Institut für
Organische Chemie II
und Neue Materialien
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Direktor: Prof. Dr. P. Bäuerle. - 2:
Dr. M. Mastalerz.- 2.1:
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Publikationen Dr. M. Mastalerz
Michael Mastalerz
Dr. rer. nat.
Institute of Organic Chemistry II & Advanced Materials
Ulm University
Albert-Einstein-Allee 11
89081 Ulm, Germany
Phone: +49-731-50-22855; e-mail: michael.mastalerz@uni-ulm.de
Dissertation
Ph.D. Thesis „Funktionalisierte Calix[4]arene: Synthese und supramolekulare Eigenschaften”, Bochum 2005.
Journal Publications
24. M. Mastalerz*, I. M. Oppel, Rational Construction of an Extrinsic Porous Organic Crystal with an Exceptional High Surface Area, Angew. Chem. Int. Ed. 2012, DOI. 10.1002/anie.201201174, selected as Very Important Paper
23. M. W. Schneider, L. G. Lechner, M. Mastalerz*, Uniform Porous Nanospheres from Discrete Shape-persistent Organic Cage Compounds, J. Mater. Chem. 2012 , 22. 7113-7116.
22. M. W. Schneider, I. M. Oppel, M. Mastalerz*, Exo-Functionalized Shape Persistent [2+3]-Cage Compounds – Influence of Molecular Rigidity on Formation and Permanent Porosity, Chem. Eur. J. 2012, 18, 4156-4160.
21b. M. Mastalerz*, Rationales Design multifunktionaler Nanoporen durch Mischen passender Moleküle, Angew. Chem. 2012, 124, 604-606.
21a. M. Mastalerz*, Rational Design of Multifunctional Nanopores by Mixing Matching Molecules, Angew. Chem.Int. Ed. 2012, 51, 584-586.
20. J. Hamacek*, D. Poggiali, S. Zebret, B. El Aroussi, C. Besnard, M. W. Schneider, M. Mastalerz, Building large supramolecular nanocapsules with europium cations, Chem. Commun. 2012, 48, 1281-1283.
19. M. W. Schneider, I. M. Oppel, H. Ott, L. G. Lechner, H.-J. S. Hauswald, R. Stoll, M. Mastalerz*, Periphery-Substituted [4+6] Salicylbisimine Cage Compounds with Exceptional High Surface Areas: Influence of the Molecular Structure on Nitrogen Sorption Properties, Chem. Eur. J. 2012, 18, 836-847.
18. M. Mastalerz*, H.-J. S. Hauswald, R. Stoll, Metal-assisted Salphen Organic Frameworks (MaSOFs) with High Surface Areas and Narrow Pore-Size Distributions, Chem. Commun.2012, 48, 130-132.
17. M. Mastalerz*, Iris M. Oppel, Synthesis of Tetrahedral Shape-Persistent Tetranuclear Metal-Salphens, Eur. J. Org. Chem. 2011, 5971-5980.
16. M. Mastalerz*, S. Sieste, M. Cenic, I. M. Oppel, Two-Step Synthesis of an Airstable Hexammoniumtriptycene salt – an Air-Stable Building Block for Condensation Reactions to extended Triptycene Derivatives, J. Org. Chem. 2011, 76, 6389-6393.
Highlighted in SYNFACTS: T. M. Swager, J. B. Goods, Synfacts 2011, 10, 1076.
15. M. Mastalerz*, H. J. E. Rivera, I. M. Oppel, G. Dyker*, Supramolecular Single-Stranded Calix[4]arene Helices – A Crystal Engineering Approach Towards Homochiral Assemblies. CrystEngComm 2011, 3979-3982.
14b. M. Mastalerz*, M. W. Schneider, I. M. Oppel, O. Presly, Eine Salicylbisimin Käfigverbindung mit großer spezifischer Oberfläche und selektiver CO2/CH4-Adsorption, Angew. Chem. 2011, 123, 1078-1083.
14a. M. Mastalerz*, M. W. Schneider, I. M. Oppel, O. Presly, A Salicylbisimine Cage Compound with High Surface Area and Selective CO2/CH4 Adsorption, Angew. Chem. Int. Ed. 2011, 50, 1046-1051.(Selected as Very Important Paper)
Highlighted in Angewandte Chemie: A. I. Cooper, Angew. Chem. Int. Ed. 2011, 50, 996-998.
