l 0.9601 0.1541 l 0.9624 0.1532 l 0.9646 0.1524 l 0.9668 0.1517 l 0.9691 0.1512 l 0.9713 0.1509 l 0.9735 0.1508 l 0.9758 0.1508 l 0.9780 0.1510 l 0.9802 0.1514 l 0.9825 0.1518 l 0.9847 0.1523 l 0.9869 0.1527 l 0.9891 0.1530 l 0.9914 0.1532 l 0.9936 0.1531 l 0.9958 0.1528 l 0.9981 0.1523 l 1.0001 0.1517 l s [0.0315 0.0135 ] 0 SD 0.0045 SLW n 0.1500 0.1400 m 0.1522 0.1400 l 0.1545 0.1400 l 0.1567 0.1400 l 0.1589 0.1400 l 0.1612 0.1400 l 0.1634 0.1400 l 0.1656 0.1400 l 0.1679 0.1400 l 0.1701 0.1400 l 0.1723 0.1400 l 0.1745 0.1400 l 0.1768 0.1400 l 0.1790 0.1400 l 0.1812 0.1400 l 0.1835 0.1400 l 0.1857 0.1400 l 0.1879 0.1400 l 0.1902 0.1400 l 0.1924 0.1400 l 0.1946 0.1400 l 0.1969 0.1400 l 0.1991 0.1400 l 0.2013 0.1400 l 0.2036 0.1399 l 0.2058 0.1399 l 0.2059 0.1399 l s n 0.2280 0.1399 m 0.2281 0.1399 l 0.2303 0.1409 l 0.2326 0.1423 l 0.2348 0.1442 l 0.2370 0.1466 l 0.2393 0.1494 l 0.2415 0.1525 l 0.2437 0.1557 l 0.2460 0.1589 l 0.2482 0.1620 l 0.2504 0.1649 l 0.2527 0.1674 l 0.2549 0.1694 l 0.2571 0.1709 l 0.2594 0.1719 l 0.2616 0.1723 l 0.2638 0.1722 l 0.2661 0.1716 l 0.2683 0.1708 l 0.2705 0.1701 l 0.2727 0.1696 l 0.2750 0.1698 l 0.2772 0.1706 l 0.2794 0.1723 l 0.2817 0.1746 l 0.2839 0.1772 l 0.2861 0.1798 l 0.2884 0.1820 l 0.2906 0.1834 l 0.2928 0.1837 l 0.2951 0.1831 l 0.2973 0.1816 l 0.2995 0.1795 l 0.3018 0.1774 l 0.3040 0.1756 l 0.3062 0.1748 l 0.3085 0.1754 l 0.3107 0.1779 l 0.3129 0.1827 l 0.3152 0.1903 l 0.3174 0.2009 l 0.3196 0.2142 l 0.3218 0.2301 l 0.3241 0.2477 l 0.3263 0.2659 l 0.3285 0.2838 l 0.3308 0.3001 l 0.3330 0.3139 l 0.3352 0.3245 l 0.3375 0.3318 l 0.3397 0.3358 l 0.3419 0.3374 l 0.3442 0.3376 l 0.3464 0.3375 l 0.3486 0.3384 l 0.3509 0.3417 l 0.3531 0.3485 l 0.3553 0.3599 l 0.3576 0.3761 l 0.3598 0.3974 l 0.3620 0.4226 l 0.3642 0.4503 l 0.3665 0.4786 l 0.3687 0.5048 l 0.3709 0.5263 l 0.3732 0.5419 l 0.3754 0.5502 l 0.3776 0.5519 l 0.3799 0.5490 l 0.3821 0.5438 l 0.3843 0.5394 l 0.3866 0.5386 l 0.3888 0.5422 l 0.3910 0.5502 l 0.3933 0.5608 l 0.3955 0.5708 l 0.3977 0.5769 l 0.4000 0.5763 l 0.4022 0.5668 l 0.4044 0.5481 l 0.4067 0.5212 l 0.4089 0.4881 l 0.4111 0.4517 l 0.4133 0.4149 l 0.4156 0.3807 l 0.4178 0.3516 l 0.4200 0.3297 l 0.4223 0.3160 l 0.4245 0.3114 l 0.4267 0.3153 l 0.4290 0.3267 l 0.4312 0.3437 l 0.4334 0.3636 l 0.4357 0.3838 l 0.4379 0.4022 l 0.4401 0.4169 l 0.4424 0.4276 l 0.4446 0.4351 l 0.4468 0.4404 l 0.4491 0.4457 l 0.4513 0.4525 l 0.4535 0.4614 l 0.4558 0.4721 l 0.4580 0.4833 l 0.4602 0.4921 l 0.4624 0.4963 l 0.4647 0.4938 l 0.4669 0.4830 l 0.4691 0.4649 l 0.4714 0.4415 l 0.4736 0.4155 l 0.4758 0.3903 l 0.4781 0.3692 l 0.4803 0.3533 l 0.4825 0.3432 l 0.4848 0.3376 l 0.4870 0.3340 l 0.4892 0.3300 l 0.4915 0.3235 l 0.4937 0.3126 l 0.4959 0.2973 l 0.4982 0.2783 l 0.5004 0.2570 l 0.5026 0.2354 l 0.5049 0.2156 l 0.5071 0.1990 l 0.5093 0.1866 l 0.5115 0.1794 l 0.5138 0.1778 l 0.5160 0.1818 l 0.5182 0.1907 l 0.5205 0.2036 l 0.5227 0.2191 l 0.5249 0.2355 l 0.5272 0.2513 l 0.5294 0.2648 l 0.5316 0.2750 l 0.5339 0.2812 l 0.5361 0.2831 l 0.5383 0.2811 l 0.5406 0.2762 l 0.5428 0.2691 l 0.5450 0.2609 l 0.5473 0.2525 l 0.5495 0.2443 l 0.5517 0.2368 l 0.5540 0.2300 l 0.5562 0.2239 l 0.5584 0.2185 l 0.5606 0.2138 l 0.5629 0.2100 l 0.5651 0.2074 l 0.5673 0.2064 l 0.5696 0.2073 l 0.5718 0.2101 l 0.5740 0.2149 l 0.5763 0.2211 l 0.5785 0.2282 l 0.5807 0.2355 l 0.5830 0.2419 l 0.5852 0.2467 l 0.5874 0.2492 l 0.5897 0.2488 l 0.5919 0.2456 l 0.5941 0.2400 l 0.5964 0.2324 l 0.5986 0.2240 l 0.6008 0.2158 l 0.6030 0.2087 l 0.6053 0.2038 l 0.6075 0.2015 l 0.6097 0.2020 l 0.6120 0.2051 l 0.6142 0.2102 l 0.6164 0.2164 l 0.6187 0.2230 l 0.6209 0.2288 l 0.6231 0.2332 l 0.6254 0.2358 l 0.6276 0.2362 l 0.6298 0.2345 l 0.6321 0.2308 l 0.6343 0.2256 l 0.6365 0.2194 l 0.6388 0.2127 l 0.6410 0.2062 l 0.6432 0.2002 l 0.6455 0.1950 l 0.6477 0.1907 l 0.6499 0.1873 l 0.6521 0.1845 l 0.6544 0.1822 l 0.6566 0.1805 l 0.6588 0.1793 l 0.6611 0.1790 l 0.6633 0.1801 l 0.6655 0.1830 l 0.6678 0.1881 l 0.6700 0.1956 l 0.6722 0.2048 l 0.6745 0.2147 l 0.6767 0.2243 l 0.6789 0.2318 l 0.6812 0.2360 l 0.6834 0.2361 l 0.6856 0.2319 l 0.6879 0.2238 l 0.6901 0.2131 l 0.6923 0.2012 l 0.6946 0.1896 l 0.6968 0.1799 l 0.6990 0.1726 l 0.7012 0.1682 l 0.7035 0.1667 l 0.7057 0.1675 l 0.7079 0.1701 l 0.7102 0.1737 l 0.7124 0.1778 l 0.7146 0.1816 l 0.7169 0.1848 l 0.7191 0.1871 l 0.7213 0.1881 l 0.7236 0.1879 l 0.7258 0.1864 l 0.7280 0.1837 l 0.7303 0.1802 l 0.7325 0.1761 l 0.7347 0.1718 l 0.7370 0.1677 l 0.7392 0.1641 l 0.7414 0.1611 l 0.7437 0.1589 l 0.7459 0.1575 l 0.7481 0.1567 l 0.7503 0.1564 l 0.7526 0.1566 l 0.7548 0.1570 l 0.7570 0.1575 l 0.7593 0.1581 l 0.7615 0.1586 l 0.7637 0.1590 l 0.7660 0.1594 l 0.7682 0.1597 l 0.7704 0.1600 l 0.7727 0.1603 l 0.7749 0.1607 l 0.7771 0.1611 l 0.7794 0.1617 l 0.7816 0.1624 l 0.7838 0.1632 l 0.7861 0.1640 l 0.7883 0.1648 l 0.7905 0.1653 l 0.7927 0.1657 l 0.7950 0.1657 l 0.7972 0.1656 l 0.7994 0.1652 l 0.8017 0.1648 l 0.8039 0.1643 l 0.8061 0.1638 l 0.8084 0.1633 l 0.8106 0.1629 l 0.8128 0.1625 l 0.8151 0.1621 l 0.8173 0.1616 l 0.8195 0.1610 l 0.8218 0.1604 l 0.8240 0.1597 l 0.8262 0.1592 l 0.8285 0.1589 l 0.8307 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0.1506 l 0.9874 0.1516 l 0.9896 0.1525 l 0.9919 0.1531 l 0.9941 0.1533 l 0.9963 0.1532 l 0.9986 0.1528 l 1.0001 0.1523 l s [0.0315 0.0135 ] 0 SD 0.0045 SLW n 0.1500 0.1400 m 0.1522 0.1400 l 0.1545 0.1400 l 0.1567 0.1400 l 0.1589 0.1400 l 0.1612 0.1400 l 0.1634 0.1400 l 0.1656 0.1400 l 0.1679 0.1400 l 0.1701 0.1400 l 0.1723 0.1400 l 0.1745 0.1400 l 0.1768 0.1400 l 0.1790 0.1400 l 0.1812 0.1400 l 0.1835 0.1400 l 0.1857 0.1400 l 0.1879 0.1400 l 0.1902 0.1400 l 0.1924 0.1400 l 0.1946 0.1400 l 0.1969 0.1400 l 0.1991 0.1400 l 0.2013 0.1400 l 0.2036 0.1400 l 0.2058 0.1400 l 0.2080 0.1400 l 0.2103 0.1400 l 0.2125 0.1400 l 0.2147 0.1400 l 0.2170 0.1400 l 0.2192 0.1400 l 0.2214 0.1400 l 0.2236 0.1400 l 0.2259 0.1399 l 0.2281 0.1399 l 0.2303 0.1399 l 0.2326 0.1399 l 0.2348 0.1399 l 0.2370 0.1400 l 0.2393 0.1400 l 0.2415 0.1401 l 0.2437 0.1403 l 0.2460 0.1405 l 0.2482 0.1407 l 0.2504 0.1409 l 0.2527 0.1412 l 0.2549 0.1414 l 0.2571 0.1417 l 0.2594 0.1419 l 0.2616 0.1421 l 0.2638 0.1423 l 0.2661 0.1424 l 0.2683 0.1425 l 0.2705 0.1426 l 0.2727 0.1425 l 0.2750 0.1425 l 0.2772 0.1424 l 0.2794 0.1423 l 0.2817 0.1423 l 0.2839 0.1422 l 0.2861 0.1422 l 0.2884 0.1423 l 0.2906 0.1424 l 0.2928 0.1425 l 0.2951 0.1427 l 0.2973 0.1429 l 0.2995 0.1430 l 0.3018 0.1431 l 0.3040 0.1431 l 0.3062 0.1431 l 0.3085 0.1430 l 0.3107 0.1428 l 0.3129 0.1427 l 0.3152 0.1425 l 0.3174 0.1424 l 0.3196 0.1423 l 0.3218 0.1422 l 0.3241 0.1421 l 0.3263 0.1421 l 0.3285 0.1421 l 0.3308 0.1422 l 