Highlighted in Nachrichten der Chemie: A. Krüger, Nachr. Chem. 2012, 3, 266-267.
13. M. Mastalerz*, Shape-Persistent Organic Cage Compounds by Dynamic Covalent Bond Formation, Angew. Chem. Int. Ed. 2010, 49, 5042-5053.
12. M. Mastalerz*, V. Fischer, C.-Q. Ma, R. A. J. Janssen, P. Bäuerle*, Conjugated Oligothienyl-Dendrimers Based on a Pyrazino[2,3-g]quinoxaline Core, Org. Lett. 2009, 11, 4500-4503.
11. M. Mastalerz*, I. M. Oppel, K. Merz, G. Dyker*, Tetrapyridoxycalix[4]arene and its Copper(II)-Complex: Activation of a Tecton for Self-Inclusion Polymers, J. Incl. Phenom. Macrocycl. Chem. 2009, 64 (1-2), 157-161.
10. M. Mastalerz*, One-pot synthesis of an endo-functionalized shape-persistent nano-sized adamantoid cage compound, Chem. Commun. 2008, 4756-4758.
9. M. Mastalerz*, H. J. E. Rivera, W. Hüggenberg, K. Merz, I. M. Oppel, G. Dyker*, Pyridoxycalix[4]arene Palladium(II) Complexes as Tectons for Self-Inclusion Polymers, CrystEngComm 2008, 10, 1120-1122.
8b. M. Mastalerz*, Die nächste Generation formstabiler Zeolith-Analoga: Kovalentgebundene Organische Netzwerkverbindungen, Angew. Chem. 2008, 120, 453-455.
8a. M. Mastalerz*, The Next Generation of Shape-Persistant Zeolite-Analoga: Covalent Organic Framworks, Angew. Chem. Int. Ed. 2008, 47, 445-447.
7. M. Mastalerz*, Konjugierte Polymere und Oligomere, Nachr. Chem. 2007, 55, 1248.
6. M. Mastalerz, G. Dyker*, U. Flörke, G. Henkel, I. M. Oppel, K. Merz, Oligophenyl-calix[4]arenes as Potential Precursors for Funnelenes and Calix[4]triphenylenes: Syntheses and Preliminary Cyclodehydration Studies, Eur. J. Org. Chem. 2006, 4951-4962.
5. M. Mastalerz, W. Hüggenberg, G. Dyker*, Photochemistry of Styrylcalix[4]arenes, Eur. J. Org. Chem. 2006, 3977-3987.
4. M. Mastalerz, G. Dyker*, Synthesis and Spectroscopic Properties of a Novel Bisspiro-calixarene, Synlett 2006, 1419-1421.
3. G. Dyker*, M. Mastalerz, I. M. Müller, K. Merz, K. Koppe, Solvent Dependent Pseudopolymorphism of Trispyridoxycalix[4]arene: cone- vs partial-cone Conformation, Eur. J. Org. Chem. 2005, 4963-4966.
2. G. Dyker*, M. Mastalerz, I. M. Müller, Electron-rich Cavitands via Fourfold Sonogashira Cross-Coupling Reaction of Calix[4]arenes and Bromopyridines – Effect of the Nitrogen Position on Complexation Abilities, Eur. J. Org. Chem. 2005, 3801-3812.
1. G. Dyker*, M. Mastalerz, K. Merz, From a Calix[4]arene to a Hexameric Supracycle, Eur. J. Org. Chem. 2003, 4355–4362.
Talks (upcoming events)
22. "Discrete Organic Molecules as Precursors for Solution Processible Permanent Pourous Materials", invited speaker, 4th Sino-German Symposium, Beijing, PR China, 03.-07.09.2012.
21. "Permanent Porous Materials from Shape-Persistent Organic Molecules", invited speaker, 4th EuChems Meeting, Prague, Czech Republic, 26.-30.08.2012
20. "Discrete Organic Molecules for Permanent Porous Materials“ invited speaker, ACS National Meeting, Philadelphia, USA, 19.-23.08.2012.
19. "Porous Crystalline Materials from Discrete Organic Molecules”, invited speaker, 27th European Crystallography Meeting, Bergen, Norway, 06.08.-12.08.2012.
18. "Construction of Permanent Porous Materials from Discrete Molecules”, Max-Planck-Institut für Intelligente Systeme, Stuttgart, 24.05.2012.
Talks
17. „Defined Organic Molecules for Permanent Porous Crystals“ Vortrag auf Einladung, SMI Symposium, Ruhr-Universität Bochum, 26.-27.03.2012.
16. „Modulare Synthese formstabiler organischer Käfigverbindungen zum Aufbau permanent poröser Materialien“, Chemiedozententagung, Universität Freiburg, 05.-06.03.2012.
15. „Funktionelle nanoporöse Materialen durch Bildung Schiff‘scher Basen, Eberhard-Karls-Universität Tübingen, 10.01.2012.
14. „Von diskreten organischen Käfigverbindungen zu permanent porösen Materialien“, OC-Kolloquium, Johannes-Gutenberg-Universität Mainz, 27.10.2011
13. „Durch dynamische Bildung kovalenter Bindungen zu funktionalisierten porösen Materialien“, 20. Nachwuchswissenschaftler-Symposium Bioorganische Chemie, Karlsruhe Institut für Technologie, 26.09.-29.09.2011.
12. „Funktionalisierte Poröse Moleküle und Materialien - Synthese und Eigenschaften“, OC-Kolloquium, RWTH Aachen, 24.06.2011
11. „Die Iminkondensation als Schlüsselschritt zu definierten, funktionalisierten Käfigverbindungen und porösen Materialien“, OC-Kolloquium, Karlsruhe Institut für Technologie, 07.06.2011
10. Poröse Materialen und definierte Käfigverbindungen - die Bildung Schiff’scher Basen als Schlüsselschritt, Universität Stuttgart, 2011
9. Durch Schiff-Base Reaktionen zu definierten Hohlraummolekülen und porösen Materialien, Chemiedozententagung, Universität Mainz, 2011
8. Via Dynamic Formation of Covalent Bonds to Functionalized Cage Compounds - From Molecules to Materials, Suprachem2011, Universität Essen, 2011
7. Towards Functional Porous Organic Materials via Schiff Base Condensations, 3rd EuChemS Meeting, Nürnberg, 2010.
6. Syntheses of π-conjugated thienyl dendrimers for solar cell applications, FPS mini-symposium of the Dutch Polymer Institute, Utrecht, Netherlands, 2009.
5. Syntheses of π-conjugated thienyl dendrimers with electron-deficient and electron-rich cores, invited talk at the Dutch Polymer Institute FPS mini-symposium, Amsterdam, Netherlands, 2008.
4. Self-assembly beyond supramolecular interactions – Dynamic covalent chemistry as versatile and efficient tool for the synthesis of new organic materials, invited talk at the INTCHEM summer school 2008, Czocha castle, Poland, 2008.
3. Formstabile Makrobizyklen: Synthese und Anwendungen, invited talk, DFG-headquarters, Bonn, Germany, 2008.
2. Progress and Development in Asymmetric Cross-Coupling Reactions, invited talk at the Ruhr-Universität Bochum, Germany, 2007.
1. Bildung eines hexameren Supracyclus aus funktionalisierten Calixarenen, talk at the Osterkolloquium of the Chemistry Faculty of the Gerhard-Mercator-Universität Duisburg, 2003.
Posters
6. Endo-Functionalized Shape-Persistent Cage Compounds via Dynamic Covalent Bond Formation, M. Mastalerz, KOPO 2009, Blaubeuren, Germany, 2009.
5. Endo-Functionalized Shape-Persistent Cage Compounds via Dynamic Covalent Bond Formation, M. Mastalerz, ISNA-13, Luxembourg, 2009.
4. Oligophenylcalix[4]arenes – Potential Precursors for Funnelenes, M. Mastalerz, G. Dyker, U. Flörke, G. Henkel, KOPO 2007, Blaubeuren, Germany, 2007.
3. An Unexpected Macrocycle Cleavage of a Styrylcalix[4]arene by UV-Irradiation, M. Mastalerz W. Hüggenberg, G. Dyker. International Symposium “Templates in Chemistry and Beyond”, Bonn, Germany, 2007.
2. An Unexpected Macrocycle Cleavage of a Styrylcalix[4]arene by UV-Irradiation, M. Mastalerz W. Hüggenberg, G. Dyker. BASF PostDoc Forum 2006, Raleigh, North Carolina, USA, 2006.
1. From a Calix[4]arene to a Hexameric Supracycle, G. Dyker, M. Mastalerz, K. Merz. Symposium “Frontiers in Advanced Synthesis”, Münster, Germany, 2004.