0.3330 0.1424 l 0.3352 0.1427 l 0.3375 0.1432 l 0.3397 0.1439 l 0.3419 0.1447 l 0.3442 0.1456 l 0.3464 0.1466 l 0.3486 0.1478 l 0.3509 0.1489 l 0.3531 0.1501 l 0.3553 0.1512 l 0.3576 0.1523 l 0.3598 0.1533 l 0.3620 0.1541 l 0.3642 0.1547 l 0.3665 0.1552 l 0.3687 0.1553 l 0.3709 0.1553 l 0.3732 0.1550 l 0.3754 0.1547 l 0.3776 0.1544 l 0.3799 0.1543 l 0.3821 0.1545 l 0.3843 0.1550 l 0.3866 0.1559 l 0.3888 0.1571 l 0.3910 0.1584 l 0.3933 0.1597 l 0.3955 0.1608 l 0.3977 0.1616 l 0.4000 0.1618 l 0.4022 0.1616 l 0.4044 0.1610 l 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0.4504 0.1870 l 0.4525 0.1916 l 0.4546 0.1957 l 0.4568 0.1990 l 0.4589 0.2012 l 0.4610 0.2020 l 0.4632 0.2016 l 0.4653 0.2001 l 0.4674 0.1981 l 0.4695 0.1959 l 0.4717 0.1941 l 0.4738 0.1931 l 0.4759 0.1930 l 0.4781 0.1941 l 0.4802 0.1960 l 0.4823 0.1985 l 0.4845 0.2013 l 0.4866 0.2040 l 0.4887 0.2063 l 0.4909 0.2083 l 0.4930 0.2104 l 0.4951 0.2126 l 0.4972 0.2155 l 0.4994 0.2193 l 0.5015 0.2239 l 0.5036 0.2294 l 0.5058 0.2352 l 0.5079 0.2406 l 0.5100 0.2450 l 0.5122 0.2478 l 0.5143 0.2488 l 0.5164 0.2479 l 0.5185 0.2454 l 0.5207 0.2417 l 0.5228 0.2376 l 0.5249 0.2338 l 0.5271 0.2312 l 0.5292 0.2303 l 0.5313 0.2318 l 0.5335 0.2358 l 0.5356 0.2425 l 0.5377 0.2517 l 0.5398 0.2629 l 0.5420 0.2755 l 0.5441 0.2887 l 0.5462 0.3014 l 0.5484 0.3124 l 0.5505 0.3211 l 0.5526 0.3265 l 0.5548 0.3286 l 0.5569 0.3279 l 0.5590 0.3256 l 0.5612 0.3232 l 0.5633 0.3229 l 0.5654 0.3267 l 0.5675 0.3359 l 0.5697 0.3515 l 0.5718 0.3735 l 0.5739 0.4006 l 0.5761 0.4314 l 0.5782 0.4629 l 0.5803 0.4916 l 0.5825 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0.7167 0.2369 l 0.7188 0.2348 l 0.7209 0.2323 l 0.7231 0.2295 l 0.7252 0.2265 l 0.7273 0.2234 l 0.7294 0.2204 l 0.7316 0.2175 l 0.7337 0.2149 l 0.7358 0.2127 l 0.7380 0.2108 l 0.7401 0.2091 l 0.7422 0.2076 l 0.7444 0.2061 l 0.7465 0.2046 l 0.7486 0.2028 l 0.7508 0.2010 l 0.7529 0.1989 l 0.7550 0.1968 l 0.7571 0.1946 l 0.7593 0.1925 l 0.7614 0.1904 l 0.7635 0.1886 l 0.7657 0.1869 l 0.7678 0.1854 l 0.7699 0.1841 l 0.7721 0.1828 l 0.7742 0.1818 l 0.7763 0.1808 l 0.7784 0.1800 l 0.7806 0.1791 l 0.7827 0.1782 l 0.7848 0.1773 l 0.7870 0.1762 l 0.7891 0.1750 l 0.7912 0.1737 l 0.7934 0.1723 l 0.7955 0.1709 l 0.7976 0.1697 l 0.7997 0.1687 l 0.8019 0.1681 l 0.8040 0.1677 l 0.8061 0.1675 l 0.8083 0.1674 l 0.8104 0.1674 l 0.8125 0.1672 l 0.8147 0.1669 l 0.8168 0.1663 l 0.8189 0.1657 l 0.8211 0.1650 l 0.8232 0.1645 l 0.8253 0.1644 l 0.8274 0.1648 l 0.8296 0.1660 l 0.8317 0.1680 l 0.8338 0.1711 l 0.8360 0.1752 l 0.8381 0.1805 l 0.8402 0.1869 l 0.8424 0.1941 l 0.8445 0.2018 l 0.8466 0.2094 l 0.8487 0.2165 l 0.8509 0.2226 l 0.8530 0.2274 l 0.8551 0.2305 l 0.8573 0.2316 l 0.8594 0.2312 l 0.8615 0.2293 l 0.8637 0.2266 l 0.8658 0.2239 l 0.8679 0.2220 l 0.8701 0.2218 l 0.8722 0.2243 l 0.8743 0.2297 l 0.8764 0.2384 l 0.8786 0.2502 l 0.8807 0.2643 l 0.8828 0.2797 l 0.8850 0.2949 l 0.8871 0.3082 l 0.8892 0.3182 l 0.8914 0.3236 l 0.8935 0.3236 l 0.8956 0.3180 l 0.8977 0.3074 l 0.8999 0.2926 l 0.9020 0.2747 l 0.9041 0.2549 l 0.9063 0.2344 l 0.9084 0.2144 l 0.9105 0.1959 l 0.9127 0.1798 l 0.9148 0.1667 l 0.9169 0.1575 l 0.9190 0.1527 l 0.9212 0.1532 l 0.9233 0.1592 l 0.9254 0.1709 l 0.9276 0.1883 l 0.9297 0.2103 l 0.9318 0.2358 l 0.9340 0.2628 l 0.9361 0.2890 l 0.9382 0.3117 l 0.9404 0.3286 l 0.9425 0.3377 l 0.9446 0.3379 l 0.9467 0.3298 l 0.9489 0.3148 l 0.9510 0.2947 l 0.9531 0.2723 l 0.9553 0.2500 l 0.9574 0.2298 l 0.9595 0.2134 l 0.9617 0.2017 l 0.9638 0.1944 l 0.9659 0.1914 l 0.9680 0.1914 l 0.9702 0.1932 l 0.9723 0.1956 l 0.9744 0.1977 l 0.9766 0.1987 l 0.9787 0.1983 l 0.9808 0.1967 l 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L .89928 .54956 L .88299 .55028 L .86669 .55137 L .85039 .55284 L .83409 .55472 L .81787 .55704 L .8178 .55705 L .8015 .55987 L .7852 .56324 L .7689 .56721 L .75261 .57188 L .74799 .57334 L .73631 .57732 L .72001 .58364 L .70652 .58963 L .70372 .59098 L .68742 .59963 L .67706 .60593 L .67112 .60987 L .65482 .62212 L .6547 .62223 L .63853 .63698 L .63701 .63853 L .62269 .65482 L .62223 .65541 L .61074 .67112 L .60593 .67852 L .60058 .68742 L .59187 .70372 L .58963 .70833 L .58437 .72001 L .5779 .73631 L .57334 .74942 L .57231 .75261 L .56747 .7689 L .56329 .7852 L .55968 .8015 L .55704 .81511 L .55656 .8178 L .55388 .83409 L .55158 .85039 L .54961 .86669 L .54793 .88299 L .54651 .89928 L .54533 .91558 L Mistroke .54434 .93188 L .54354 .94817 L .5429 .96447 L .54241 .98077 L Mfstroke .05771 .98077 m .05826 .96447 L .05883 .94817 L .05945 .93188 L .0601 .91558 L .06079 .89928 L .06153 .88299 L .06231 .86669 L .06314 .85039 L .06401 .83409 L .06494 .8178 L .06592 .8015 L .06695 .7852 L .06805 .7689 L .06812 .76781 L .06919 .75261 L .0704 .73631 L .07167 .72001 L .07301 .70372 L .07443 .68742 L .07592 .67112 L .07749 .65482 L .07914 .63853 L .08088 .62223 L .08271 .60593 L .08442 .59135 L .08462 .58963 L .08662 .57334 L .08872 .55704 L .09092 .54074 L .09322 .52445 L .09565 .50815 L .09823 .49185 L .10072 .47714 L .10099 .47555 L .10394 .45926 L .10712 .44296 L .11055 .42666 L .11428 .41037 L .11701 .3993 L .11836 .39407 L .12281 .37777 L .12773 .36147 L .13318 .34518 L .13331 .3448 L .13923 .32888 L .146 .31258 L .14961 .30459 L .15358 .29628 L .1621 .27999 L Mistroke .16591 .2733 L .17169 .26369 L .1822 .24791 L .18257 .24739 L .19499 .2311 L .1985 .22688 L .20935 .2148 L .2148 .20924 L .2262 .1985 L .2311 .19421 L .24588 .1822 L .24739 .18104 L .26369 .16915 L .2684 .16591 L .27999 .15824 L .29385 .14961 L .29628 .14814 L .31258 .13867 L .3222 .13331 L .32888 .12967 L .34518 .12101 L .35287 .11701 L .36147 .1126 L .37777 .10443 L .38528 .10072 L .39407 .09641 L .41037 .08851 L .41885 .08442 L .42666 .08066 L .44296 .07285 L .45286 .06812 L .45926 .06507 L .47555 .05729 L .48701 .05183 L .49185 .04951 L .50815 .04173 L .52117 .03553 L .52445 .03397 L .54074 .02628 L .55576 .01923 L Mfstroke .98077 .53335 m .96447 .5324 L .94817 .53175 L .93188 .53139 L .91558 .53131 L .89928 .5315 L .88299 .53199 L .86669 .53278 L .85039 .53389 L .83409 .53534 L .8178 .53716 L .8015 .53938 L .79281 .54074 L .7852 .54204 L .7689 .54519 L .75261 .5489 L .73631 .55322 L .72372 .55704 L .72001 .55826 L .70372 .56411 L .68742 .57098 L .6824 .57334 L .67112 .5791 L .65482 .58874 L .65344 .58963 L .63853 .60029 L .63158 .60593 L .62223 .61434 L .61432 .62223 L .60593 .63153 L .60018 .63853 L .58963 .65292 L .58836 .65482 L .57838 .67112 L .57334 .68052 L .56992 .68742 L .5627 .70372 L .55704 .71858 L .55654 .72001 L .55126 .73631 L .54674 .75261 L .54286 .7689 L .54074 .77897 L .53954 .7852 L .5367 .8015 L .53425 .8178 L .53215 .83409 L .53034 .85039 L .5288 .86669 L .52748 .88299 L Mistroke .52636 .89928 L .52542 .91558 L .52464 .93188 L .52445 .93644 L .524 .94817 L .52347 .96447 L .52306 .98077 L Mfstroke .06301 .98077 m .06359 .96447 L .0642 .94817 L .06486 .93188 L .06555 .91558 L .06628 .89928 L .06706 .88299 L .06789 .86669 L .06812 .86221 L .06876 .85039 L .06967 .83409 L .07064 .8178 L .07167 .8015 L .07276 .7852 L .0739 .7689 L .07512 .75261 L .0764 .73631 L .07775 .72001 L .07917 .70372 L .08067 .68742 L .08225 .67112 L .08392 .65482 L .08442 .65007 L .08566 .63853 L .08748 .62223 L .0894 .60593 L .09143 .58963 L .09355 .57334 L .09579 .55704 L .09813 .54074 L .10059 .52445 L .10072 .5236 L .10315 .50815 L .10588 .49185 L .10881 .47555 L .11197 .45926 L .11538 .44296 L .11701 .43556 L .11905 .42666 L .12304 .41037 L .12743 .39407 L .13225 .37777 L .13331 .37438 L .13755 .36147 L .14344 .34518 L .14961 .32984 L .15002 .32888 L .15736 .31258 L .16563 .29628 L .16591 .29577 L Mistroke .17491 .27999 L .1822 .26849 L .18544 .26369 L .19747 .24739 L .1985 .24609 L .21133 .2311 L .2148 .22738 L .22751 .2148 L .2311 .21151 L .24649 .1985 L .24739 .19779 L .26369 .18552 L .26838 .1822 L .27999 .17435 L .29328 .16591 L .29628 .16407 L .31258 .15447 L .32121 .14961 L .32888 .14538 L .34518 .13666 L .35158 .13331 L .36147 .1282 L .37777 .11999 L .38378 .11701 L .39407 .11196 L .41037 .10405 L .41728 .10072 L .42666 .0962 L .44296 .08837 L .45119 .08442 L .45926 .08055 L .47555 .07275 L .48522 .06812 L .49185 .06495 L .50815 .05717 L .51939 .05183 L .52445 .04942 L .54074 .04175 L .55407 .03553 L .55704 .03415 L .57334 .02662 L .58945 .01923 L Mfstroke .98077 .51597 m .96447 .51502 L .94817 .51431 L .93188 .51382 L .91558 .51356 L .89928 .51354 L .88299 .51376 L .86669 .51423 L .85039 .51498 L .83409 .51601 L .8178 .51736 L .8015 .51905 L .7852 .52111 L .7689 .52358 L .76377 .52445 L .75261 .5265 L .73631 .52995 L .72001 .53397 L .70372 .53866 L .69719 .54074 L .68742 .54412 L .67112 .55051 L .65683 .55704 L .65482 .55804 L .63853 .56699 L .62854 .57334 L .62223 .57774 L .60717 .58963 L .60593 .59071 L .59018 .60593 L .58963 .60652 L .57633 .62223 L .57334 .62621 L .56487 .63853 L .55704 .65166 L .55531 .65482 L .5473 .67112 L .54074 .68688 L .54054 .68742 L .53485 .70372 L .52999 .72001 L .52583 .73631 L .52445 .74229 L .52221 .75261 L .51908 .7689 L .51636 .7852 L .51403 .8015 L .51202 .8178 L .5103 .83409 L .50885 .85039 L Mistroke .50815 .85929 L .50762 .86669 L .50659 .88299 L .50575 .89928 L .50506 .91558 L .50452 .93188 L .50411 .94817 L .5038 .96447 L .50358 .98077 L Mfstroke .06865 .98077 m .06926 .96447 L .06991 .94817 L .0706 .93188 L .07133 .91558 L .07211 .89928 L .07293 .88299 L .0738 .86669 L .07472 .85039 L .0757 .83409 L .07673 .8178 L .07783 .8015 L .07898 .7852 L .08021 .7689 L .0815 .75261 L .08286 .73631 L .0843 .72001 L .08442 .71868 L .0858 .70372 L .08738 .68742 L .08905 .67112 L .09081 .65482 L .09267 .63853 L .09463 .62223 L .09669 .60593 L .09886 .58963 L .10072 .57631 L .10114 .57334 L .10351 .55704 L .10599 .54074 L .1086 .52445 L .11136 .50815 L .1143 .49185 L .11701 .47777 L .11745 .47555 L .12083 .45926 L .12449 .44296 L .12846 .42666 L .13281 .41037 L .13331 .40858 L .13755 .39407 L .14279 .37777 L .14857 .36147 L .14961 .35872 L .15497 .34518 L .16216 .32888 L .16591 .32107 L .1702 .31258 L .17927 .29628 L .1822 .29142 L Mistroke .18954 .27999 L .1985 .26735 L .20127 .26369 L .2148 .2474 L .2148 .24739 L .23054 .2311 L .2311 .23056 L .24739 .21608 L .24894 .2148 L .26369 .20329 L .27026 .1985 L .27999 .19175 L .29468 .1822 L .29628 .1812 L .31258 .17143 L .32226 .16591 L .32888 .16222 L .34518 .15342 L .35239 .14961 L .36147 .14488 L .37777 .13661 L .38438 .13331 L .39407 .12853 L .41037 .12058 L .41774 .11701 L .42666 .1127 L .44296 .10483 L .45149 .10072 L .45926 .09697 L .47555 .08913 L .48537 .08442 L .49185 .0813 L .50815 .07346 L .51927 .06812 L .52445 .06565 L .54074 .05791 L .55371 .05183 L .55704 .05027 L .57334 .04273 L .58913 .03553 L .58963 .0353 L .60593 .02796 L .62223 .02072 L .6256 .01923 L Mfstroke .98077 .49891 m .96447 .49785 L .94817 .49699 L .93188 .49631 L .91558 .49582 L .89928 .49553 L .88299 .49546 L .86669 .4956 L .85039 .49598 L .83409 .49661 L .8178 .49751 L .8015 .4987 L .7852 .5002 L .7689 .50205 L .75261 .50429 L .73631 .50696 L .72983 .50815 L .72001 .51011 L .70372 .51381 L .68742 .51814 L .67112 .5232 L .66749 .52445 L .65482 .52916 L .63853 .53617 L .62921 .54074 L .62223 .54447 L .60593 .55433 L .60191 .55704 L .58963 .56613 L .58104 .57334 L .57334 .5805 L .56455 .58963 L .55704 .59842 L .55125 .60593 L .54074 .62164 L .54039 .62223 L .53145 .63853 L .52445 .65371 L .52397 .65482 L .51761 .67112 L .51217 .68742 L .50815 .70131 L .5075 .70372 L .50348 .72001 L .50001 .73631 L .49703 .75261 L .49448 .7689 L .4923 .7852 L .49185 .7889 L .49045 .8015 L Mistroke .4889 .8178 L .48761 .83409 L .48656 .85039 L .48571 .86669 L .48505 .88299 L .48456 .89928 L .48421 .91558 L .48398 .93188 L .48387 .94817 L .48386 .96447 L .48393 .98077 L Mfstroke .07464 .98077 m .0753 .96447 L .076 .94817 L .07674 .93188 L .07752 .91558 L .07835 .89928 L .07923 .88299 L .08017 .86669 L .08116 .85039 L .0822 .83409 L .08331 .8178 L .08442 .80234 L .08448 .8015 L .0857 .7852 L .087 .7689 L .08836 .75261 L .08981 .73631 L .09134 .72001 L .09296 .70372 L .09466 .68742 L .09647 .67112 L .09837 .65482 L .10038 .63853 L .10072 .63584 L .10247 .62223 L .10467 .60593 L .10699 .58963 L .10944 .57334 L .11201 .55704 L .11471 .54074 L .11701 .52739 L .11753 .52445 L .12049 .50815 L .12365 .49185 L .12706 .47555 L .13075 .45926 L .13331 .44866 L .13474 .44296 L .13906 .42666 L .14381 .41037 L .14902 .39407 L .14961 .39233 L .15474 .37777 L .16108 .36147 L .16591 .35015 L .16813 .34518 L .17604 .32888 L .1822 .31743 L .18497 .31258 L .1951 .29628 L Mistroke .1985 .29126 L .20667 .27999 L .2148 .26979 L .22002 .26369 L .2311 .25181 L .23554 .24739 L .24739 .23644 L .25363 .2311 L .26369 .22296 L .2745 .2148 L .27999 .21087 L .29628 .19994 L .29854 .1985 L .31258 .18989 L .32588 .1822 L .32888 .18051 L .34518 .17158 L .35582 .16591 L .36147 .16294 L .37777 .15456 L .38762 .14961 L .39407 .1464 L .41037 .13838 L .42076 .13331 L .42666 .13043 L .44296 .12249 L .4542 .11701 L .45926 .11455 L .47555 .10664 L .48778 .10072 L .49185 .09875 L .50815 .09085 L .52142 .08442 L .52445 .08295 L .54074 .07508 L .55529 .06812 L .55704 .06729 L .57334 .05965 L .58963 .05215 L .59034 .05183 L .60593 .04477 L .62223 .03753 L .62678 .03553 L .63853 .03043 L .65482 .02349 L .66502 .01923 L Mfstroke .98077 .48202 m .96447 .48077 L .94817 .47967 L .93188 .47873 L .91558 .47797 L .89928 .47739 L .88299 .47699 L .86669 .47678 L .85039 .47679 L .83409 .47701 L .8178 .47747 L .8015 .47818 L .7852 .47916 L .7689 .48043 L .75261 .48204 L .73631 .48399 L .72001 .48636 L .70372 .48916 L .69027 .49185 L .68742 .49247 L .67112 .49637 L .65482 .50098 L .63853 .50643 L .63394 .50815 L .62223 .51291 L .60593 .52056 L .59859 .52445 L .58963 .52962 L .57334 .54043 L .57291 .54074 L .55704 .5534 L .55299 .55704 L .54074 .56939 L .53726 .57334 L .52472 .58963 L .52445 .59003 L .51451 .60593 L .50815 .61788 L .50603 .62223 L .49891 .63853 L .49287 .65482 L .49185 .65784 L .48772 .67112 L .48333 .68742 L .47959 .70372 L .4764 .72001 L .47555 .72484 L .4737 .73631 L .47141 .75261 L .46949 .7689 L Mistroke .4679 .7852 L .4666 .8015 L .46555 .8178 L .46472 .83409 L .4641 .85039 L .46365 .86669 L .46336 .88299 L .46321 .89928 L .46319 .91558 L .46328 .93188 L .46346 .94817 L .46373 .96447 L .46408 .98077 L Mfstroke .08112 .98077 m .08183 .96447 L .08258 .94817 L .08338 .93188 L .08422 .91558 L .08442 .91195 L .08511 .89928 L .08605 .88299 L .08704 .86669 L .08809 .85039 L .08921 .83409 L .09039 .8178 L .09164 .8015 L .09297 .7852 L .09437 .7689 L .09586 .75261 L .09743 .73631 L .0991 .72001 L .10072 .70496 L .10085 .70372 L .10269 .68742 L .10462 .67112 L .10667 .65482 L .10884 .63853 L .11113 .62223 L .11355 .60593 L .1161 .58963 L .11701 .58397 L .11875 .57334 L .12154 .55704 L .12446 .54074 L .12754 .52445 L .1308 .50815 L .13331 .49629 L .13428 .49185 L .13799 .47555 L .14203 .45926 L .14643 .44296 L .14961 .43201 L .15122 .42666 L .15644 .41037 L .1622 .39407 L .16591 .38439 L .16855 .37777 L .17557 .36147 L .1822 .34766 L .18346 .34518 L .19235 .32888 L .1985 .31875 L .20248 .31258 L Mistroke .21408 .29628 L .2148 .29534 L .22745 .27999 L .2311 .27594 L .24301 .26369 L .24739 .2595 L .26105 .24739 L .26369 .24519 L .27999 .23241 L .28177 .2311 L .29628 .22089 L .3056 .2148 L .31258 .21043 L .32888 .20076 L .33284 .1985 L .34518 .19162 L .36147 .18283 L .36266 .1822 L .37777 .17429 L .39407 .16599 L .39423 .16591 L .41037 .15783 L .42666 .14977 L .42699 .14961 L .44296 .1417 L .45926 .13365 L .45994 .13331 L .47555 .1256 L .49185 .11759 L .49301 .11701 L .50815 .10957 L .52445 .10156 L .52615 .10072 L .54074 .09354 L .55704 .08559 L .55945 .08442 L .57334 .07773 L .58963 .07003 L .59374 .06812 L .60593 .06251 L .62223 .05516 L .62975 .05183 L .63853 .04798 L .65482 .04099 L .66792 .03553 L .67112 .03421 L .68742 .02767 L .70372 .02138 L .70945 .01923 L Mfstroke .98077 .46522 m .96447 .46366 L .94817 .46225 L .93188 .461 L .91558 .4599 L .90473 .45926 L .89928 .45897 L .88299 .45821 L .86669 .45764 L .85039 .45726 L .83409 .45707 L .8178 .45709 L .8015 .45733 L .7852 .45781 L .7689 .45853 L .75651 .45926 L .75261 .45952 L .73631 .46081 L .72001 .46242 L .70372 .46439 L .68742 .46674 L .67112 .46957 L .65482 .47296 L .64409 .47555 L .63853 .47703 L .62223 .48192 L .60593 .4877 L .59567 .49185 L .58963 .49451 L .57334 .50262 L .5637 .50815 L .55704 .51234 L .54074 .52411 L .54032 .52445 L .52445 .53852 L .52223 .54074 L .50815 .55655 L .50775 .55704 L .49605 .57334 L .49185 .58011 L .4865 .58963 L .4786 .60593 L .47555 .61311 L .47201 .62223 L .46648 .63853 L .46183 .65482 L .45926 .66522 L .45793 .67112 L .45466 .68742 L .45193 .70372 L Mistroke .44966 .72001 L .44779 .73631 L .44625 .75261 L .44501 .7689 L .44403 .7852 L .44328 .8015 L .44296 .80994 L .44272 .8178 L .44234 .83409 L .44211 .85039 L .44201 .86669 L .44203 .88299 L .44216 .89928 L .44238 .91558 L .44268 .93188 L .44296 .94409 L .44306 .94817 L .44351 .96447 L .444 .98077 L Mfstroke .08811 .98077 m .08888 .96447 L .08969 .94817 L .09054 .93188 L .09145 .91558 L .09242 .89928 L .09344 .88299 L .09452 .86669 L .09568 .85039 L .0969 .83409 L .09819 .8178 L .09956 .8015 L .10072 .78847 L .10101 .7852 L .10253 .7689 L .10413 .75261 L .10584 .73631 L .10765 .72001 L .10957 .70372 L .1116 .68742 L .11375 .67112 L .11603 .65482 L .11701 .64806 L .11842 .63853 L .12092 .62223 L .12358 .60593 L .12638 .58963 L .12934 .57334 L .13245 .55704 L .13331 .55268 L .13568 .54074 L .13907 .52445 L .14268 .50815 L .14655 .49185 L .14961 .47975 L .1507 .47555 L .15518 .45926 L .16009 .44296 L .16545 .42666 L .16591 .42535 L .17128 .41037 L .17776 .39407 L .1822 .38383 L .18495 .37777 L .19298 .36147 L .1985 .35132 L .20203 .34518 L .21236 .32888 L .2148 .32535 L .22422 .31258 L Mistroke .2311 .30411 L .23793 .29628 L .24739 .28631 L .25384 .27999 L .26369 .27095 L .27214 .26369 L .27999 .25732 L .29309 .24739 L .29628 .24509 L .31258 .23402 L .31715 .2311 L .32888 .22387 L .34447 .2148 L .34518 .2144 L .36147 .20533 L .37412 .1985 L .37777 .19655 L .39407 .18799 L .40531 .1822 L .41037 .17962 L .42666 .17134 L .4374 .16591 L .44296 .16309 L .45926 .15482 L .46955 .14961 L .47555 .14657 L .49185 .13832 L .50179 .13331 L .50815 .1301 L .52445 .12188 L .53409 .11701 L .54074 .11365 L .55704 .10547 L .56657 .10072 L .57334 .09737 L .58963 .08941 L .60003 .08442 L .60593 .08162 L .62223 .07403 L .63525 .06812 L .63853 .06666 L .65482 .05951 L .67112 .0526 L .67299 .05183 L .68742 .04594 L .70372 .03956 L .71446 .03553 L .72001 .03349 L .73631 .02771 L .75261 .02222 L Mistroke .76191 .01923 L Mfstroke .98077 .44768 m .96447 .44579 L .94817 .44407 L .93672 .44296 L .93188 .44251 L .91558 .44113 L .89928 .43991 L .88299 .43885 L .86669 .43796 L .85039 .43723 L .83409 .43666 L .8178 .43625 L .8015 .43602 L .7852 .43598 L .7689 .43613 L .75261 .4365 L .73631 .4371 L .72001 .43796 L .70372 .4391 L .68742 .44052 L .67112 .44231 L .666 .44296 L .65482 .44454 L .63853 .44732 L .62223 .45075 L .60593 .45486 L .59104 .45926 L .58963 .45971 L .57334 .46547 L .55704 .47234 L .55036 .47555 L .54074 .48066 L .52445 .49086 L .52304 .49185 L .50815 .50357 L .50309 .50815 L .49185 .51962 L .48763 .52445 L .47555 .54013 L .47512 .54074 L .46465 .55704 L .45926 .56681 L .45599 .57334 L .44893 .58963 L .44315 .60593 L .44296 .60652 L .43841 .62223 L .43451 .63853 L .4313 .65482 L .42866 .67112 L Mistroke .42666 .68614 L .42651 .68742 L .42475 .70372 L .42334 .72001 L .42222 .73631 L .42136 .75261 L .42073 .7689 L .4203 .7852 L .42003 .8015 L .41992 .8178 L .41993 .83409 L .42006 .85039 L .42028 .86669 L .42059 .88299 L .42097 .89928 L .42141 .91558 L .4219 .93188 L .42243 .94817 L .42299 .96447 L 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.56255 L .35657 .57334 L .35011 .58963 L Mistroke .34518 .60407 L .34459 .60593 L .33983 .62223 L .3357 .63853 L .3321 .65482 L .32896 .67112 L .32888 .67156 L .32619 .68742 L .32376 .70372 L .32162 .72001 L .31972 .73631 L .31805 .75261 L .31658 .7689 L .31527 .7852 L .31412 .8015 L .31311 .8178 L .31258 .82724 L .31222 .83409 L .31144 .85039 L .31075 .86669 L .31015 .88299 L .30962 .89928 L .30916 .91558 L .30875 .93188 L .30839 .94817 L .30808 .96447 L .30779 .98077 L Mfstroke .04955 .98077 m .04979 .96447 L .05005 .94817 L .05034 .93188 L .05065 .91558 L .05099 .89928 L .05136 .88299 L .05176 .86669 L .05183 .86414 L .05217 .85039 L .05261 .83409 L .05307 .8178 L .05357 .8015 L .05409 .7852 L .05465 .7689 L .05525 .75261 L .05587 .73631 L .05653 .72001 L .05723 .70372 L .05796 .68742 L .05873 .67112 L .05955 .65482 L .0604 .63853 L .06129 .62223 L .06223 .60593 L .06321 .58963 L .06423 .57334 L .0653 .55704 L .06641 .54074 L .0676 .52445 L .06812 .5176 L .06884 .50815 L .07015 .49185 L .07159 .47555 L .07317 .45926 L .07491 .44296 L .07683 .42666 L .07895 .41037 L .08131 .39407 L .08391 .37777 L .08442 .3748 L .08671 .36147 L .0899 .34518 L .09355 .32888 L .09771 .31258 L .10072 .30203 L .10239 .29628 L .10771 .27999 L .11402 .26369 L .11701 .25691 L Mistroke .12155 .24739 L .13071 .2311 L .13331 .227 L .14183 .2148 L .14961 .20499 L .15513 .1985 L .16591 .18718 L .17109 .1822 L .1822 .17257 L .19072 .16591 L .1985 .16033 L .2148 .14976 L .21505 .14961 L .2311 .14018 L .2432 .13331 L .24739 .13093 L .26369 .12154 L .27145 .11701 L .27999 .11197 L .29628 .10209 L .2985 .10072 L .31258 .09177 L .32369 .08442 L .32888 .08088 L .34518 .06933 L .34682 .06812 L .36147 .05707 L .36817 .05183 L .37777 .04406 L .38794 .03553 L .39407 .03022 L .40631 .01923 L Mfstroke .98077 .3975 m .96447 .39741 L .94817 .39729 L .93188 .39713 L .91558 .39694 L .89928 .39672 L .88299 .39647 L .86669 .3962 L .85039 .39591 L .83409 .3956 L .8178 .39529 L .8015 .39496 L .7852 .39462 L .7689 .39429 L .75712 .39407 L .75261 .39399 L .73631 .39374 L .72001 .39356 L .70372 .39342 L .68742 .39336 L .67112 .39341 L .65482 .3936 L .63853 .39396 L .63486 .39407 L .62223 .39455 L .60593 .39539 L .58963 .39656 L .57334 .39811 L .55704 .40013 L .54074 .4027 L .52445 .40593 L .50815 .40991 L .50647 .41037 L .49185 .41477 L .47555 .42068 L .46178 .42666 L .45926 .42787 L .44296 .43661 L .43286 .44296 L .42666 .44725 L .41137 .45926 L .41037 .46013 L .3943 .47555 L .39407 .47581 L .38026 .49185 L .37777 .49508 L .36847 .50815 L .36147 .51923 L .35843 .52445 L .34985 .54074 L Mistroke .34518 .55079 L .3425 .55704 L .33623 .57334 L .33088 .58963 L .32888 .59644 L .32628 .60593 L .3223 .62223 L .31884 .63853 L .31582 .65482 L .31317 .67112 L .31258 .67508 L .31085 .68742 L .30881 .70372 L .30702 .72001 L .30544 .73631 L .30406 .75261 L .30284 .7689 L .30178 .7852 L .30084 .8015 L .30003 .8178 L .29933 .83409 L .29872 .85039 L .29819 .86669 L .29773 .88299 L .29734 .89928 L .29701 .91558 L .29673 .93188 L .29649 .94817 L .29628 .96436 L .29628 .96447 L .29611 .98077 L Mfstroke .05326 .98077 m .05351 .96447 L .05378 .94817 L .05408 .93188 L .0544 .91558 L .05475 .89928 L .05513 .88299 L .05554 .86669 L .05598 .85039 L .05645 .83409 L .05695 .8178 L .05748 .8015 L .05804 .7852 L .05864 .7689 L .05928 .75261 L .05995 .73631 L .06065 .72001 L .0614 .70372 L .06218 .68742 L .06301 .67112 L .06387 .65482 L .06478 .63853 L .06574 .62223 L .06673 .60593 L .06778 .58963 L .06812 .58439 L .06883 .57334 L .06991 .55704 L .07104 .54074 L .07225 .52445 L .07357 .50815 L .07501 .49185 L .07658 .47555 L .07831 .45926 L .08022 .44296 L .08232 .42666 L .08442 .41188 L .08463 .41037 L .08708 .39407 L .08984 .37777 L .09297 .36147 L .09658 .34518 L .10069 .32888 L .10072 .3288 L .10521 .31258 L .11052 .29628 L .11679 .27999 L .11701 .27945 L .12409 .26369 L .1331 .24739 L Mistroke .13331 .24704 L .14404 .2311 L .14961 .22388 L .15716 .2148 L .16591 .20549 L .17312 .1985 L .1822 .19063 L .19308 .1822 L .1985 .17837 L .2148 .16794 L .21826 .16591 L .2311 .15864 L .24739 .14976 L .24766 .14961 L .26369 .14077 L .27705 .13331 L .27999 .13165 L .29628 .12224 L .30507 .11701 L .31258 .11242 L .32888 .10204 L .33089 .10072 L .34518 .09095 L .35428 .08442 L .36147 .07908 L .37565 .06812 L .37777 .06643 L .39407 .05302 L .39548 .05183 L .41037 .0388 L .41399 .03553 L .42666 .02374 L .43135 .01923 L Mfstroke .98077 .37941 m .96447 .37929 L .94817 .37914 L .93188 .37894 L .91558 .3787 L .89928 .37842 L .88299 .3781 L .86765 .37777 L .86669 .37775 L .85039 .37737 L .83409 .37696 L .8178 .37652 L .8015 .37605 L .7852 .37556 L .7689 .37507 L .75261 .37458 L .73631 .37413 L .72001 .37371 L .70372 .37331 L .68742 .37297 L .67112 .3727 L .65482 .37254 L .63853 .37252 L .62223 .37269 L .60593 .37307 L .58963 .37373 L .57334 .37472 L .55704 .37611 L .54246 .37777 L .54074 .378 L .52445 .38047 L .50815 .38361 L .49185 .38754 L .47555 .39243 L .47079 .39407 L .45926 .39848 L .44296 .40595 L .43468 .41037 L .42666 .41511 L .41037 .42625 L .40982 .42666 L .39407 .43983 L .39074 .44296 L .37777 .45648 L .37536 .45926 L .36257 .47555 L .36147 .4771 L .35174 .49185 L .34518 .50314 L .34248 .50815 L Mistroke .3345 .52445 L .32888 .53757 L .32761 .54074 L .32165 .55704 L .31649 .57334 L .31258 .58762 L .31207 .58963 L .30826 .60593 L .30496 .62223 L .30209 .63853 L .29959 .65482 L .2974 .67112 L .29628 .68038 L .29549 .68742 L .29382 .70372 L .29236 .72001 L .29108 .73631 L .28997 .75261 L .28901 .7689 L .28817 .7852 L .28746 .8015 L .28684 .8178 L .28631 .83409 L .28587 .85039 L .2855 .86669 L .28519 .88299 L .28493 .89928 L .28473 .91558 L .28457 .93188 L .28444 .94817 L .28434 .96447 L .28426 .98077 L Mfstroke .05715 .98077 m .05743 .96447 L .05773 .94817 L .05806 .93188 L .05841 .91558 L .0588 .89928 L .05921 .88299 L .05966 .86669 L .06013 .85039 L .06064 .83409 L .06118 .8178 L .06175 .8015 L .06236 .7852 L .06301 .7689 L .06369 .75261 L .06441 .73631 L .06517 .72001 L .06597 .70372 L .06681 .68742 L .0677 .67112 L .06812 .66357 L .06859 .65482 L .06951 .63853 L .07048 .62223 L .0715 .60593 L .07258 .58963 L .07371 .57334 L .07491 .55704 L .07615 .54074 L .07749 .52445 L .07894 .50815 L .08052 .49185 L .08225 .47555 L .08415 .45926 L .08442 .45708 L .08613 .44296 L .08833 .42666 L .09081 .41037 L .09361 .39407 L .09676 .37777 L .10034 .36147 L .10072 .35986 L .10425 .34518 L .10882 .32888 L .1142 .31258 L .11701 .305 L .1204 .29628 L .12778 .27999 L .13331 .2696 L .13674 .26369 L Mistroke .1477 .24739 L .14961 .24486 L .16085 .2311 L .16591 .22569 L .17719 .2148 L .1822 .21052 L .19818 .1985 L .1985 .19828 L .2148 .18809 L .22539 .1822 L .2311 .17916 L .24739 .1707 L .25657 .16591 L .26369 .16217 L .27999 .15353 L .28727 .14961 L .29628 .14465 L .31258 .13536 L .31607 .13331 L .32888 .1255 L .34206 .11701 L .34518 .11492 L .36147 .1035 L .36528 .10072 L .37777 .09124 L .38637 .08442 L .39407 .07811 L .40581 .06812 L .41037 .06415 L .42407 .05183 L .42666 .04943 L .44131 .03553 L .44296 .03392 L .45759 .01923 L Mfstroke .98077 .36076 m .96447 .36062 L .94817 .36043 L .93188 .36018 L .91558 .35988 L .89928 .35954 L .88299 .35914 L .86669 .35869 L .85039 .35821 L .83409 .35767 L .8178 .3571 L .8015 .35647 L .7852 .35581 L .7689 .35512 L .75261 .35442 L .73631 .35372 L .72001 .35302 L .70372 .35232 L .68742 .35163 L .67112 .35099 L .65482 .35042 L .63853 .34996 L .62223 .34964 L .60593 .34948 L .58963 .34954 L .57334 .34986 L .55704 .35052 L .54074 .35161 L .52445 .3532 L .50815 .35538 L .49185 .35826 L .47756 .36147 L .47555 .36199 L .45926 .36676 L .44296 .37281 L .43188 .37777 L .42666 .38038 L .41037 .38976 L .40387 .39407 L .39407 .40132 L .38336 .41037 L .37777 .41562 L .36722 .42666 L .36147 .43337 L .35398 .44296 L .34518 .45559 L .34282 .45926 L .33328 .47555 L .32888 .48396 L .32502 .49185 L Mistroke .31783 .50815 L .31258 .52155 L .31152 .52445 L .30599 .54074 L .30116 .55704 L .29697 .57334 L .29628 .57625 L .29337 .58963 L .29028 .60593 L .2876 .62223 L .28529 .63853 L .28328 .65482 L .28153 .67112 L .28002 .68742 L .27999 .68779 L .27871 .70372 L .27758 .72001 L .2766 .73631 L .27576 .75261 L .27505 .7689 L .27444 .7852 L .27393 .8015 L .27351 .8178 L .27316 .83409 L .27288 .85039 L .27266 .86669 L .27249 .88299 L .27237 .89928 L .27228 .91558 L .27223 .93188 L .2722 .94817 L .27219 .96447 L .2722 .98077 L Mfstroke .06142 .98077 m .06173 .96447 L .06206 .94817 L .06243 .93188 L .06282 .91558 L .06324 .89928 L .0637 .88299 L .06418 .86669 L .0647 .85039 L .06526 .83409 L .06584 .8178 L .06647 .8015 L .06713 .7852 L .06782 .7689 L .06812 .76218 L .06853 .75261 L .06926 .73631 L .07003 .72001 L .07085 .70372 L .07171 .68742 L .07263 .67112 L .0736 .65482 L .07462 .63853 L .0757 .62223 L .07685 .60593 L .07805 .58963 L .07931 .57334 L .08064 .55704 L .08201 .54074 L .08349 .52445 L .08442 .51482 L .08504 .50815 L .08666 .49185 L .08847 .47555 L .0905 .45926 L .09278 .44296 L .09533 .42666 L .0982 .41037 L .10072 .39749 L .10137 .39407 L .1048 .37777 L .1088 .36147 L .11353 .34518 L .11701 .33461 L .11896 .32888 L .12528 .31258 L .13295 .29628 L .13331 .29558 L .14209 .27999 L .14961 .26874 L Mistroke .1532 .26369 L .16591 .24847 L .16688 .24739 L .1822 .23287 L .18431 .2311 L .1985 .22065 L .20778 .2148 L .2148 .21081 L .2311 .20245 L .23936 .1985 L .24739 .19469 L .26369 .18687 L .27332 .1822 L .27999 .17892 L .29628 .17066 L .30534 .16591 L .31258 .16198 L .32888 .15271 L .33407 .14961 L .34518 .14265 L .35913 .13331 L .36147 .13167 L .37777 .11974 L .38134 .11701 L .39407 .10688 L .4015 .10072 L .41037 .09309 L .4201 .08442 L .42666 .07838 L .43752 .06812 L .44296 .06286 L .45413 .05183 L .45926 .04664 L .46999 .03553 L .47555 .02963 L .48511 .01923 L Mfstroke .98077 .34129 m .96447 .34111 L .94817 .34088 L .93188 .34057 L .91558 .34021 L .89928 .33978 L .88299 .33928 L .86669 .33872 L .85039 .3381 L .83409 .33741 L .8178 .33667 L .8015 .33585 L .7852 .33497 L .7689 .33404 L .75261 .33307 L .73631 .33207 L .72001 .33103 L .70372 .32995 L .68803 .32888 L .68742 .32884 L .67112 .32772 L .65482 .32664 L .63853 .32561 L .62223 .32467 L .60593 .32381 L .58963 .32307 L .57334 .32251 L .55704 .32219 L .54074 .32219 L .52445 .3226 L .50815 .32347 L .49185 .32492 L .47555 .3271 L .46552 .32888 L .45926 .33021 L .44296 .33451 L .42666 .34025 L .41533 .34518 L .41037 .34762 L .39407 .35701 L .38747 .36147 L .37777 .3689 L .36769 .37777 L .36147 .38398 L .35244 .39407 L .34518 .40322 L .34 .41037 L .3295 .42666 L .32888 .4277 L .32043 .44296 L Mistroke .31258 .45907 L .31249 .45926 L .30548 .47555 L .29925 .49185 L .29628 .50034 L .29371 .50815 L .28879 .52445 L .28443 .54074 L .28061 .55704 L .27999 .55992 L .27731 .57334 L .2745 .58963 L .27209 .60593 L .27003 .62223 L .26826 .63853 L .26674 .65482 L .26545 .67112 L .26434 .68742 L .26369 .69838 L .2634 .70372 L .26261 .72001 L .26194 .73631 L .26139 .75261 L .26094 .7689 L .26057 .7852 L .26028 .8015 L .26005 .8178 L .25988 .83409 L .25976 .85039 L .25968 .86669 L .25964 .88299 L .25964 .89928 L .25965 .91558 L .25969 .93188 L .25974 .94817 L .2598 .96447 L .25987 .98077 L Mfstroke .06614 .98077 m .06649 .96447 L .06686 .94817 L .06727 .93188 L .0677 .91558 L .06812 .90085 L .06817 .89928 L .06863 .88299 L .06912 .86669 L .06965 .85039 L .07022 .83409 L .07082 .8178 L .07147 .8015 L .07215 .7852 L .07288 .7689 L .07366 .75261 L .07448 .73631 L .07535 .72001 L .07628 .70372 L .07726 .68742 L .0783 .67112 L .07939 .65482 L .08055 .63853 L .08177 .62223 L .08306 .60593 L .0844 .58963 L .08442 .58944 L .08569 .57334 L .08705 .55704 L .08849 .54074 L .09006 .52445 L .0918 .50815 L .09373 .49185 L .09587 .47555 L .09826 .45926 L .10072 .44418 L .10091 .44296 L .10364 .42666 L .10683 .41037 L .11054 .39407 L .11484 .37777 L .11701 .37032 L .11962 .36147 L .12526 .34518 L .13208 .32888 L .13331 .32624 L .14009 .31258 L .14961 .29677 L .14991 .29628 L .16166 .27999 L Mistroke .16591 .27503 L .17666 .26369 L .1822 .25881 L .19731 .24739 L .1985 .24663 L .2148 .23731 L .22823 .2311 L .2311 .22987 L .24739 .22324 L .26369 .21667 L .26833 .2148 L .27999 .21001 L .29628 .20306 L .30646 .1985 L .31258 .19561 L .32888 .18733 L .33811 .1822 L .34518 .17798 L .36147 .16733 L .36352 .16591 L .37777 .15544 L .3853 .14961 L .39407 .14246 L .40485 .13331 L .41037 .12843 L .42285 .11701 L .42666 .1134 L .4397 .10072 L .44296 .09745 L .45566 .08442 L .45926 .08063 L .47093 .06812 L .47555 .06309 L .48577 .05183 L .49185 .04501 L .50018 .03553 L .50815 .0263 L .51413 .01923 L Mfstroke .98077 .32077 m .96447 .32055 L .94817 .32026 L .93188 .31989 L .91558 .31944 L .89928 .3189 L .88299 .31828 L .86669 .31758 L .85039 .31679 L .83409 .31592 L .8178 .31496 L .8015 .3139 L .7852 .31275 L .78286 .31258 L .7689 .31152 L .75261 .31021 L .73631 .30882 L .72001 .30735 L .70372 .30578 L .68742 .30412 L .67112 .3024 L .65482 .30062 L .63853 .29882 L .62223 .29699 L .61601 .29628 L .60593 .29513 L .58963 .29325 L .57334 .29138 L .55704 .28955 L .54074 .28782 L .52445 .28622 L .50815 .28477 L .49185 .28353 L .47555 .28257 L .45926 .28204 L .44296 .28213 L .42666 .28315 L .41037 .28551 L .39407 .29006 L .37987 .29628 L .37777 .29758 L .36147 .31054 L .3591 .31258 L .34522 .32888 L .34518 .32894 L .33399 .34518 L .32888 .35353 L .32415 .36147 L .31532 .37777 L .31258 .38328 L Mistroke .30746 .39407 L .30037 .41037 L .29628 .42053 L .29392 .42666 L .28805 .44296 L .28268 .45926 L .27999 .46801 L .27777 .47555 L .27331 .49185 L .26926 .50815 L .26563 .52445 L .26369 .53395 L .26239 .54074 L .25956 .55704 L .25715 .57334 L .25513 .58963 L .25344 .60593 L .25201 .62223 L .25082 .63853 L .24983 .65482 L .24902 .67112 L .24834 .68742 L .2478 .70372 L .24739 .71896 L .24737 .72001 L .24703 .73631 L .24678 .75261 L .24659 .7689 L .24647 .7852 L .2464 .8015 L .24637 .8178 L .24638 .83409 L .24642 .85039 L .24648 .86669 L .24656 .88299 L .24666 .89928 L .24676 .91558 L .24687 .93188 L .24697 .94817 L .24707 .96447 L .24716 .98077 L Mfstroke .07117 .98077 m .07154 .96447 L .07194 .94817 L .07237 .93188 L .07283 .91558 L .07333 .89928 L .07386 .88299 L .07444 .86669 L .07505 .85039 L .0757 .83409 L .0764 .8178 L .07714 .8015 L .07793 .7852 L .07877 .7689 L .07966 .75261 L .0806 .73631 L .08161 .72001 L .08267 .70372 L .08379 .68742 L .08442 .67858 L .0849 .67112 L .08602 .65482 L .08721 .63853 L .0885 .62223 L .08988 .60593 L .09137 .58963 L .09295 .57334 L .09463 .55704 L .09638 .54074 L .09828 .52445 L .10037 .50815 L .10072 .50557 L .10242 .49185 L .10475 .47555 L .10746 .45926 L .1106 .44296 L .1142 .42666 L .11701 .41532 L .11819 .41037 L .12264 .39407 L .12803 .37777 L .13331 .36415 L .13437 .36147 L .14177 .34518 L .14961 .33106 L .15081 .32888 L .1617 .31258 L .16591 .30741 L .17572 .29628 L .1822 .29053 L Mistroke .19614 .27999 L .1985 .27861 L .2148 .27035 L .2311 .26469 L .23458 .26369 L .24739 .26046 L .26369 .25671 L .27999 .25336 L .29628 .25025 L .31123 .24739 L .31258 .24711 L .32888 .24314 L .34518 .2374 L .35877 .2311 L .36147 .22936 L .37777 .21687 L .3807 .2148 L .39407 .20151 L .39729 .1985 L .41037 .18389 L .41196 .1822 L .4258 .16591 L .42666 .16486 L .43954 .14961 L .44296 .14548 L .45318 .13331 L .45926 .12595 L .46669 .11701 L .47555 .10618 L .48004 .10072 L .49185 .08611 L .49322 .08442 L .50623 .06812 L .50815 .06572 L .51925 .05183 L .52445 .04528 L .53218 .03553 L .54074 .02465 L .54493 .01923 L Mfstroke .234 .98077 m .23388 .96447 L .23373 .94817 L .23356 .93188 L .23337 .91558 L .23317 .89928 L .23295 .88299 L .23274 .86669 L .23252 .85039 L .23231 .83409 L .2321 .8178 L .23192 .8015 L .23175 .7852 L .23162 .7689 L .23152 .75261 L .23146 .73631 L .23145 .72001 L .23151 .70372 L .23164 .68742 L .23186 .67112 L .23218 .65482 L .23262 .63853 L .2332 .62223 L .23395 .60593 L .23489 .58963 L .23607 .57334 L .23753 .55704 L .23928 .54074 L .2413 .52445 L .24355 .50815 L .246 .49185 L .24739 .48311 L .24864 .47555 L .25141 .45926 L 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sc 90.0 rot (Center of mass distance Z \(\305\)) col0 sh gr /Helvetica-iso ff 330.00 scf sf 4725 7425 m gs 1 -1 sc (H-H distance d\(\305\)) col0 sh gr /Helvetica-iso ff 330.00 scf sf 6030 3105 m gs 1 -1 sc (Cu\(100\)) col0 sh gr % Polyline n 5198 5030 m 5693 5345 l 5513 5570 l 5063 5300 l cp gs col7 1.00 shd ef gr /Times-Roman-iso ff 300.00 scf sf 5220 5220 m gs 1 -1 sc 330.0 rot (0.6) col0 sh gr /Times-Roman-iso ff 300.00 scf sf 7245 5805 m gs 1 -1 sc 10.0 rot (0.2) col0 sh gr $F2psEnd rs %%EndDocument @endspecial 2042 4685 a Fr(FIG.)20 b(6:)32 b(P)n(oten)n(tial)20 b(energy)g(surface)h(for)f(the)g(h)n(ydrogen)f(disso)r(ciation)2042 4772 y(on)j(Cu\(111\))g(and)g(Cu\(100\))h(as)f(a)g(function)g(of)h(the) f(H-H)e(in)n(teratomic)2042 4859 y(distance)h Fq(d)f Fr(and)g(the)g(cen)n(ter)g(of)h(mass)f(distance)h(from)f(the)g(surface) h Fq(Z)5 b Fr(.)2042 4946 y(The)25 b(energy)g(is)g(in)g(eV/molecule,)h (the)e(energy)h(spacing)h(of)g(the)e(con-)2042 5033 y(tour)g(lines)h (is)f(0.1)i(eV.)e(The)g(disso)r(ciation)i(path)e(corresp)r(onds)h(to)f (the)2042 5120 y(h-b-h)29 b(geometry)-6 b(,)32 b(i.e.,)i(the)c(cen)n (ter)h(of)h(mass)f(has)g(b)r(een)g(k)n(ept)f(\014xed)2042 5208 y(laterally)g(ab)r(o)n(v)n(e)f(the)f(bridge)h(site)h(with)f(the)f (h)n(ydrogen)g(atoms)h(dis-)2042 5295 y(so)r(ciating)f(in)n(to)e(the)f (neigh)n(b)r(oring)i(three-)f(or)g(fourfold)h(hollo)n(w)h(sites,)2042 5382 y(resp)r(ectiv)n(ely)-6 b(.)34 b(Note)26 b(the)f(di\013eren)n(t)g (scale)i(of)f(the)g Fq(d)f Fr(axes.)p eop %%Page: 7 7 7 6 bop 4043 -299 a Fu(7)p 742 -163 2451 4 v 759 -102 a Fr(lattice)433 b(Cu\(111\))832 b(Cu\(100\))767 -10 y(strain)42 b Fq(E)1058 -1 y Fc(b)1114 -10 y Fr(\(eV\))33 b Fq(d)25 b Fr(\()1394 -23 y(\027)1394 -10 y(A\))33 b Fq(Z)e Fr(\()1628 -23 y(\027)1628 -10 y(A\))i Fq(E)1806 -1 y Fb(des)1920 -10 y Fr(\(eV\))g Fq(E)2162 -1 y Fc(b)2218 -10 y Fr(\(eV\))g Fq(d)25 b Fr(\()2498 -23 y(\027)2498 -10 y(A\))33 b Fq(Z)e Fr(\()2732 -23 y(\027)2732 -10 y(A\))i Fq(E)2910 -1 y 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963 y(surfaces,)23 b(w)n(e)f(ha)n(v)n(e)f(k)n (ept)h(the)h(cen)n(ter)f(of)h(mass)f(of)g(the)h(h)n(ydrogen)-150 1058 y(molecule)31 b(\014xed)h(ab)r(o)n(v)n(e)e(the)j(bridge)e(site)g (with)h(the)h(molecular)-150 1154 y(axis)j(parallel)g(to)g(the)h (surface.)64 b(W)-7 b(e)37 b(ha)n(v)n(e)f(then)h(determined)-150 1249 y(the)23 b(disso)r(ciation)f(path)h(in)n(to)g(the)g(adjacen)n(t)g (hollo)n(w)f(adsorption)-150 1344 y(site)k(b)n(y)h(calculating)e(the)i (p)r(oten)n(tial)f(energy)f(surface)h(\(PES\))g(as)-150 1440 y(a)40 b(function)i(of)f(the)g(H-H)g(in)n(teratomic)f(distance)g Fn(d)h Fu(and)g(the)-150 1535 y(cen)n(ter)24 b(of)g(mass)f(distance)h (from)g(the)g(surface)g Fn(Z)30 b Fu(in)24 b(this)g(con\014g-)-150 1631 y(uration.)37 b(Th)n(us)28 b(the)g(studied)g(disso)r(ciation)f (paths)h(corresp)r(ond)-150 1726 y(to)k(the)h(hollo)n(w-bridge-hollo)n (w)c(\(h-b-h\))k(con\014guration)d(whic)n(h)-150 1822 y(is)k(w)n(ell-kno)n(wn)e([18)o(,)k(36)o(])e(to)g(b)r(e)g(the)g(most)g 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GS [0.0255 0.0000 0.0000 0.0255 0 0] CC (2) show GR /Font0 FFSF 0.3907 0.6819 m GS [0.0361 0.0000 0.0000 0.0361 0 0] CC ( TS to dissociation) show GR [] 0 SD 0.0015 SLW n 0.2469 0.6870 m 0.3069 0.6870 l s n 0.2469 0.7016 m 0.2323 0.6870 l 0.2469 0.6724 l 0.2615 0.6870 l c [/DeviceRGB] SCS Color0 SC fill [/DeviceRGB] SCS Color1 SC [] 0 SD 0.0045 SLW n 0.2469 0.7016 m 0.2323 0.6870 l 0.2469 0.6724 l 0.2615 0.6870 l 0.2469 0.7016 l c s n 0.3069 0.7016 m 0.2923 0.6870 l 0.3069 0.6724 l 0.3215 0.6870 l c [/DeviceRGB] SCS Color0 SC fill [/DeviceRGB] SCS Color1 SC n 0.3069 0.7016 m 0.2923 0.6870 l 0.3069 0.6724 l 0.3215 0.6870 l 0.3069 0.7016 l c s /Font0 FFSF 0.2216 0.2451 m GS [0.0560 0.0000 0.0000 0.0560 0 0] CC (Cu\(111\)) show GR %%Trailer %%BoundingBox: 1 14 523 594 %%DocumentNeededResources: font Times-Roman %%EOF %%EndDocument @endspecial 2042 4987 a Fr(FIG.)c(8:)33 b(Change)23 b(of)g(the)f(h)n(ydrogen)f(adsorption)i(energy)f(and)g(disso-)2042 5075 y(ciation)k(barrier)h(and)e(the)g(o)n(xygen)g(atomic)h(and)f (molecular)h(adsorp-)2042 5162 y(tion)31 b(energies)h(as)g(w)n(ell)g (as)g(the)f(transition)h(state)g(\(TS\))f(to)g(disso)r(ci-)2042 5249 y(ation)g(on)f(Cu\(111\))h(as)g(a)g(function)f(of)h(the)f(lattice) h(constan)n(t.)49 b(The)2042 5336 y(data)26 b(for)g(o)n(xygen)f(are)i (tak)n(en)e(from)g(Ref.)h([6)q(].)p eop %%Page: 9 9 9 8 bop 4043 -299 a Fu(9)p 948 -81 2039 5 v 1203 -80 1529 7 v 1458 -79 1020 9 v 1712 -78 510 11 v -112 167 a Fr([1])35 b(C.)c(Stamp\015,)g(M.)g(V.)g(Ganduglia-Piro)n(v)l(ano,)i (K.)e(Reuter,)h(and)3 254 y(M.)26 b(Sc)n(he\017er,)34 b(Surf.)26 b(Sci.)g Fo(500)g Fr(\(2002\))h(368.)-112 341 y([2])35 b(A.)25 b(Gro\031,)36 b(Surf.)25 b(Sci.)h Fo(500)h Fr(\(2002\))g(347.)-112 429 y([3])35 b(M.)29 b(Gsell,)i(P)-6 b(.)28 b(Jak)n(ob,)i(and)e(D.)h(Menzel,)44 b(Science)29 b Fo(280)g Fr(\(1998\))3 516 y(717.)-112 603 y([4])35 b(P)-6 b(.)26 b(Jak)n(ob,)g(M.)g(Gsell,)i(and)d(D.)h (Menzel,)35 b(J.)27 b(Chem.)e(Ph)n(ys.)h Fo(114)3 690 y Fr(\(2001\))h(10075.)-112 777 y([5])35 b(M.)d(Ma)n(vrik)l(akis,)j(B.) e(Hammer,)f(and)g(J.)g(K.)h(N\034rsk)n(o)n(v,)54 b(Ph)n(ys.)3 864 y(Rev.)25 b(Lett.)h Fo(81)g Fr(\(1998\))h(2819.)-112 952 y([6])35 b(Y.)25 b(Xu)g(and)g(M.)i(Ma)n(vrik)l(akis,)34 b(Surf.)26 b(Sci.)g Fo(494)g Fr(\(2001\))h(131.)-112 1039 y([7])35 b(M.)56 b(M.)h(G)r(\177)-41 b(un)n(ter,)64 b(T.)56 b(Ressler,)64 b(B.)57 b(Bems,)63 b(C.)57 b(B)r(\177)-41 b(usc)n(her,)3 1126 y(T.)35 b(Genger,)i(O.)e(Hinric)n(hsen,)h(M.)f (Muhler,)i(and)d(R.)g(Sc)n(hl\177)-38 b(ogl,)3 1213 y(Catal.)27 b(Lett.)f Fo(71)g Fr(\(2001\))h(37.)-112 1300 y([8])35 b(A.)25 b(Roudgar)h(and)f(A.)h(Gro\031,)35 b(submitted.)-112 1388 y([9])g(Y.)k(Uesugi-Saito)n(w)h(and)f(M.)h(Y)-6 b(ata,)78 b(Ph)n(ys.)40 b(Rev.)e(Lett.)i Fo(88)3 1475 y Fr(\(2002\))27 b(256104.)-150 1562 y([10])35 b(B.)20 b(Hammer)e(and)i(J.)h(K.)f(N\034rsk)n(o)n(v,)26 b(Surf.)20 b(Sci.)g Fo(343)h Fr(\(1995\))g(211.)-150 1649 y([11])35 b(A.)g(Ruban,)j(B.)e(Hammer,)h(P)-6 b(.)36 b(Stoltze,)j(H.)d(L.)g (Skriv)n(er,)i(and)3 1736 y(J.)26 b(K.)g(N\034rsk)n(o)n(v,)34 b(J.)26 b(Mol.)h(Catal.)g(A)f Fo(115)g Fr(\(1997\))h(421.)-150 1823 y([12])35 b(G.)f(Anger,)i(A.)d(Winkler,)j(and)e(K.)f(D.)h (Rendulic,)60 b(Surf.)34 b(Sci.)3 1911 y Fo(220)26 b Fr(\(1989\))h(1.)-150 1998 y([13])35 b(A.)27 b(Ho)r(dgson,)i(J.)f (Moryl,)h(P)-6 b(.)27 b(T)-6 b(ra)n(v)n(ersaro,)30 b(and)d(H.)g(Zhao,) 41 b(Na-)3 2085 y(ture)25 b Fo(356)h Fr(\(1992\))h(501.)-150 2172 y([14])35 b(C.)27 b(T.)h(Rettner,)f(H.)g(A.)g(Mic)n(helsen,)i(and) e(D.)g(J.)g(Auerbac)n(h,)39 b(J.)3 2259 y(Chem.)25 b(Ph)n(ys.)g Fo(102)i Fr(\(1994\))g(4625.)-150 2346 y([15])35 b(M.)29 b(Gostein,)i(H.)d(P)n(arhiktheh,)h(and)f(G.)i(O.)e(Sitz,)44 b(Ph)n(ys.)29 b(Rev.)3 2434 y(Lett.)c Fo(75)h Fr(\(1995\))h(342.)-150 2521 y([16])35 b(H.)20 b(Hou,)i(S.)e(J.)h(Gulding,)h(C.)g(T.)f (Rettner,)g(A.)f(M.)i(W)-6 b(o)r(dtk)n(e,)21 b(and)3 2608 y(D.)k(J.)i(Auerbac)n(h,)33 b(Science)26 b Fo(277)g Fr(\(1997\))h(80.)-150 2695 y([17])35 b(K.)50 b(Sv)n(ensson,)57 b(L.)51 b(Bengtsson,)58 b(J.)51 b(Bellman,)58 b(M.)51 b(Hassel,)3 2782 y(M.)17 b(P)n(ersson,)k(and)16 b(S.)i(Andersson,)j(Ph) n(ys.)d(Rev.)e(Lett.)i Fo(83)f Fr(\(1999\))3 2869 y(124.)-150 2957 y([18])35 b(B.)29 b(Hammer,)f(M.)h(Sc)n(he\017er,)h(K.)f (Jacobsen,)i(and)d(J.)i(N\034rsk)n(o)n(v,)3 3044 y(Ph)n(ys.)25 b(Rev.)g(Lett.)h Fo(73)g Fr(\(1994\))h(1400.)-150 3131 y([19])35 b(A.)20 b(Gro\031,)j(B.)e(Hammer,)f(M.)h(Sc)n(he\017er,)h (and)e(W.)g(Brenig,)28 b(Ph)n(ys.)3 3218 y(Rev.)d(Lett.)h Fo(73)g Fr(\(1994\))h(3121.)-150 3305 y([20])35 b(G.)j(R.)g(Darling)g (and)g(S.)g(Hollo)n(w)n(a)n(y)-6 b(,)74 b(J.)39 b(Chem.)e(Ph)n(ys.)h Fo(101)2194 167 y Fr(\(1994\))27 b(3268.)2042 254 y([21])34 b(G.)k(R.)e(Darling)i(and)e(S.)h(Hollo)n(w)n(a)n(y)-6 b(,)71 b(Rep.)36 b(Prog.)i(Ph)n(ys.)f Fo(58)2194 341 y Fr(\(1995\))27 b(1595.)2042 429 y([22])34 b(G.-J.)e(Kro)r(es,)h(E.)e (J.)h(Baerends,)h(and)d(R.)h(C.)g(Mo)n(wrey)-6 b(,)51 b(Ph)n(ys.)2194 516 y(Rev.)26 b(Lett.)f Fo(78)h Fr(\(1997\))h(3583.) 2042 603 y([23])34 b(D.)26 b(M.)g(Bird,)35 b(F)-6 b(arada)n(y)26 b(Discuss.)g Fo(110)h Fr(\(1998\))f(333.)2042 690 y([24])34 b(G.-J.)27 b(Kro)r(es,)35 b(Prog.)27 b(Surf.)f(Sci.)g Fo(60)g Fr(\(1999\))h(1.)2042 777 y([25])34 b(A.)26 b(Gro\031,)35 b(Surf.)26 b(Sci.)g(Rep.)g Fo(32)g Fr(\(1998\))g(291.)2042 864 y([26])34 b(W.)h(Di)r(~)-41 b(no,)39 b(H.)34 b(Kasai,)39 b(and)34 b(A.)h(Okiji,)64 b(Prog.)36 b(Surf.)f(Sci.)g Fo(63)2194 952 y Fr(\(2000\))27 b(63.)2042 1049 y([27])2199 1031 y(\025)2194 1049 y(Z.)2288 1031 y(\025)2286 1049 y(Sljiv)l(an)n(\025)-36 b(canin)23 b(and)f(B.)i(Hammer,)29 b(Ph)n(ys.)23 b(Rev.)f(B)h Fo(65)h Fr(\(2002\))2194 1137 y(085414.)2042 1224 y([28])34 b(G.)d(Kresse)g(and)e(J.)i(F)-6 b(urthm)r(\177)-41 b(uller,)48 b(Ph)n(ys.)30 b(Rev.)f(B)h Fo(54)h Fr(\(1996\))2194 1311 y(11169.)2042 1398 y([29])j(J.)25 b(P)-6 b(.)23 b(P)n(erdew,)i(J.)f(A.)f(Chev)l(ary)-6 b(,)23 b(S.)h(H.)f(V)-6 b(osk)n(o,)23 b(K.)h(A.)f(Jac)n(kson,)2194 1485 y(M.)g(R.)e(P)n(ederson,)i(D.)f(J.)g(Singh,)g(and)f(C.)i (Fiolhais,)30 b(Ph)n(ys.)22 b(Rev.)2194 1572 y(B)k Fo(46)g Fr(\(1992\))h(6671.)2042 1660 y([30])34 b(D.)26 b(V)-6 b(anderbilt,)34 b(Ph)n(ys.)25 b(Rev.)g(B)h Fo(41)g Fr(\(1990\))h(7892.) 2042 1747 y([31])34 b(G.)d(Kresse)g(and)g(J.)g(Hafner,)50 b(J.)31 b(Ph)n(ys.:)44 b(Condens.)31 b(Matter)g Fo(6)2194 1834 y Fr(\(1994\))c(8245.)2042 1921 y([32])34 b(V.)d(P)n(allassana,)36 b(M.)31 b(Neuro)r(c)n(k,)h(L.)g(B.)f(Hansen,)i(B.)f(Hammer,)2194 2008 y(and)26 b(J.)g(K.)g(N\034rsk)n(o)n(v,)34 b(Ph)n(ys.)25 b(Rev.)g(B)h Fo(60)g Fr(\(1999\))h(6146.)2042 2095 y([33])34 b(B.)g(Hammer,)e(O.)h(H.)f(Nielsen,)j(and)d(J.)h(K.)g(N\034rsk)n(o)n (v,)55 b(Catal.)2194 2183 y(Lett.)26 b Fo(46)g Fr(\(1997\))h(31.)2042 2270 y([34])34 b(N.)f(D.)f(Lang)h(and)g(A.)f(Williams,)58 b(Ph)n(ys.)32 b(Rev.)g(B)h Fo(18)g Fr(\(1978\))2194 2357 y(616.)2042 2444 y([35])h(H.)26 b(Hjelm)n(b)r(erg,)34 b(Ph)n(ysica)26 b(Scripta)g Fo(18)g Fr(\(1978\))h(481.)2042 2531 y([36])34 b(P)-6 b(.)33 b(Kratzer,)i(B.)e(Hammer,)f(and)g(J.)h(K.) f(Norsk\034v,)56 b(Surf.)33 b(Sci.)2194 2619 y Fo(359)27 b Fr(\(1996\))g(45.)2042 2706 y([37])34 b(J.)e(Str\177)-38 b(omquist,)32 b(L.)f(Bengtsson,)j(M.)d(P)n(ersson,)j(and)d(B.)h(Ham-) 2194 2793 y(mer,)i(Surf.)26 b(Sci.)g Fo(397)g Fr(\(1998\))h(382.)2042 2880 y([38])34 b(B.)27 b(Hammer)d(and)h(J.)h(K.)g(N\034rsk)n(o)n(v,)34 b(Nature)25 b Fo(376)h Fr(\(1995\))h(238.)2042 2967 y([39])34 b(S.)26 b(Wilk)n(e)g(and)f(M.)h(Sc)n(he\017er,)34 b(Surf.)26 b(Sci.)g Fo(329)h Fr(\(1995\))f(L605.)2042 3054 y([40])34 b(C.)28 b(M.)g(W)-6 b(ei,)27 b(A.)g(Gro\031,)i(and)d(M.)i(Sc)n (he\017er,)38 b(Ph)n(ys.)27 b(Rev.)f(B)i Fo(57)2194 3142 y Fr(\(1998\))f(15572.)p eop %%Trailer end userdict /end-hook known{end-hook}if %%EOF